Journal of Inorganic Materials, Volume. 36, Issue 6, 629(2021)

Passiviation of L-3-(4-Pyridyl)-alanine on Interfacial Defects of Perovskite Solar Cell

Wenwen LIU1... Zhilei HU1, Li WANG1, Mengsha CAO1, Jing ZHANG1, Jing ZHANG1, Shuai ZHANG1,*, Ningyi YUAN1 and Jianning DING2,* |Show fewer author(s)
Author Affiliations
  • 11. School of Materials Science and Engineering, Jiangsu Photovoltaic Science and Engineering Collaborative Innovation Center, Changzhou university, Changzhou 213164, China
  • 22. Micro Center for Science and Technology, Jiangsu University, Zhenjiang 212013, China
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    Figures & Tables(11)
    (a) Molecular structure of PLA and (b) schematic diagram of PSC device with PLA
    (a,b) Surface and (c,d) cross sectional SEM images, (e,f) grain size distributions of FTO/TiO2/perovskite films (a, c, e) without and (b, d, f) with PLA
    (a) ATR-FT-IR spectra, ((b) magnified ATR-FT-LR spectra of rectangular area in (a)), (c) UV-Vis absorption spectra and (d) XRD patterns of FTO/TiO2/perovskite films with and without PLA
    Statistical deviations of (a)JSC, (b)VOC, (c) FF, and (d) PCE for PSC devices without and with PLA
    Forward and reverse scan J-V curves of the optimal PSC devices (a) without and (b) with PLA, (c) comparison of the reverse J-V curves, and (d) external quantum efficiency spectra and integrated JSC curves for the optimal PSC devices without and with PLA
    (a) PL spectra, (b) TRPL spectra (λexcitation=510 nm) and TRPL fitting results of glass/perovskite films with and without PLA
    (a) Schematic diagram of electron-only perovskite film device with PLA, and (b) SCLC measurements of electron-only perovskite film devices with and without PLA
    (a,b) Surface and (c,d) cross sectional SEM images of FTO/TiO2/PbI2 film without PLA (a, c) and with PLA (b, d)
    EIS plots of PSC without and with PLA (a) under illumination and (b) in dark
    • Table 1. EIS fitting parameters of PSC without and with PLA under illumination and in dark

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      Table 1. EIS fitting parameters of PSC without and with PLA under illumination and in dark

      DeviceRS / (Ω·cm-2)R1 / (Ω·cm-2)R2 / (Ω·cm-2)
      Without PLA (Illumination)1.8058.707.90
      With PLA (Illumination)1.4315.7440.49
      Without PLA (Dark)0.783.46×1052.27×104
      With PLA (Dark)1.212.15×1044.50×105
    • Table 1. Mean values and standard deviation (SD) of photovoltaic parameters for PSC devices without and with PLA

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      Table 1. Mean values and standard deviation (SD) of photovoltaic parameters for PSC devices without and with PLA

      DeviceJSC(SD)/(mA·cm-2)VOC(SD)/VFF(SD)/%PCE(SD)/%
      Without PLA23.84(0.74)1.07(0.02)76.80(1.15)19.49(0.48)
      With PLA24.37(0.50)1.07(0.02)78.74(1.43)20.55(0.39)
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    Wenwen LIU, Zhilei HU, Li WANG, Mengsha CAO, Jing ZHANG, Jing ZHANG, Shuai ZHANG, Ningyi YUAN, Jianning DING. Passiviation of L-3-(4-Pyridyl)-alanine on Interfacial Defects of Perovskite Solar Cell[J]. Journal of Inorganic Materials, 2021, 36(6): 629

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Aug. 27, 2020

    Accepted: --

    Published Online: Nov. 25, 2021

    The Author Email: ZHANG Shuai (shuaizhang@cczu.edu.cn), DING Jianning (dingjn@cczu.edu.cn)

    DOI:10.15541/jim20200495

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