Journal of Inorganic Materials, Volume. 35, Issue 12, 1295(2020)

Research Progress on Nanostructured Metal Oxides as Anode Materials for Li-ion Battery

Shiyou ZHENG... Fei DONG, Yuepeng PANG, Pan HAN and Junhe YANG |Show fewer author(s)
Author Affiliations
  • School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
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    Figures & Tables(9)
    (a, b) SEM images of SnO2/C-NTs; (c) Cycling performance at 500 mA/g, and (d) rate capabilities of SnO2-NTs and SnO2/C-NTs[23]
    (a) Illustration of the synthesis principles of ultrafine SnO2 NPs immobilized in the mesopore channels of mesoporous carbon; (b) Cycle performance at 200 mA/g between 0.005 and 3 V, and (c) rate performance of electrodes based on different SnO2 content[31]
    (a) SEM image, and (b) cycle performance at 100 mA/g of CuO NRAs[42]
    (a) Schematic illustration of the synthesis of hollow CuO@NCS composites; (b) Cycle performance of CuO@NCS at 100 mA/g[46]
    TEM images of (a) Fe2O3-graphene particle-on-sheet composite, and (b-d) Fe2O3-graphene sheet-on-sheet composite[57]
    (a) Illustration for the synthetic procedure, (b) TEM image, and (c) rate capabilities of Fe3O4@N-HPCNs[63]
    (a) Structure diagrams of the amorphous porous CoSnO3/Au composite nanocubes; Cycle performance of the amorphous porous CoSnO3/Au composite nanocubes at (b) 0.2 and (c) 5 A/g[65]
    (a) Schematic illustration for the synthetic procedure, (b) TEM image, and (c) rate capabilities of spinel ZnxCo3-xO4 hollow polyhedron[79]
    • Table 1. Structures and comprehensive electrochemical performances of different metal oxide anode materials

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      Table 1. Structures and comprehensive electrochemical performances of different metal oxide anode materials

      Materials structureFirst cyclic capacity/(mAh∙g-1) (Current density/(A∙g-1))Coulombic efficiencyCycling performance/ (mAh∙g-1) (Current density/ (A∙g-1), cycle number)Rate performance/(mAh∙g-1) (Current density/(A∙g-1))Ref.
      SnO2 NPs (5~20 nm)1310 (0.1)69%800 (0.1, 100)850 (1); 800 (2)[22]
      SnO2/C-NT (15 nm)483 (0.5)51%596 (0.5, 200)683 (1); 550 (2)[23]
      SnO2 nanosheets (7.4 nm)1338 (0.1)55%763 (0.1, 300)460 (1); 280 (2)[24]
      SnO2 HS (50 nm)736 (0.1)47%540 (0.1, 50)550 (1); 422 (2)[26]
      SnO2/C (50~100 nm)998 (0.1)69%750 (0.1, 100)413 (1); 325 (2)[28]
      C-SnO2/CNT (7 nm)1373 (1)52%950 (1, 100)1100 (1); 950 (2)[29]
      SnO2@G-SWCNT (7 nm)1007 (0.1)53%785 (0.1, 100)510 (1); 426 (2)[30]
      SnO2@CMK-5 (4~5 nm)694 (0.2)71%1039 (0.1, 100)770 (1)[31]
      SnO2/C (2.8 nm)899 (1.4)44%560 (1.4, 100)700 (1.4); 538 (2.8)[32]
      CuO spheres (400 nm)590 (0.45)66%400 (0.45, 50)-[34]
      CuO octahedra (5 nm)506 (0.5)70%785 (0.5, 50)488 (1); 370 (2)[40]
      CuO labyrinths (20 nm)645 (0.1)66%330 (1, 100)340 (1.3); 255 (3.4)[41]
      CuO NRAs (2~3 μm)751 (0.1)56%671 (0.1, 150)367 (1); 300 (2)[42]
      CuO spheres (10 nm)552 (0.67)55%750 (0.67, 350)650 (1.3); 600 (3.4)[43]
      CuO/MWCNT (10 nm)462 (0.07)69%650 (0.07, 100)590 (1.3); 590 (2)[44]
      Cu2O/CuO/rGO (500 nm)375 (0.3)75%570 (0.3, 100)350 (1.3); 250 (2.7)[45]
      Cu@NCSs (45 nm)909 (0.5)62%602 (0.5, 200)760 (1); 570 (2)[46]
      Graphene/Fe2O3 (40 nm)1074 (0.1)65%800 (0.1, 50)-[57]
      Fe2O3/CA (5~50 nm)836 (0.1)55%635 (0.1, 100)652 (0.4); 546 (0.8)[58]
      RG-O/Fe2O3 (60 nm)1219 (0.1)72%1027 (0.1, 50)970 (0.4); 760 (0.8)[59]
      Fe3O4@PCFs (10~60 nm)1014 (0.2)72%920 (0.2, 80)677 (1); 523 (2)[51]
      Fe3O4/PPy (200 nm)493 (1)89%554 (1, 100)500 (1); 330 (2)[61]
      Fe3O4-CNTs (50~100 nm)845 (0.05)77%702 (0.05, 50)-[62]
      Fe3O4@N-HPCNs (6 nm)521 (0.1)54%1240 (0.1, 100)700 (1); 600 (2)[63]
      CoMoO4 NPs (2~10 nm)1051 (0.2)72%1185 (0.2, 100)900 (1); 850 (2)[77]
      CoSnO3/Au cube (70 nm)1693 (0.2)68%1615 (0.2, 100)1425 (1); 1289 (2)[65]
      NiFe2O4 NPs (20 nm)1177 (0.1)79%1390 (0.1, 20)823 (1); 725 (3)[70]
      ZnxCo3-xO4 (10 nm)967 (0.1)76%990 (0.1, 50)1020 (0.9); 988 (2.7)[79]
      NixCo3-xO4 (40 nm)1133 (0.1)70%1109 (0.1, 100)864 (1); 728 (2)[80]
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    Shiyou ZHENG, Fei DONG, Yuepeng PANG, Pan HAN, Junhe YANG. Research Progress on Nanostructured Metal Oxides as Anode Materials for Li-ion Battery[J]. Journal of Inorganic Materials, 2020, 35(12): 1295

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    Paper Information

    Category: REVIEW

    Received: Mar. 16, 2020

    Accepted: --

    Published Online: Mar. 10, 2021

    The Author Email:

    DOI:10.15541/jim20200134

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