Journal of Inorganic Materials, Volume. 36, Issue 5, 513(2021)

Valence State Control of Manganese in MgAl2O4:Mn4+ Phosphor by Varying the Al2O3 Crystal Form

Zhaowu WANG1, Haipeng JI1、*, Feixiang WANG1, Xinghui HOU1, Shasha YI1, Ying ZHOU1, and Deliang CHEN1,2、*
Author Affiliations
  • 11. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
  • 22. School of Materials Science and Engineering, Dongguan University of Technology, Dongguan 523808, China
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    References(24)

    [5] ZHOU Y Y, WANG L Y, DENG T T et al. Recent advances in Mn4+-doped fluoride narrow-band red-emitting phosphors[J]. Scientia Sinica Technologica, 47, 1111-1125(2017).

    [14] ZHONG R X, ZHANG J H, WEI H Z et al. The different luminescent characteristics of MgAl2O4:Mn2+ between phosphor powder and nanoparticles[J]. Chemical Physics Letters, 508, 207-209(2011).

    [15] SONG E H, ZHOU Y Y, WEI Y et al. A thermally stable narrow- band green-emitting phosphor MgAl2O4:Mn2+ for wide color gamut backlight display application[J]. Journal of Materials Chemistry C, 7, 8192-8198(2019).

    [16] WAKUI Y, SHAN Y J, TEZUKA K et al. Crystal-site engineering approach for preparation of MgB2O4:Mn2+,Mn4+(B=Al,Ga) phosphors: control of green/red luminescence properties[J]. Materials Research Bulletin, 90, 51-58(2017).

    [17] ZHANG Y L, LIU Y L, YANG L et al. Preparation and luminescence properties of thermally stable Mn4+ doped spinel red-emitting ceramic phosphors[J]. Journal of Luminescence, 220, 117016(2020).

    [18] CHI N T K, QUANG N V, TUAN N T et al. Deep red emitting MgAl2O4:Cr3+ phosphor for solid state lighting[J]. Journal of Electronic Materials, 48, 5891-5899(2019).

    [19] ZHANG Y L, HU S, LIU Y L et al. Red-emitting Lu3Al5O12:Mn transparent ceramic phosphors: valence state evolution studies of Mn ions[J]. Ceramics International, 44, 23259-23262(2018).

    [20] DUAN C J, DELSING A C A, HINTZEN H T. Photoluminescence properties of novel red-emitting Mn2+-activated MZnOS (M= Ca, Ba) phosphors[J]. Chemistry of Materials, 21, 1010-1016(2009).

    [21] KÜCK S, HARTUNG S, HURLING S et al. Optical transitions in Mn3+-doped garnets[J]. Physical Review B, 57, 2203-2216(1998).

    [22] ZHANG Y L, HU S, LIU Y L et al. Influences of thermal post-treatment on the Mn valence states and luminescence properties of red-emitting Lu3Al5O12:Mn4+ transparent ceramic phosphors[J]. Optical Materials, 101, 109705(2020).

    [23] CHEN L, XUE S, CHEN X et al. The site occupation and valence of Mn ions in the crystal lattice of Sr4Al14O25 and its deep red emission for high color-rendering white light-emitting diodes[J]. Materials Research Bulletin, 60, 604-611(2014).

    [24] XU H, WANG L, MA X et al. A novel Mn(II)-based green phosphor and its self-reduction mechanism[J]. Journal of Luminescence, 194, 303-310(2018).

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    Zhaowu WANG, Haipeng JI, Feixiang WANG, Xinghui HOU, Shasha YI, Ying ZHOU, Deliang CHEN. Valence State Control of Manganese in MgAl2O4:Mn4+ Phosphor by Varying the Al2O3 Crystal Form[J]. Journal of Inorganic Materials, 2021, 36(5): 513

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Jul. 9, 2020

    Accepted: --

    Published Online: Nov. 25, 2021

    The Author Email: Haipeng JI (jihp@zzu.edu.cn), Deliang CHEN (dlchen@zzu.edu.cn)

    DOI:10.15541/jim20200386

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