Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF

Jiong YANG; Zhi-li QIU; Bo SUN; Xian-zi GU; Yue-feng ZHANG; Ming-kui GAO; Dong-zhou BAI; Ming-jia CHEN

doi:10.3964/j.issn.1000-0593(2022)02-0446-08

Spectroscopy and Spectral Analysis, Volume. 42, Issue 2, 446(2022)

Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF

Jiong YANG^{1、1; 2;}, Zhi-li QIU^{1、1; 4; *;}, Bo SUN^3、3;, Xian-zi GU^5、5;, Yue-feng ZHANG^1、1;, Ming-kui GAO^3、3;, Dong-zhou BAI^1、1;, and Ming-jia CHEN^1、1;

Author Affiliations

¹1. Guangdong Key Laboratory of Geodynamic and Geological Hazards, Guangdong Key Laboratory of Geological Process and Mineral Resources Exploration, School of Earth Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275, China

³3. Institution of Archaeology and Cultural Relic, Shandong Provence, Ji'nan 250012, China

⁵5. Shanghai Museum, Shanghai 200003, China

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Figures & Tables(7)

Fig. 1. Photos of representative samples
(a), (b), (d), (e), (h): Unearthed serpentine jades; (c), (f): Taishan jade materials; (g): Unearthed ancient jade, 50×(reflected light); (i): Microphoto of magnetite in Taishan serpentine jade by reflected light

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Fig. 2. Infrared spectra of serpentine jade unearthed from Dawenkou culture (p-FTIR)
(a): Ultrabasic type serpentine jades unearthed from Dawenkou site; (b): Dolomite type serpentine jade unearthed from Dawenkou culture;(c): Ultrabasic type serpentine Jades unearthed from the other Dawenkou culture sites; (d): Taishan jades

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Fig. 3. Distribution of Cr-Cr/Ni values of serpentine jade from different producing (The data source is consistent with table 3 )

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Fig. 4. The position of unearthed serpentine jade and Taishan jade mine
4: Yedian site at Zou county; 5: Dawenkou site in Taian city;13: Lingyanghe site at Jv county; 14: Dazhucun site at Jv county;21: Donghaiyu site in Rizhao city

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Table 1. Characteristic description of serpentine jade unearthed from Dawenkou Culture

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Table 1. Characteristic description of serpentine jade unearthed from Dawenkou Culture

序号	编号	遗址地	器形	矿物学基本特征
1	B型环	泰安大汶口	石环(玉镯)	白色, 粒状变晶结构, 隐晶质结构, 质地细腻, 主要矿物蛇纹石, 黑色磁铁矿呈侵染状分布
2	M2004:1	泰安大汶口	石环(玉镯)	白色, 隐晶质结构, 质地细腻
3	M1005:3	泰安大汶口	玉璜, 残	灰黑色, 不透明, 柱状变晶结构, 主要矿物蛇纹石, 可见黑色磁铁矿, 磁性明显
4	M1006:4	泰安大汶口	石环(玉镯)	灰白-灰绿色, 带蓝色色调, 隐晶质结构, 主要矿物蛇纹石
5	M1013:12	泰安大汶口	石环(玉镯)	原色暗黑色, 表面白色, 柱状变晶结构, 主要矿物蛇纹石, 可见多条黑色磁铁矿条带, 磁性明显
6	无编号	泰安大汶口	玉璜(残损)	绿褐色, 针状或柱状结构
7	M25:66	莒县陵阳河	鼓型珠	白化
8	T11M26	莒县大朱村	玉环(残)	白色, 完全白化, 隐晶质结构, 表面有溶蚀坑、黑点
9	M11	莒县陵阳河	玉饰(四棱锥形)	灰绿色, 粒状结构
10	M20:30	莒县陵阳河	石环	灰白-灰绿色, 柱状、粒状结构, 表面多溶蚀坑, 少量磁铁矿
11	T333-2B①:2	日照东海峪	石饰(长方形坠)	灰绿色, 柱状结构, 少量磁铁矿
12	M49:04	邹县野店	石环(残)	灰绿, 轻微受沁, 柱状结构, 少量磁铁矿
13	资002903M59	邹县野店	石纺轮(残损)	白色, 细腻, 表面有溶蚀坑, 表面擦痕明显
14	92ZJT2062M9	枣庄建新	石镞	白化, 细粒结构, 表面有溶蚀坑, 无使用痕迹
15	采集002418	荏平尚庄	石玦	白色, 完全风化, 玦口平直

Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g^-1)

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Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g^-1)

样号	遗址地	SiO₂	TFe₂O₃	MgO	Cr	Ni	Cr/Ni	类型
M1005:3	泰安大汶口	43.00	6.30	38.25	389	1 072	0.41	S型
M1006:4	泰安大汶口	43.00	3.80	38.00	988	2 124	0.44	S型
M1013	泰安大汶口	43.00	7.93	23.00	1 028	1 632	0.69	S型
M2004:1	泰安大汶口	43.00	0.25	31.50	-	46	-	D型
B型环	泰安大汶口	43.00	0.30	42.00	-	24	-	D型
M25:66	莒县陵阳河	43.00	0.55	36.00	-	32	-	D型
T11M26	莒县大朱村	43.00	0.80	40.00	-	30	-	D型
M11	莒县陵阳河	43.00	1.60	41.00	240	1 464	0.16	S型
M20:30	莒县陵阳河	43.00	4.30	41.67	1 143	2 860	0.4	S型
T333-2B①:2	日照东海峪	43.00	2.6	34.00	1 023	1 613	0.63	S型
M49:04	邹县野店	43.00	2.23	38.67	511	2 014	0.25	S型

Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g^-1)

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Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g^-1)

现代玉料	样号	产地	Cr	Ni	Cr/Ni	成因类型	备注(测试方法)
无损分析	szt003	山东泰安	693	1 776	0.39	S型	p-XRF
	szt004		1 445	3 940	0.37
	szt005		496	1 823	0.27
	szt006		623	2 181	0.29
	szt010		216	984	0.22
	tsy1201		570	2 249	0.25
	tsy1203		977	1 720	0.57
	tsy1204		740	2 719	0.27
	tsy1205		499	2 381	0.21
	tsy1206		1 162	2 553	0.46
	ts05		472	2 042	0.23
	ts04		928	2 152	0.43
	ts03		1 702	6 515	0.26
	ts02		755	1 939	0.39
	ts01		1 004	2 250	0.45
有损分析	泰山玉	山东泰安	797	2 256	0.35	S型	ICP-MS
	鸳鸯玉	甘肃武山	2 262	1 760	1.29	S型	ICP-MS
	岫玉	辽宁岫岩	249	67.7	3.68	D型	ICP-MS
	小寺沟玉	河北小寺沟	2.80	1.06	2.67	D型	ICP-MS
	淅川玉	河南淅川	1 384	1 175	1.18	S型	ICP-AES
	营口玉	辽宁营口	3.74	21.5	0.17	D型	ICP-MS

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Jiong YANG, Zhi-li QIU, Bo SUN, Xian-zi GU, Yue-feng ZHANG, Ming-kui GAO, Dong-zhou BAI, Ming-jia CHEN. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 446

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Paper Information

Category: Research Articles

Received: Dec. 17, 2020

Accepted: Mar. 6, 2021

Published Online: Apr. 2, 2022

The Author Email:

DOI:10.3964/j.issn.1000-0593(2022)02-0446-08

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. Characteristic description of serpentine jade unearthed from Dawenkou Culture

Table 1. Characteristic description of serpentine jade unearthed from Dawenkou Culture

Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g-1)

Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g-1)

Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g-1)

Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g-1)

Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g^-1)

Table 2. p-XRF results of major and trace elements in serpentine jades unearthed from Dawenkou culture(major element: Wt%; trace element: μg·g^-1)

Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g^-1)

Table 3. Nondestructive and destructive test results of Cr, Ni and Cr/Ni value in serpentine jade from different habitats (μg·g^-1)