Journal of Inorganic Materials, Volume. 34, Issue 6, 590(2019)

Nb2O5 Coating on the Performance of Flexible Dye Sensitized Solar Cell Based on TiO2 Nanoarrays/Upconversion Luminescence Composite Structure

Xi-Qing LÜ... Huan-Yu ZHANG, Rui LI, Mei ZHANG and Min GUO |Show fewer author(s)
Author Affiliations
  • School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
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    Figures & Tables(12)
    Flow chart of the preparation process of flexible DSSC based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure
    (a) XRD pattern and (b) SEM image of YEF-TiO2-UCNPs; (c) UV-Vis-NIR absorption spectra of YEF-TiO2-UCNPs and P25; (d) Upconversion fluorescence spectra of YEF-TiO2-UCNPs and YE-TiO2-UCNPs, under 980 nm excitation
    EDS elemental mapping images of Ti, O, F, Er, and Yb in YEF-TiO2-UCNPs
    (a) Low and (b) high magnification SEM images of Ti mesh supported TNWAs/YEF-TiO2-UCNPs composite structure; (c) J-V curves and photovoltaic properties of DSSCs based on Ti mesh supported TNWAs/P25 and TNWAs/YEF-TiO2- UCNPs composite structures
    XRD patterns of Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure photoanodes prepared with different NbCl5 concentrations
    (a) SEM images of Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations
    J-V curves of DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations
    UV-Vis absorption spectra of dyes desorbed from corresponding sensitized Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure photoanodes prepared with different NbCl5 concentrations
    Schematic diagram of the energy levels of materials in the DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF- TiO2-UCNPs composite structure
    EIS plots of DSSCs based on Ti mesh supported Nb2O5@TNWAsYEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations: Nyquist plots of DSSCs under (a) dark and (b) illumination; (c) Bode plots of DSSCs under dark; (d) Equivalent circuit of DSSCs
    • Table 1. Photoelectric properties of DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations

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      Table 1. Photoelectric properties of DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations

      NbCl5concentration/(mmol∙L-1)Jsc/(mA·cm-2)Voc/VFFPCE/%
      012.810.740.585.54
      1013.200.760.636.29
      2013.720.780.656.89
      408.800.710.543.40
      605.320.680.471.69
    • Table 2. EIS data of DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations after fitting by equivalent circuit

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      Table 2. EIS data of DSSCs based on Ti mesh supported Nb2O5@TNWAs/YEF-TiO2-UCNPs composite structure prepared with different NbCl5 concentrations after fitting by equivalent circuit

      NbCl5concentration /(mmol∙L-1)RtrRrecηecfp/Hzτe/ms
      036.60101.50.733.7842.0
      1024.24130.20.843.0951.3
      2018.25186.90.913.0651.8
      4031.9589.120.735.5128.9
      6034.0475.560.696.6423.9
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    Xi-Qing LÜ, Huan-Yu ZHANG, Rui LI, Mei ZHANG, Min GUO. Nb2O5 Coating on the Performance of Flexible Dye Sensitized Solar Cell Based on TiO2 Nanoarrays/Upconversion Luminescence Composite Structure[J]. Journal of Inorganic Materials, 2019, 34(6): 590

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    Paper Information

    Category: RESEARCH PAPER

    Received: Sep. 6, 2018

    Accepted: --

    Published Online: Sep. 24, 2021

    The Author Email:

    DOI:10.15541/jim20180406

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