Laser & Optoelectronics Progress, Volume. 59, Issue 15, 1516017(2022)

Rare Earth Ion-Doped Tellurite Upconversion Luminescent Glass and Optical Fiber for Fluorescence Sensing Applications

Tonglei Cheng†、*, Zhiyuan Yin1、†, Wei Liu, Dianchang Song, Xin Yan, Fang Wang, and Xuenan Zhang
Author Affiliations
  • State Key Laboratory of Synthetical Automation for Process Industries, College of Information Science and Engineering, Northeastern University, Shenyang 110819, Liaoning , China
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    Figures & Tables(17)
    UC luminescence mechanism of the Er3+/Yb3+
    Preparation process of the rare earth ion-doped tellurite glass
    Rare earth ion-doped tellurite glasses fabricated by melt-annealing method
    Process of manufacturing tellurite fiber by combining suction casting method and rotational casting method
    DTA curve of Er3+/Yb3+ co-doped TWNZN glass[13]
    UC and NIR luminescence spectra of visible light region. (a) TZBE glass; (b) TZBEY glass[20]
    Absorption spectrum of co-doped TPO glass in the range of 350‒2000 nm[21]
    UC luminescence spectrum of TZLB glass excited at 980 nm; (a) Different Er3+ mole fractions; (b) different Yb3+ mole fractions
    Change curve of emission spectrum of TZLB glass with temperature
    Basic mechanism of rare earth ion glass and optical fiber optical temperature measurement[34]
    Manufacturing method of temperature-sensitive optical fiber head[35]
    Experimental setup for measuring brain and body temperature[35]
    Schematic diagram of the integrated microsphere sensing structure[37]
    Experiment setup for monitoring ammonia content in water[37]
    Schematic diagram of the all-fiber temperature sensing system[13]
    • Table 1. Properties of tellurite glasses doped with different host materials and rare earth ions

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      Table 1. Properties of tellurite glasses doped with different host materials and rare earth ions

      Glasses typeDopedPropertyRef.
      TeO2-ZnOHo3+/Pr3+long fluorescence lifetime with green,orange and red emission25
      TeO2-ZnOTm3+/Dy3+transparent in the 500‒2000 nm spectral region,strong absorption is observed in the region below 370 nm26
      TeO2-ZnO-BaOYb3+/Ho3+emission intensity is dependent on the pump power27
      TeO2-ZnO-BaOYb3+/Tm3+as Tm3+ concentration increases,each emission line turns red28
      TeO2-ZnO-BaOGd3+/Sm3+fluoresces in the orange region29
      TeO2-Ga2O3-ZnOTm3+/Ho3+strong emission of 2 µm is achieved30
      TeO2-Sb2O3-WO3Pr3+life value decreases with the increase of Pr3+ content31
      TeO2-ZnO-WO3-Bi2O3Er3+/Tm3+/Nd3+ultra-wide light emission characteristics,large signal-to-noise ratio32
      TeO2-Bi2O3-ZnO-Li2O-Nb2O5Pr3+/Yb3+exhibits RGB(Red,Green,Blue)light emission33
    • Table 2. Sensing parameters and SA of different rare earth ion-doped tellurite glasses and optical fibers

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      Table 2. Sensing parameters and SA of different rare earth ion-doped tellurite glasses and optical fibers

      Glass materialsExcitation wavelengt /nmExcitation power /mWSA /(10-4 K-1EM /cm-1Ref.
      Er3+/Yb3+∶TeO2/TiO2/Nb2O5/Al2O39800.9559@480 K66938
      Er3+/Yb3+∶TeO2/WO3980 and 80810828@690 K678.9439
      Er3+∶TeO2/ZnO975-72@429 K862.0540
      Er3+∶TeO2/ZnO/Nb2O5/BaF2476.5 or 514-72@550 K77541
      Er3+/Yb3+∶TeO2/ZnO/BaO975-67@353 K52520
      Er3+/Yb3+∶TeO2/ZnO/ZnF2/La2O3980-60@353 K74542
      Er3+/Yb3+∶TeO2/WO3/La2O3/NaO29801.486.7@553 K75519
      Er3+/Yb3+∶TeO2/ZnO/Nb976195@363 K88043
      Er3+/Yb3+∶TeO2/Lu2O3980-103@623 K86344
      Er3+/Yb3+∶TeO2/BaF2/Al2O3/ZnO/La2O3/BaO978-47.7@587.5 K78445
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    Tonglei Cheng, Zhiyuan Yin, Wei Liu, Dianchang Song, Xin Yan, Fang Wang, Xuenan Zhang. Rare Earth Ion-Doped Tellurite Upconversion Luminescent Glass and Optical Fiber for Fluorescence Sensing Applications[J]. Laser & Optoelectronics Progress, 2022, 59(15): 1516017

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    Paper Information

    Category: Materials

    Received: May. 5, 2022

    Accepted: Jun. 15, 2022

    Published Online: Jul. 27, 2022

    The Author Email: Cheng Tonglei (chengtonglei@ise.neu.edu.cn)

    DOI:10.3788/LOP202259.1516017

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