Infrared and Laser Engineering, Volume. 52, Issue 6, 20230219(2023)

Control of photoelectric properties in all-inorganic CsPbBr3 thin films with two-dimensional interface modification

Qingwei Zhou1,2, Fan Wu1,2, Fang Luo1,2, Xianyan Huang1,2, Chucai Guo1,2、*, and Zhihong Zhu1,2
Author Affiliations
  • 1College of Advanced Interdisciplinary Studies & Hunan Provincial Key Laboratory of Novel Nano-Optoelectronic Information Materials and Devices, National University of Defense Technology, Changsha 410073, China
  • 2Nanhu Laser Laboratory, National University of Defense Technology, Changsha 410073, China
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    Figures & Tables(12)
    Schematic diagrams of an all-inorganic CsPbBr3 PSC with TMDCs interlayer. Schematic diagrams of (a) device structure and (b) energy levels of different layers in the PSC device
    TEM and HRTEM image of TMDCs nanoflakes. (a)-(d) TEM pictures and (e)-(f) HRTEM pictures for (a), (e) MoS2 nanoflake, (b), (f) MoSe2 nanoflake, (c), (g) WS2 nanoflake, (d), (h) WSe2 nanoflake
    Top-view SEM images of the SnO2 films with TMDCs modification. Top-view SEM images of the films with different magnifications, (a1)-(a3) bare SnO2, (b1)-(b3) SnO2/MoS2, (c1)-(c3) SnO2/MoSe2, (d1)-(d3) SnO2/WS2 and (e1)-(e3) SnO2/WSe2
    Transmission curves of FTO/ETL substrates with different TMDCs modification at visible wavelengths
    Schematic diagram and SEM images of CsPbBr3 perovskite grown on TMDCs. (a) Schematic diagram of CsPbBr3 perovskite grown on TMDCs; Top-view SEM images of CsPbBr3 perovskite films grown at the surface of (b) bare SnO2, (c) SnO2/MoS2, (d) SnO2/MoSe2, (e) SnO2/WS2 and (f) SnO2/WSe2
    XRD patterns of the CsPbBr3 perovskite films grown at different surfaces
    Cross-sectional SEM image of an all-inorganic CsPbBr3 PSC with TMDCs interlayer
    Photovoltaic performance of the PSCs with and without TMDCs modification. (a) J–V curves and (b) steady power output curves of different devices; (c) J-V curves of the pristine device and the device with WS2 modification under forward and reverse scan directions; (d) Normalized Voc, Jsc, PCE and FF stability curves of FTO/SnO2/WS2/CsPbBr3/C device under 25 °C and 80% humidity condition
    Mott-Schottky curves of the PSCs with and without TMDCs modification
    (a) TRPL decay curves and (b) PL curves of perovskite films with and without TMDCs modification
    • Table 1. Photovoltaic parameters(Voc, Jsc, PCE and FF) for all-inorganic PSCs with and without TMDCs modification

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      Table 1. Photovoltaic parameters(Voc, Jsc, PCE and FF) for all-inorganic PSCs with and without TMDCs modification

      All-inorganic PSC devicesVoc/V Jsc/mA·cm−2PCEFF
      FTO/SnO2/CsPbBr3/C 1.4747.017.94%76.9%
      FTO/SnO2/MoS2/CsPbBr3/C 1.5257.138.26%75.9%
      FTO/SnO2/MoSe2/CsPbBr3/C 1.5627.519.26%78.9%
      FTO/SnO2/WS2/CsPbBr3/C 1.5677.9710.02%80.2%
      FTO/SnO2/WSe2/CsPbBr3/C 1.5567.799.03%74.5%
    • Table 2. TRPL fitting parameters of perovskite films with and without TMDCs modification

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      Table 2. TRPL fitting parameters of perovskite films with and without TMDCs modification

      Sampleτ1/ns a1τ2/ns a2τave/ns
      Pristine0.53866.08%8.34933.92%0.788
      MoS20.57275.69%7.78324.31%0.738
      MoSe20.46864.09%10.73235.91%0.713
      WS20.53780.64%6.42819.36%0.653
      WSe20.57978.68%6.87521.32%0.720
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    Qingwei Zhou, Fan Wu, Fang Luo, Xianyan Huang, Chucai Guo, Zhihong Zhu. Control of photoelectric properties in all-inorganic CsPbBr3 thin films with two-dimensional interface modification[J]. Infrared and Laser Engineering, 2023, 52(6): 20230219

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    Paper Information

    Category: Mirco-nano optics

    Received: Apr. 12, 2023

    Accepted: --

    Published Online: Jul. 26, 2023

    The Author Email: Guo Chucai (gcc_1981@163.com)

    DOI:10.3788/IRLA20230219

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