<trans-title>Synthesis and Gas Separation of Chabazite Zeolite Membranes</trans-title>

Ziyi LI; Jiajia ZHANG; Xiaoqin ZOU; Jiayu ZUO; Jun LI; Yingshu LIU; David Youhong PUI

doi:10.15541/jim20200555

Journal of Inorganic Materials, Volume. 36, Issue 6, 579(2021)

Synthesis and Gas Separation of Chabazite Zeolite Membranes

Ziyi LI1... Jiajia ZHANG1, Xiaoqin ZOU2, Jiayu ZUO1, Jun LI1, Yingshu LIU1,*, and David Youhong PUI34 |Show fewer author(s)

Author Affiliations

¹1. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China

²2. Institute of Chemistry, Northeast Normal University, Changchun 130024, China

³3. School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen 518172, China

⁴4. Department of Engineering, University of Minnesota, Minneapolis 55455, USA

show less

Abstract Get PDF(in Chinese)

Figures & Tables(10)

1. Proportions of publications and structures for primary 8-membered ring zeolite members

Download full size

View in Article

2. Schematic diagrams of CHA zeolite membrane preparation methods

Download full size

View in Article

3. Summary of influences of CHA zeolite membrane synthesis conditions

Download full size

View in Article

4. Schematic diagram of gas separation mechanisms on CHA zeolite membrane before (left) and after (right) the modulation of membrane surface chemistry^{[24,36,49,83,87]}

Download full size

View in Article

5. Separation performances of different gas mixtures on CHA zeolite membranes

Download full size

View in Article

6. Performance of gas with different kinetic diameters on CHA zeolite membranes

Download full size

View in Article

Table 1. Comparison of CHA zeolite membrane synthesis methods

View table

View in Article

Table 1. Comparison of CHA zeolite membrane synthesis methods

Method	Advantage	Disadvantage	Status of use
In-situ synthesis	① Simple production equipment② Easy to use	① Low success rate② Long synthesis time③ Difficult to control	Less research, basically used for the synthesis of SAPO-34 membrane
Secondary growth	① Simple production equipment② High success rate③ Short synthesis time	① Tedious steps	More research, conducive to large-scale mass production
Microwave heating	① High success rate② Short synthesis time	① Tedious steps② High equipment cost③ High energy consumption	New method, still in basic research stage

Table 2. Summary table of preferred conditions for secondary synthesis of SSZ-13 membrane and SAPO-34 membrane

View table

View in Article

Table 2. Summary table of preferred conditions for secondary synthesis of SSZ-13 membrane and SAPO-34 membrane

Influencing factors		SSZ-13	SAPO-34
Seed conditions	Support	α-Al₂O₃, mullite	α-Al₂O₃
	Seed crystal	Ball milled nano seeds	Flake nano seeds
	Seeding method	Dip coating	Wipe, electrophoretic deposition
Hydrothermal synthesis conditions	Formula (structure directing agent, Si/Al, water content, cationic species)	Non-pure silica: 1SiO₂ : (5-100)Al₂O₃ : (0.1-0.2)NaOH : (0-0.06)KOH(Oriented growth regulation) : (0.05-0.6)TMAdaOH : (0-0.05)TEAOH : (40-120)H₂OPure silica : 1SiO₂ : (0.5-1.4)TMAdaOH : (0.5-1.4)HF : (3-6)H₂O	1Al₂O₃ : (1-2)P₂O₅ : (0.3-0.6)SiO₂ : (1-4)TEAOH : (0-1.6)DPA : (55-400)H₂O
	Temperature	160-170 ℃	180-230 ℃
	Time	24-72 h	6-30 h
Calcination conditions	Conventional calcination	400-550 ℃ (6-12 h), temperature rise and fall rate (0.2-1) ℃/min	400-480 ℃ (4-10 h), temperature rise and fall rate (0.5- 2) ℃/min
Calcination conditions	Rapid heat treatment	700-1000 ℃ (0.5-2 min)+conventional calcination	700 ℃ (1-5 min)+ conventional calcination

Table 3. Separation performances of H₂, hydrocarbon and noble gases on CHA zeolite membranes

View table

View in Article

Table 3. Separation performances of H₂, hydrocarbon and noble gases on CHA zeolite membranes

Serial number	Ref.	Thickness/μm	Temperature/℃	Pressure/MPa	Gas separation, X/Y	X permeance/ (×10^-8, mol·m^-2·s^-1·Pa^-1)	Separation selectivity, X/Y
1	Kalipcilar^[7]	10-40	25	-	H₂/n-C₄H₁₀	14	8.7
2	Zheng^[27]	10	30	0.2	C₂H₄/C₂H₆	0.29	11
3	Feng^[72]	4.3	20	0.138	Kr/Xe	12	35
4	Yang^[82]	3.7	22	-	H₂/C₃H₈	8.4	810

Table 4. Separation performances of CO₂/CH₄, CO₂/N₂, N₂/CH₄, H₂/CH₄ on CHA zeolite membranes

View table

View in Article

Table 4. Separation performances of CO₂/CH₄, CO₂/N₂, N₂/CH₄, H₂/CH₄ on CHA zeolite membranes

