Journal of Inorganic Materials, Volume. 36, Issue 10, 1083(2021)

Co-modification of Biochar and Bentonite for Adsorption and Stabilization of Pb2+ ions

Yao XIAO1... Zhongjie WU2, Mei CUI3, Rongxin SU3,4, Lianke XIE2 and Renliang HUANG4,* |Show fewer author(s)
Author Affiliations
  • 11. School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
  • 22. Shandong Electric Power Research Institute of Chinese Power Company, Jinan 250002, China
  • 33. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 44. School of Marine Science and Technology, Tianjin University, Tianjin 300072, China
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    Figures & Tables(13)
    SEM images of three biochars
    XRD patterns of CB,CaO-CB and CaO-Bent-CB
    FT-IR spectra of CB,CaO-CB and CaO-Bent-CB
    Effect of different adsorbents on the removal of Pb2+ in the solution
    Effect of solution pH on the absorption quatity and removal of Pb2+ by CaO-Bent-CB
    Effect of ionic strength on the removal of Pb2+ in the solution by CaO-Bent-CB
    Effect of bentonite loading on the absorption quatity and removal of Pb2+ by CaO-Bent-CB
    Adsorption kinetic curves for Pb2+ removal by CaO-Bent-CB
    Adsorption isotherm curves for Pb2+ removal by CaO-Bent-CB
    Lead concentrations in acid leachate with different adsorbents
    • Table 1. Specific surface area and pore size of biochars

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      Table 1. Specific surface area and pore size of biochars

      SampleSpecific surface area/(m2·g-1) Average pore width/nm
      CB132.723.06
      CaO-CB177.223.63
      CaO-Bent-CB441.063.78
    • Table 2. Parameters of the kinetic model for the adsorption of Pb2+ by CaO-Bent-CB

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      Table 2. Parameters of the kinetic model for the adsorption of Pb2+ by CaO-Bent-CB

      SampleQe/(mg·g-1) Pseudo first-order kinetic model Pseudo second-order kinetic model Intraparticle diffusion kinetic model
      R2k1/min-1R2k2/(g·mg-1·min-1/2) R2kid/(g·mg-1·min-1/2)
      CaO-Bent-CB88.6160.8870.02840.9830.0004840.8511.923
    • Table 3. Thermodynamic parameters of the adsorption of Pb2+ by CaO-Bent-CB according to models

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      Table 3. Thermodynamic parameters of the adsorption of Pb2+ by CaO-Bent-CB according to models

      SampleQmax/(mg·g-1) Langmuir adsorption modelFreundlich adsorption modelTemkin adsorption model
      R2KL/(L·g-1) R2KF/(mg·g-1) R2KT/(mg·g-1) B
      CaO-Bent-CB232.1670.9890.001020.9881.2380.96877.3950.0671
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    Yao XIAO, Zhongjie WU, Mei CUI, Rongxin SU, Lianke XIE, Renliang HUANG. Co-modification of Biochar and Bentonite for Adsorption and Stabilization of Pb2+ ions [J]. Journal of Inorganic Materials, 2021, 36(10): 1083

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Dec. 30, 2020

    Accepted: --

    Published Online: Nov. 26, 2021

    The Author Email: HUANG Renliang (tjuhrl@tju.edu.cn)

    DOI:10.15541/jim20200745

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