Journal of Inorganic Materials, Volume. 34, Issue 8, 873(2019)

Oxidation Characteristics of Magnesium Diboride

Yang GUO1...2, Wei ZHANG2,*, Xing ZHOU2,* and Lei DENG2 |Show fewer author(s)
Author Affiliations
  • 1PLA Academy of Military Science, Beijing 100091, China
  • 2College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
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    Figures & Tables(12)
    TG and DTA curves of MgB2 oxidation in air flow
    SEM images of MgB2 oxidation residues
    XRD patterns of MgB2 oxidation residues
    B2O3-MgO binary phase diagram[23]
    Cross-sectional SEM image of oxide layer structure of MgB2 pellet after being heated up to 1665 K
    Linear EDS mapping of MgB2 pellet across the oxide layer
    XRD pattern of the internal porous oxide layer
    Schematic diagram of evolution of MgB2 oxidation reaction
    TG and DTA curves of amorphous boron oxidation under ultra-high temperature[24]
    • Table 1. Combustion heats and combustion efficiencies of amorphous boron and MgB2

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      Table 1. Combustion heats and combustion efficiencies of amorphous boron and MgB2

      SampleTheoretical combustion heat/(J·g-1)Experimental combustion heat/(J·g-1)Combustion efficiency/%
      B-58826-22465±11438
      MgB2-38781-23943±78862
    • Table 2.

      Chemical analytical results of MgB2 oxidation residues

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      Table 2.

      Chemical analytical results of MgB2 oxidation residues

      Temperature
      /K
      ${{n}_{\text{MgO}}}/{{n}_{{{\text{B}}_{\text{2}}}\text{O}}}_{_{\text{3}}}$Fraction of
      unoxidized Mg/mol%
      Fraction of unoxidized boron/mol%${{n}_{\text{B}}}/{{n}_{\text{Mg}}}$
      11651.14 : 181.1183.382.06 : 1
      13003.04 : 122.7374.626.56 : 1
      14051.52 : 16.3538.3512.08 : 1
      15201.26 : 12.1422.3020.89 : 1
    • Table 3. EDS results of the internal and external oxide layer of MgB2 pellet

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      Table 3. EDS results of the internal and external oxide layer of MgB2 pellet

      PositionB/mol%O/mol%Mg/mol%
      Internal11.7851.2237.00
      External56.4343.57
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    Yang GUO, Wei ZHANG, Xing ZHOU, Lei DENG. Oxidation Characteristics of Magnesium Diboride[J]. Journal of Inorganic Materials, 2019, 34(8): 873

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    Paper Information

    Category: RESEARCH PAPER

    Received: Sep. 14, 2018

    Accepted: --

    Published Online: Sep. 26, 2021

    The Author Email: ZHANG Wei (wzhang_nudt@nudt.edu.cn), ZHOU Xing (xingzhou_nudt@nudt.edu.cn)

    DOI:10.15541/jim20180428

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