Serial number	Ref.	Thickness/μm	Temperature/℃	Pressure/MPa	Gas separation, X/Y	X permeance/(×10^-7, mol·m^-2·s^-1·Pa^-1)	Separation selectivity, X/Y
1	Kosinov^[14]	4-6	20	0.6	CO₂/CH₄	2.5	42
1	Kosinov^[14]	4-6	20	0.6	CO₂/N₂	2.5	12
2	Wu^[21]	6-8	20	0.27	CO₂/CH₄	2.1	178
2	Wu^[21]	6-8	20	0.27	N₂/CH₄	0.18	9
3	Song^[29]	6	25	0.2	CO₂/CH₄	5.6	56.5
3	Song^[29]	6	25	0.2	N₂/CH₄	0.89	10
4	Li^[31]	2	25	0.2	CO₂/CH₄	1.16	213
4	Li^[31]	2	25	0.2	N₂/CH₄	1.07	13
5	Yu^[57]	1.5	-24	0.9	CO₂/CH₄	79	76
6	Karakiliç^[64]	2-4	22	0.2	CO₂/CH₄	2.6	176
7	Qiu^[66]	0.44	20	0.14	CO₂/CH₄	48	153
8	Kida^[71]	-	40	0.1	CO₂/CH₄	17	54
8	Kida^[71]	-	40	0.1	H₂/CH₄	11	34
9	Tang^[81]	10	20	0.2	CO₂/CH₄	9.3	208
10	Kida^[83]	5	25	0.1	CO₂/CH₄	40	130
11	Imasaka^[98]	3	40	0.3	CO₂/CH₄	15	115
12	Maghsoudi^[99]	20	30	0.1	CO₂/CH₄	0.34	21.6
13	Yu^[100]	1.3	3	0.9	CO₂/CH₄	84	47
14	Li^[5]	5	80	0.14	CO₂/CH₄	2.0	270
15	Li^[19]	-	24	0.138	CO₂/CH₄	1.6	67
16	Carreon^[23]	-	22	0.138	CO₂/CH₄	3.8	170
17	Venna^[36]	-	22	0.138	CO₂/CH₄	5.0	245
17	Venna^[36]	-	22	0.138	CO₂/N₂	2.1	39
18	Huang^[40]	2	22	0.074	N₂/CH₄	4.93	11.3
19	Chen^[41]	2-3	25	0.1	CO₂/CH₄	1.18	160
20	Chang^[43]	-	-	4	CO₂/CH₄	6.1	88
21	Liu^[48]	3	30	0.1	CO₂/CH₄	12	95
22	Rehman^[53]	-	80	0.4	CO₂/CH₄	47.3	65
23	Liu^[55]	7-15	25	0.1	CO₂/N₂	18.5	29.8
24	Li^[74]	4-6	22	7	CO₂/CH₄	0.4	100
25	Zhang^[78]	-	20	4.6	CO₂/CH₄	8.2	55
26	Noble^[101]	-	22	0.14	CO₂/CH₄	1.2	170
27	Shi^[102]	2-4	22	0.14	CO₂/CH₄	23.2	186
28	Shi^[103]	4-5	22	0.14	CO₂/CH₄	16.8	256
29	Li^[104]	3	-	4	CO₂/CH₄	13.2	62
30	Bai^[105]	0.8	-	0.2	CO₂/CH₄	25.3	70

Tools

Get Citation

Copy Citation Text

Ziyi LI, Jiajia ZHANG, Xiaoqin ZOU, Jiayu ZUO, Jun LI, Yingshu LIU, David Youhong PUI. Synthesis and Gas Separation of Chabazite Zeolite Membranes[J]. Journal of Inorganic Materials, 2021, 36(6): 579

Download Citation

EndNote(RIS)BibTex Plain Text

Set citation alerts for article

Save article for my favorites

Paper Information

Category: REVIEW

Received: Sep. 22, 2020

Accepted: --

Published Online: Nov. 25, 2021

The Author Email: LIU Yingshu (ysliu@ustb.edu.cn)

DOI:10.15541/jim20200555

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. Comparison of CHA zeolite membrane synthesis methods

Table 1. Comparison of CHA zeolite membrane synthesis methods

Table 2. Summary table of preferred conditions for secondary synthesis of SSZ-13 membrane and SAPO-34 membrane

Table 2. Summary table of preferred conditions for secondary synthesis of SSZ-13 membrane and SAPO-34 membrane

Table 3. Separation performances of H2, hydrocarbon and noble gases on CHA zeolite membranes

Table 3. Separation performances of H2, hydrocarbon and noble gases on CHA zeolite membranes

Table 4. Separation performances of CO2/CH4, CO2/N2, N2/CH4, H2/CH4 on CHA zeolite membranes

Table 4. Separation performances of CO2/CH4, CO2/N2, N2/CH4, H2/CH4 on CHA zeolite membranes

微信扫一扫：分享

Table 3. Separation performances of H₂, hydrocarbon and noble gases on CHA zeolite membranes

Table 3. Separation performances of H₂, hydrocarbon and noble gases on CHA zeolite membranes

Table 4. Separation performances of CO₂/CH₄, CO₂/N₂, N₂/CH₄, H₂/CH₄ on CHA zeolite membranes

Table 4. Separation performances of CO₂/CH₄, CO₂/N₂, N₂/CH₄, H₂/CH₄ on CHA zeolite membranes