Laser & Optoelectronics Progress, Volume. 56, Issue 14, 143001(2019)

Pb Detection in Paint Coatings Through Combined Laser-Induced Breakdown Spectroscopy and CARS Variable Screening

Zijun Wu, Jingqi Lu*, Jian Huang, and Dewei Cheng
Author Affiliations
  • School of Science, Wuhan University of Technology, Wuhan, Hubei 430070, China
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    Figures & Tables(9)
    Diagram of LIBS experimental setup
    Characteristic spectra of lead in paint coatings at 308-417 nm
    Calibration curve of 405.78 nm analytical line of Pb I
    Prediction results of multiple linear regression model for correction set
    Screening results of wavelength variables by CARS algorithm. (a) Trend of variable number of wavelength; (b) trend of RMSECV; (c) trend of regression coefficients of various wavelength variables
    Distribution of wavelength variables screened by CARS algorithm
    Prediction results of CARS-PLS model for correction set
    • Table 1. Reference content of lead in paint coating samples

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      Table 1. Reference content of lead in paint coating samples

      Sample numberReference content /%
      1#0.014
      2#0.015
      3#0.027
      4#0.036
      5#0.042
      6#0.055
      7#0.11
      8#0.15
      9#0.17
      10#0.24
    • Table 2. Prediction result of each analysis model for sample of prediction set

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      Table 2. Prediction result of each analysis model for sample of prediction set

      PredictsetReferencecontent /%Univariate calibrationMLRALL-PLSCARS-PLS
      Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%Predictedcontend /%Relativeerror /%
      4#0.0360.03211.10.040311.90.031711.90.03651.4
      7#0.110.09315.50.10861.30.11999.00.11161.5
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    Zijun Wu, Jingqi Lu, Jian Huang, Dewei Cheng. Pb Detection in Paint Coatings Through Combined Laser-Induced Breakdown Spectroscopy and CARS Variable Screening[J]. Laser & Optoelectronics Progress, 2019, 56(14): 143001

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    Paper Information

    Category: Spectroscopy

    Received: Jan. 9, 2019

    Accepted: Feb. 17, 2019

    Published Online: Jul. 12, 2019

    The Author Email: Lu Jingqi (lujingqi@whut.edu.cn)

    DOI:10.3788/LOP56.143001

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