Chinese Optics Letters, Volume. 22, Issue 1, 013001(2024)

Terahertz spectroscopy of water in nonionic reverse micelles

Jiaqi Zhang1, Yuyue Yan1, Liyuan Liu1、*, and Weili Zhang2、**
Author Affiliations
  • 1Centre for Terahertz Waves and College of Precision Instrument and Optoeletronics Engineering, Tianjin University, Tianjin 300072, China
  • 2School of Electrical and Computer Engineering, Oklahoma State University, Stillwater, Oklahoma 74078, United States
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    Figures & Tables(8)
    (a) Molecular formula of Igepal CO-520; n in the formula is about 5. (b) Schematic illustration of prepared reverse micelle.
    (a) Time-domain spectra of air reference and measured reverse micelle mixtures; (b) frequency-domain spectra of air reference and measured reverse micelle mixtures.
    THz complex permittivity (circle markers) of reverse micelles and fitted lines (solid lines) with proposed model.
    Decomposed spectra of (a)–(b) ω0 = 5 and (c)–(d) 15 including fast water (blue solid line), bulk water (green solid line), and the background, which is determined linearly by the permittivity of ω0 = 0 mixture (pink solid line). (a), (c) and (b), (d) represent the real and imaginary part of obtained complex permittivity, respectively. The black dashed line is the fitted line with the proposed model.
    (a) Obtained molar concentration of fast water (blue dashed line), bulk water (green dashed line), hydration water (red dashed line), and total water (black dashed line); (b) zoomed-in molar concentration of fast water; (c) calculated hydration water number per Igepal molecule.
    (a) Definition of radius of nonhydrated, hydrated, and the total water nanopool; (b) ratios of the radius of nonhydrated (blue circles and dashed line) and hydrated water (red circles and dashed line) to the radius of the total water nanopool.
    • Table 1. Quantities of Chemical Compound Components in Prepared Reverse Micelles

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      Table 1. Quantities of Chemical Compound Components in Prepared Reverse Micelles

      ω001.53581015
      Water/g00.120.240.40.640.81.2
      Igepal/g2222222
      Cyclohexane/g5555555
    • Table 2. Relevant and Fitted Parameters from Eq. (5)

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      Table 2. Relevant and Fitted Parameters from Eq. (5)

      ω0SfastSbulkεf
      1.50.0600.040.98
      30.100.260.070.97
      50.141.060.120.95
      80.162.280.220.93
      100.183.260.280.91
      150.245.540.420.87
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    Jiaqi Zhang, Yuyue Yan, Liyuan Liu, Weili Zhang, "Terahertz spectroscopy of water in nonionic reverse micelles," Chin.Opt.Lett. 22, 013001 (2024)

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    Paper Information

    Category: Spectroscopy

    Received: May. 31, 2023

    Accepted: Aug. 15, 2023

    Published Online: Jan. 9, 2024

    The Author Email: Liyuan Liu (lyliuma@tju.edu.cn), Weili Zhang (weili.zhang@okstate.edu)

    DOI:10.3788/COL202422.013001

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