Chinese Physics B, Volume. 29, Issue 10, (2020)

Exciton dynamics in different aromatic hydrocarbon systems

Milica Rutonjski, Petar Mali, Slobodan Radošević, Sonja Gombar, Milan Pantić, and Milica Pavkov-Hrvojević
Author Affiliations
  • Department of Physics, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 4, 21000 Novi Sad, Serbia
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    The exciton dispersion is examined in the case of four selected prototypical molecular solids: pentacene, tetracene, picene, and chrysene. The model parameters are determined by fitting to experimental data obtained by inelastic electron scattering. Within the picture that relies on Frenkel-type excitons we obtain that theoretical dispersion curves along different directions in the Brillouin zone are in good agreement with the experimental data, suggesting that the influence of charge-transfer excitons on exciton dispersion of the analyzed organic solids is not as large as proposed. In reciprocal space directions where Davydov splitting is observed we employ the upgraded version of Hamiltonian used in Materials11, 2219 (2018).

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    Milica Rutonjski, Petar Mali, Slobodan Radošević, Sonja Gombar, Milan Pantić, Milica Pavkov-Hrvojević. Exciton dynamics in different aromatic hydrocarbon systems[J]. Chinese Physics B, 2020, 29(10):

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    Paper Information

    Received: Apr. 14, 2020

    Accepted: --

    Published Online: Apr. 21, 2021

    The Author Email: Rutonjski Milica (milica.rutonjski@df.uns.ac.rs)

    DOI:10.1088/1674-1056/aba2de

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