Spectroscopy and Spectral Analysis, Volume. 42, Issue 2, 341(2022)
Research Progress of Surface-Enhanced Raman Scattering Detection Analyte Molecules
Figures & Tables(11)
![(a) Raman spectra of Ag/ZnO nanorods for R6G detection in 2017 and 2019; (b) Raman spectra of 10-14~10-6 mol·L-1 R6G detected on Ag/ZnO nanorods[26]](/Images/icon/loading.gif){kind=icon}
Fig. 1. (a) Raman spectra of Ag/ZnO nanorods for R6G detection in 2017 and 2019; (b) Raman spectra of 10-14~10-6 mol·L-1 R6G detected on Ag/ZnO nanorods[26]
Fig. 2. Schematic diagram of preparation of Au@H-C3N4substrates and the process of SERS detection[31]
Fig. 3. Process of preparing ITO-Au@Ag@ZIF-8 chip and schematic diagram for detection of carbendazim in Seawater[34]
Fig. 4. Schematic of preparation process of superhydrophobic Ag coated cotton fabric substrate and SERS evaluation of prepared substrates[43]
Fig. 5. (a) Average spectrum of normalized SERS signals of 60 normal serum samples (solid blue line) and 60 cancer serum samples (dashed red line); (b) Difference spectrum between the average spectrum of normal serum and the average spectrum of cancer serum[13]
Fig. 6. Schematic fabrication process of PA @Ag SERS substrate and interaction between polyamide 6[27]
Fig. 7. (a)Schematic illustration of the fabrication process of F-SANC substrate and its application in SERS detection of AAm;(b) EMF simulation of SANC corresponding to mono-particle and dual-particles[11]
Table 1. Detection of analyte molecules in the field of chemical analysis
View tableView in ArticleTable 1. Detection of analyte molecules in the field of chemical analysis
分析物分子 基底 检出限 激发光源波长/nm 文献 4-巯基苯甲酸 Au-Ag dealloyed nanorod 10-6 mol·L-1 532 [23] 三硝基甲苯 wrinkled nanocone flexible SERS substrate(WNFSS) 10-13 mol·L-1 633 [24] 罗丹明6G Ag/ZnO NRs 10-13 mol·L-1 532 [26] 罗丹明6G GR/Au NDs 10-12 mol·L-1 532 [28] 结晶紫 Au nanocrystals 10-6 mol·L-1 785 [29] 结晶紫 dendritic silver nanostructures layer 10-8 mol·L-1 532 [30] 结晶紫 Au@H-C3N4 10-9 mol·L-1 785 [31] 罗丹明6G graphene nano-mesh-Ag-ZnO metal (GNMM) 10-13 mol·L-1 532 [32] 罗丹明6G Ag NPs/Cu NWs 10-13 mol·L-1 532 [33] 罗丹明6G ITO-Au@Ag5@ZIF-8 10-9 mol·L-1 633 [34] 罗丹明6G ER-Au film 10-11 mol·L-1 633 [35] 罗丹明6G PS/AuAg NDs 10-14 mol·L-1 633 [36]
Table 2. Detection of analyte molecules in the field of environmental monitoring
View tableView in ArticleTable 2. Detection of analyte molecules in the field of environmental monitoring
