Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 2, 020201(2023)

Preparation of hydroxoxime group-modified ultra-high molecular weight polyethylene fiber adsorbent by radiation-induced graft polymerization and its application to heavy metal ions removal

Xingfang HAO1... Chunying XIAN1, Hengdong WANG2 and Li SHEN1,* |Show fewer author(s)
Author Affiliations
  • 1College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201821, China
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    Figures & Tables(8)
    Synthetic route of UHMWPE-HO fiber
    Digital images of (a) UHMWPE-PAA, (b) UHMWPE-PAM, (c) UHMWPE-P AA/NH2OH, (d) UHMWPE-PAM/NH2OH, and (e) UHMWPE-HO after adsorption of Fe(III) ions
    SEM images of (a) and (a') original UHMWPE fiber, (b) and (b') UHMWPE-HO fiber, and (c) and c') the Cu (II)-loaded UHMWPE-HO fibers: (a), (b) and (c) magnification 2 000×, (a'), (b') and (c') magnification 400×
    ATR-FTIR spectra of (a) UHMWPE, (b) UHMWPE-g-PAA, (c) (UHMWPE-g-PAA)-g-PAM, and (d) UHMWPE-HO fibers
    Thermogravimetric analysis curves of the UHMWPE, UHMWPE-g-PAA, (UHMWPE-g-PAA)-g-PAM, and UHMWPE-HO fibers: (a) TG; (b) DTG
    Effects of (a) pH, (b) reaction time, and (c) initial concentration on absorption performance of UHMWPE-HO fibers; (d) adsorption ability of UHMWPE-HO fibers at different regeneration cycles
    Effects of absorbent dosage on (a) residual concentration, and (b) removal ratio for Cu (II), Co(II), and Ni(II) ions in mixed solution
    • Table 1. AM grafted alone and AM grafted after AA onto UHMWPE

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      Table 1. AM grafted alone and AM grafted after AA onto UHMWPE

      样品Sample123456

      首次预辐照的吸收剂量 / kGy

      First absorbed dose

      20020010101010

      反应时间 / min

      Reaction time

      //608090120

      丙烯酸接枝率 / %

      Dg of AA

      //5102050

      二次预辐照的吸收剂量 / kGy

      Secondary absorbed dose

      //100100100100

      丙烯酰胺单体浓度 / %

      C0 of AM

      304030303030

      丙烯酰胺接枝率 / %

      Dg of AM

      235517225017885
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    Xingfang HAO, Chunying XIAN, Hengdong WANG, Li SHEN. Preparation of hydroxoxime group-modified ultra-high molecular weight polyethylene fiber adsorbent by radiation-induced graft polymerization and its application to heavy metal ions removal[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(2): 020201

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    Paper Information

    Category: Research Articles

    Received: Aug. 22, 2022

    Accepted: Oct. 26, 2022

    Published Online: Jul. 24, 2023

    The Author Email: SHEN Li (shenli@dhu.edu.cn)

    DOI:10.11889/j.1000-3436.2022-0088

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