Chinese Journal of Chemical Physics, Volume. 33, Issue 5, 540(2020)

Ultrafast Infrared Spectroscopic Study of Microscopic Structural Dynamics in pH Stimulus-Responsive Hydrogels

Jian Hong, De-xia Zhou, Hong-xing Hao, Min Zhao, and Hong-tao Bian*
Figures & Tables(8)
(a) Swelling behavior of the poly(DMAEMA-co-AA) hydrogels with time under different pH conditions. (b) pH dependence of the equilibrium swelling ratio (ESR) for the poly(DMAEMA-co-AA) hydrogels
The reaction route to prepare the poly(DMAEMA-co-AA) hydrogels.
Swelling kinetic in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves with the expression of ln(SR) = ln\begin{document}$ K $\end{document}+\begin{document}$ n $\end{document}ln\begin{document}$ t $\end{document}
Normalized FTIR spectra of CN stretching in the SCN- anionic probe dissolved in the poly(DMAEMA-co-AA) hydrogels with different pH. The solid lines are the fitting curves using a pseudo-Voigt function [25, 38]. The background signal of poly(DMAEMA-co-AA) without the addition of SCN- has been subtracted
(a) Vibrational relaxation for the CN stretching of the SCN- anionic probe in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves using a biexponential decay function. (b) pH dependent vibrational lifetime constants of SCN- probe in the poly(DMAEMA-co-AA) hydrogels
(a) Rotational anisotropy decay of SCN- anionic probe in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves using a biexponential decay function. (b) pH dependence of the rotational time constants of the SCN- probe in the poly(DMAEMA-co-AA) hydrogels.
  • Table 1. Swelling parameters of the poly(DMAEMA-co-AA) hydrogels under different pH conditions

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    Table 1. Swelling parameters of the poly(DMAEMA-co-AA) hydrogels under different pH conditions

  • Table 2. Rotational time constants of the SCN- anion in the poly(DMAEMA-co-AA) hydrogels under different pH conditions

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    Table 2. Rotational time constants of the SCN- anion in the poly(DMAEMA-co-AA) hydrogels under different pH conditions

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Jian Hong, De-xia Zhou, Hong-xing Hao, Min Zhao, Hong-tao Bian. Ultrafast Infrared Spectroscopic Study of Microscopic Structural Dynamics in pH Stimulus-Responsive Hydrogels[J]. Chinese Journal of Chemical Physics, 2020, 33(5): 540

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Paper Information

Received: Jun. 13, 2020

Accepted: Jul. 13, 2020

Published Online: Apr. 21, 2021

The Author Email: Bian Hong-tao (htbian@snnu.edu.cn)

DOI:10.1063/1674-0068/cjcp2006096

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