分析物分子 基底 检出限 激发光源波长/nm 文献 二氟沙星 Ag/TiO2 NPs 4.36×10-12 mol·L-1 633 [10] 环丙沙星 Ag/TiO2 NPs 7.08×10-11 mol·L-1 633 [10] 恩诺沙星 Ag/TiO2 NPs 3.94×10-11 mol·L-1 633 [10] 达氟沙星 Ag/TiO2 NPs 3.16×10-11 mol·L-1 633 [10] 依诺沙星 Ag/TiO2 NPs 3.15×10-10 mol·L-1 633 [10] 福美双 h-BN/CuAg NAs 10-12 mol·L-1 633 [12] 苯甲醚 dendritic silver nanostructures layer 4×10-9 mol·L-1 532 [30] 多菌灵 ITO-Au@Ag5@ZIF-8(1.5 h) 10-9 mol·L-1 633 [34] 对硝基苯酚 ER-Au film 10-9 mol·L-1 633 [35] 邻苯二甲酸二甲酯 Au NP/PDA-MIP/SPE 10-10 mol·L-1 785 [39] 甲基对硫磷 Au NRs 0.44 μg·cm-2 785 [41] 毒死蜱 PSPs 10-10 mol·L-1 785 [42] 福美双 Ag-coated cotton 8×10-7 mol·L-1 532 [43] 福美双 Au/Ni NWs 10-10 mol·L-1 633 [44] 蒽 Ag NPs 10-5 mol·L-1 488 [46] 芘 Ag NPs 10-6 mol·L-1 488 [46] 艹屈 Ag NPs 10-6 mol·L-1 488 [46] 蒽 Ag NPs 100 ng·L-1 785 [48] 芘 Ag NPs 50ng·L-1 785 [48] Hg2+ 4-MPy/Au NPs/ITO 1 ng·L-1 633 [49] Hg2+ Au@Ag NPs 10-10 mol·L-1 633 [50]
Table 3. Detection of analyte molecules in the field of biomedical
View tableView in ArticleTable 3. Detection of analyte molecules in the field of biomedical
分析物分子 基底 检出限 激发光源波长/nm 文献 叶酸 PA@Ag NRs 5.24×10-12 mol·L-1 532 [27] 腺苷酸 PA@Ag NRs 10-8 mol·L-1 532 [27] 糖化白蛋白 multiscale flaked silver SERS-substrate(MFSS) 15 μL血清 785 [54] A型流感病毒 Au nano-poocorn 97 PFU·mL-1 632.8 [55] 跨膜糖蛋白MUC4 Au NFs 0.1 ng·mL-1 785 [58] 苏林酸 Ag NPs 10-10 mol·L-1 633 [59] 甲氨蝶呤 Ag colloid 2.36×10-6 mol·L-1 785 [61] 甲氨蝶呤 AO-Ag 4.2 μg·mL-1 532 [62]
Table 4. Probe analyte molecules in the field of food safety
View tableView in ArticleTable 4. Probe analyte molecules in the field of food safety
分析物分子 基底 检出限 激发光源波长/nm 文献 罗丹明 B Ag/Ag2O NPs 10-11 mol·L-1 633 [8] 丙烯酰胺 SiO2/Ag nanocomposites(SANC) 2×10-11 mol·L-1 633 [11] 三聚氰胺 Au@H-C3N4 1.8×10-7 mol·L-1 785 [31] 丙烯酰胺 PDA@Ag NPs 0.04 μg·L-1 785 [64] 黄曲霉素B1 Fe3O4@Au NFs Au@Ag NSs 0.4 ng·L-1 633 [65] 黄曲霉素B1 Au NBP/AAO 0.5 μg·L-1 785 [66] 罗丹明 B Ag@AAO DHPCs 10-11 mol·L-1 633 [69] 三聚氰胺 ZnO∶Al/Ag 10-9 mol·L-1 532 [70] 三聚氰胺 Ag NWs 10-12 mol·L-1(10 μA) 785 [72] 孔雀石绿 Ag NPs 0.1 μg·L-1 785 [73] 酸性橙Ⅱ Fe3O4@Au 1 μg·mL-1 785 [74] 邻苯二甲酸丁苄酯 Au NS@Ag NCs 10-9 mol·L-1 633 [75]
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Zi-xiong WANG, Da-peng XU, Yi-fan ZHANG, Jia-jia LI. Research Progress of Surface-Enhanced Raman Scattering Detection Analyte Molecules[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 341
Paper Information
Category: Research Articles
Received: Jan. 11, 2021
Accepted: Apr. 2, 2021
Published Online: Apr. 2, 2022
The Author Email: WANG Zi-xiong (1968804635@qq.com)
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