Journal of Inorganic Materials, Volume. 39, Issue 4, 359(2024)

Influence of Upconversion Luminescent Nanoparticles on Hysteresis Effect and Ion Migration Kinetics in Perovskite Solar Cells

Man YU1... Rongyao GAO2, Yujun QIN2 and Xicheng AI2,* |Show fewer author(s)
Author Affiliations
  • 11. School of Materials Engineering, Xi'an Aeronautical Institute, Xi’an 710077, China
  • 22. Department of Chemistry, Renmin University of China, Beijing 100872, China
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    Figures & Tables(14)
    Schematic diagrams of structures of (a) perovskite solar cells and (b) UCNP
    (a) Schematic illustration of the cs-TPT setup ](ND filter: neutral density filter, DUT: device under test, Sync.: synchronizing, Trig.: trigger, Sig.= signal); (b) Time sequences of typical cs-TPT settings (Trigger, Laser, VG, and RS)
    SEM images of (a) Compact/PVK, (b) UCNP+ Compact/PVK, (c) Compact/PVK+UCNP, and (d) UCNP+ Compact/PVK+UCNP
    (a) TEM image and (b) XRD pattern of NaLuF4:20%Yb3+, 2%Er3+
    Mixed solutions of (a) UCNP+Compact and (b) PVK+ UCNP irradiated with 980 nm laser
    XRD patterns of Compact/PVK, UCNP+Compact/PVK, Compact/PVK+UCNP, and UCNP+Compact/PVK+UCNP samples
    (a) UV-Vis absorption and steady-state fluorescence spectra of perovskite films deposited on quartz substrates, and (b) time resolved fluorescence spectra of four perovskite thin films
    Pictures of (a) UCNP+Compact/PVK, (b) Compact/PVK+UCNP and (c) UCNP+Compact/PVK+UCNP irradiated with 980 nm laser
    PCE and HF statistical data of different devices under forward and reverse scanning
    J-V curves under forward and reverse scanning conditions for perovskite solar cells with champion performances of (a) Compact/PVK, (b) UCNP+Compact/PVK, (c) Compact/PVK+UCNP, and (d) UCNP+Compact/PVK+UCNP
    (a) Open-circuit photovoltage buildup curves and (b) cs-TPT kinetics curves of different perovskite solar cells
    Mechanism of UCNP inhibiting ion migration
    • Table 1. HF and variance of PCE under forward and reverse scanning conditions of cells

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      Table 1. HF and variance of PCE under forward and reverse scanning conditions of cells

      SampleS2(PCEreverse) S2(PCEforward) S2(HF)
      Compact/PVK0.559560.580460.01156
      UCNP+Compact/PVK0.413180.409680.01130
      Compact/PVK+UCNP0.258380.336910.00810
      UCNP+Compact/PVK+UCNP0.193040.962620.01451
    • Table 1. Photovoltaic parameters and hysteresis factors (HF) of four perovskite devices upon forward and reverse scanning conditions

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      Table 1. Photovoltaic parameters and hysteresis factors (HF) of four perovskite devices upon forward and reverse scanning conditions

      SampleScan directionOpen-circuit voltage/mV Short-circuit current/ (mA·cm-2) FF/%PCE/%HF
      Compact/PVKReverse99619.5663.4512.360.42
      Forward91217.8944.137.20
      UCNP+Compact/PVKReverse103820.370.7415.650.07
      Forward104519.840.7014.52
      Compact/PVK+UCNPReverse103420.960.7516.270.05
      Forward103220.390.7315.37
      UCNP+Compact/PVK+UCNPReverse101618.310.6612.280.15
      Forward97617.760.6010.40
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    Man YU, Rongyao GAO, Yujun QIN, Xicheng AI. Influence of Upconversion Luminescent Nanoparticles on Hysteresis Effect and Ion Migration Kinetics in Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2024, 39(4): 359

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    Paper Information

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    Received: Sep. 18, 2023

    Accepted: --

    Published Online: Jul. 8, 2024

    The Author Email: AI Xicheng (xcai@ruc.edu.cn)

    DOI:10.15541/jim20230424

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