Synthesis of Novel MAX Phase Ti3ZnC2via A-site-element-substitution Approach

Mian LI; You-Bing LI; Kan LUO; Jun LU; Per EKLUND; Per PERSSON; Johanna ROSEN; Lars HULTMAN; Shi-Yu DU; Zheng-Ren HUANG; Qing HUANG; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]

doi:10.15541/jim20180377

Journal of Inorganic Materials, Volume. 34, Issue 1, 60(2019)

Synthesis of Novel MAX Phase Ti₃ZnC₂via A-site-element-substitution Approach

Mian LI1... You-Bing LI1, Kan LUO1, Jun LU2, Per EKLUND2, Per PERSSON2, Johanna ROSEN2, Lars HULTMAN2, Shi-Yu DU1, Zheng-Ren HUANG1, Qing HUANG1, [in Chinese]1, [in Chinese]1, [in Chinese]1, [in Chinese]2, [in Chinese]2, [in Chinese]2, [in Chinese]2, [in Chinese]2, [in Chinese]1, [in Chinese]1 and [in Chinese]1 |Show fewer author(s)

Author Affiliations

¹1. Engineering Laboratory of Nuclear Energy Materials, Ningbo Institute of Industrial Technology, Chinese Academy of Sciences, Ningbo 315201, China

²2. Department of Physics, Chemistry, and Biology (IFM), Linköping University, 581 83 Linköping, Sweden;

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Figures & Tables(7)

. Element distribution of the MAX phases known to date

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. (a) The unit cell and (b) phonon spectra of Ti₃ZnC₂

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. XRD patterns of the samples (a) before and (b) after exchange reactions

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. SEM images of (a) Ti₃AlC₂, (b)Ti₃ZnC₂, and (c) EDS analysis of the marked area in (b)

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. TEM image and EDS analysis of Ti₃ZnC₂

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Table 1. Lattice parameters and elastic coefficient (C_ij) of Ti₃ZnC₂ and Ti₃AlC₂
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Table 1. Lattice parameters and elastic coefficient (C_ij) of Ti₃ZnC₂ and Ti₃AlC₂
Materials a/nm c/nm C₁₁ C₁₂ C₁₃ C₃₃ C₄₄
Ti₃ZnC₂ 0.3074 1.8602 328 82.3 60.7 242 63.4
Ti₃AlC₂ 0.3069 1.8501 355 73.0 67.6 294 120

Table 2. Gibbs free energy of some exchange reactions by using Ti₃AlC₂ and some oxides (700℃)
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Table 2. Gibbs free energy of some exchange reactions by using Ti₃AlC₂ and some oxides (700℃)
Oxide ZnO CuO NiO CoO Fe₂O₃
Gibbs free energy, ΔG/(kJ·mol^-1) -73.884 -139.154 -109.613 -104.420 -96.082

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Mian LI, You-Bing LI, Kan LUO, Jun LU, Per EKLUND, Per PERSSON, Johanna ROSEN, Lars HULTMAN, Shi-Yu DU, Zheng-Ren HUANG, Qing HUANG, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Synthesis of Novel MAX Phase Ti₃ZnC₂via A-site-element-substitution Approach[J]. Journal of Inorganic Materials, 2019, 34(1): 60

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Paper Information

Category: Research Articles

Received: Aug. 21, 2018

Accepted: --

Published Online: Feb. 4, 2021

The Author Email:

DOI:10.15541/jim20180377

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. Lattice parameters and elastic coefficient (Cij) of Ti3ZnC2 and Ti3AlC2

Table 1. Lattice parameters and elastic coefficient (Cij) of Ti3ZnC2 and Ti3AlC2

Table 2. Gibbs free energy of some exchange reactions by using Ti3AlC2 and some oxides (700℃)

Table 2. Gibbs free energy of some exchange reactions by using Ti3AlC2 and some oxides (700℃)

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Table 1. Lattice parameters and elastic coefficient (C_ij) of Ti₃ZnC₂ and Ti₃AlC₂

Table 1. Lattice parameters and elastic coefficient (C_ij) of Ti₃ZnC₂ and Ti₃AlC₂

Table 2. Gibbs free energy of some exchange reactions by using Ti₃AlC₂ and some oxides (700℃)

Table 2. Gibbs free energy of some exchange reactions by using Ti₃AlC₂ and some oxides (700℃)