Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 2, 020202(2023)

Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance

Changxian JIN... Dadong SHAO* and Qianhong GAO** |Show fewer author(s)
Author Affiliations
  • School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
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    Figures & Tables(12)
    Schematic diagram of diethyl (2-aminoethyl) phosphonate preparation process
    Schematic diagram of phosphate ester based fiber modification process
    SEM images of UHMWPE (a), (b); UHMWPE-g-GMA (c), (d),; and UHMWPE-g-DEPP (e), (f)
    FTIR spectra (a), XRD patterns (b), TGA patterns (c), and XPS survey spectra (d) of UHMWPE, UHMWPE-g-GMA, UHMWPE-g-DEPP, and U-laden UHMWPE-g-DEPP
    XPS C1s (a), O1s (b), P2p (c), and U4f (d) spectra of UHMWPE, UHMWPE-g-GMA, UHMWPE-g-DEPP and U-laden UHMWPE-g-DEPP
    Effects of pH (a), contact time (b), reaction temperature (c), and lnKd-1/T (d) on the adsorption of U(VI) on UHMWPE, UHMWPE-g-GMA, and UHMWPE-g-DEPP. m/V = 0.2 g/L. (a) T = 298 K; t= 24 h; (b) pH = 5.0; T = 298 K; (c) pH = 5.0; t = 8 h
    Competitive cation effect (a), adsorption desorption cycle (b), T = 298 K, m/V = 0.2 g/L, pH = 5.0, t = 8 h
    • Table 1. Curve fitting results of XPS C1s spectra

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      Table 1. Curve fitting results of XPS C1s spectra

      特征峰

      Peak

      结合能 / eV

      Bingding energy

      半峰宽 / eV

      Full width half maximum

      物质的量分数 / %

      Mole fraction

      UHMWPE碳化物 Carbide C283.821.2214.0
      C-C284.861.8270.7
      C-O286.481.7010.4
      C=O288.091.172.25
      COOH289.021.102.65
      UHMWPE-g-GMA碳化物 Carbide C283.822.363.32
      C-C284.801.2953.8
      C-O286.461.9929.8
      C=O288.091.436.61
      COOH288.901.026.44
    • Table 2. Curve fitting results of XPS O1s spectra

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      Table 2. Curve fitting results of XPS O1s spectra

      特征峰 Peak

      结合能 / eV

      Bingding energy

      半峰宽 / eV

      Full width half maximum

      物质的量分数 / %

      Mole fraction

      UHMWPE-g-DEPPC=O/P=O531.001.6620.3
      C-O/P-O-C532.071.4036.1
      OH533.191.5843.6
      U-laden UHMWPE-g-DEPPC=O/P=O531.181.8717.2
      C-O/P-O-C532.001.4246.2
      OH533.231.6336.6
    • Table 3. Curve fitting results of XPS P2p spectra

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      Table 3. Curve fitting results of XPS P2p spectra

      特征峰 Peak

      结合能 / eV

      Bingding energy

      半峰宽 / eV

      Full width half maximum

      物质的量分数 / %

      Mole fraction

      UHMWPE-g-DEPPP2p3/2133.461.4267.0
      P2p1/2134.261.4333.0
      U-laden UHMWPE-g-DEPPP2p3/2133.441.2971.7
      P2p1/2134.441.3828.3
    • Table 4. Parameters calculated from the Langmuir and Freundlich models for U(VI) adsorption on UHMWPE-g-DEPP at pH=5.0

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      Table 4. Parameters calculated from the Langmuir and Freundlich models for U(VI) adsorption on UHMWPE-g-DEPP at pH=5.0

      T / KLangmuirFreundlich

      qmax

      / (mg‧g-1)

      KL

      / (L‧mg-1)

      R2

      KF

      / (L‧mg-1)

      1/nR2
      2981280.032 00.99916.40.3680.964
      3081340.035 70.99819.10.3510.943
      3181430.045 80.99924.60.3220.948
      3281440.011 50.98944.20.2260.933
    • Table 5. Thermodynamic parameters of U(VI) adsorption by UHMWPE-g-DEPP

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      Table 5. Thermodynamic parameters of U(VI) adsorption by UHMWPE-g-DEPP

      T

      / K

      lnKd热力学参数 Thermodynamic parameters

      ΔG0

      / (kJ‧mol-1)

      ΔH0

      / (kJ‧mol-1)

      ΔS0

      / (J‧mol-1‧K-1)

      2980.104-0.2410.736.7
      3080.261-0.60
      3180.369-0.97
      3280.505-1.33
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    Changxian JIN, Dadong SHAO, Qianhong GAO. Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(2): 020202

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    Paper Information

    Category: Research Articles

    Received: Nov. 14, 2022

    Accepted: Jan. 7, 2023

    Published Online: Jul. 24, 2023

    The Author Email:

    DOI:10.11889/j.1000-3436.2022-0126

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