Chinese Journal of Chemical Physics, Volume. 33, Issue 5, 540(2020)
Ultrafast Infrared Spectroscopic Study of Microscopic Structural Dynamics in pH Stimulus-Responsive Hydrogels†
Fig. 1. (a) Swelling behavior of the poly(DMAEMA-co-AA) hydrogels with time under different pH conditions. (b) pH dependence of the equilibrium swelling ratio (ESR) for the poly(DMAEMA-co-AA) hydrogels
Fig. 1. The reaction route to prepare the poly(DMAEMA-co-AA) hydrogels.
Fig. 2. Swelling kinetic in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves with the expression of ln(SR) = ln
Fig. 3. Normalized FTIR spectra of CN stretching in the SCN- anionic probe dissolved in the poly(DMAEMA-co-AA) hydrogels with different pH. The solid lines are the fitting curves using a pseudo-Voigt function [25, 38]. The background signal of poly(DMAEMA-co-AA) without the addition of SCN- has been subtracted
Fig. 4. (a) Vibrational relaxation for the CN stretching of the SCN- anionic probe in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves using a biexponential decay function. (b) pH dependent vibrational lifetime constants of SCN- probe in the poly(DMAEMA-co-AA) hydrogels
Fig. 5. (a) Rotational anisotropy decay of SCN- anionic probe in the poly(DMAEMA-co-AA) hydrogels under different pH conditions. The solid lines are the fitting curves using a biexponential decay function. (b) pH dependence of the rotational time constants of the SCN- probe in the poly(DMAEMA-co-AA) hydrogels.
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Jian Hong, De-xia Zhou, Hong-xing Hao, Min Zhao, Hong-tao Bian. Ultrafast Infrared Spectroscopic Study of Microscopic Structural Dynamics in pH Stimulus-Responsive Hydrogels†[J]. Chinese Journal of Chemical Physics, 2020, 33(5): 540
Received: Jun. 13, 2020
Accepted: Jul. 13, 2020
Published Online: Apr. 21, 2021
The Author Email: Bian Hong-tao (htbian@snnu.edu.cn)