Quantitative Analysis of <inline-formula><math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="Mml35-1000-0593-42-6-1855"><msubsup><mrow><mi mathvariant="normal">NO</mi></mrow><mrow><mn>3</mn></mrow><mrow><mo>-</mo></mrow></msubsup></math></inline-formula>, <inline-formula><math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="Mml36-1000-0593-42-6-1855"><msubsup><mrow><mi mathvariant="normal">SO</mi></mrow><mrow><mn>4</mn></mrow><mrow><mn>2</mn><mo>-</mo></mrow></msubsup></math></inline-formula>, <inline-formula><math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="Mml37-1000-0593-42-6-1855"><msubsup><mrow><mi mathvariant="normal">ClO</mi></mrow><mrow><mn>4</mn></mrow><mrow><mo>-</mo></mrow></msubsup></math></inline-formula> With Water as Internal Standard by Raman Spectroscopy

Gan-lin WANG; Qian LIU; Ding-ming LI; Su-liang YANG; Guo-xin TIAN

doi:10.3964/j.issn.1000-0593(2022)06-1855-07

Spectroscopy and Spectral Analysis, Volume. 42, Issue 6, 1855(2022)

Quantitative Analysis of ${NO}_{3}^{-}$ , ${SO}_{4}^{2 -}$ , ${ClO}_{4}^{-}$ With Water as Internal Standard by Raman Spectroscopy

Gan-lin WANG*... Qian LIU1;, Ding-ming LI1;, Su-liang YANG1; *; and Guo-xin TIAN1; 2; *; |Show fewer author(s)

Author Affiliations

1. Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China

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Figures & Tables(8)

Fig. 1. Raman spectra of NaNO₃ (a, b), Na₂SO₄ (c, d), NaClO₄ (e, f) solutions with different

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Table 1. Working curves curve of NaNO₃, Na₂SO₄, NaClO₄
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Table 1. Working curves curve of NaNO₃, Na₂SO₄, NaClO₄
盐 A B 工作曲线 R²
NaNO₃ 18.8 0.6 c=18.8R_S/(1+0.6R_S) 0.999 1
Na₂SO₄ 20.2 1.0 c=20.2R_S/(1+1.0R_S) 0.998 8
NaClO₄ 15.0 0.7 c=15.0R_S/(1+0.7R_S) 0.999 8

Table 2. Deviation of NaNO₃ analysis results under different concentrations of NaClO₄

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Table 2. Deviation of NaNO₃ analysis results under different concentrations of NaClO₄

$c_{NaCl O_{4}}$ /(mol·L^-1)	$c_{NaN O_{3}}$ /(mol·L^-1)
	1.6		3.0		4.2		5.3		6.3
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
0.17	1.4	0.5	2.6	1.8	2.7	1.9	3.1	2.3	1.9	1.1
0.35	7.1	5.1	8.1	6.2	6.5	4.6	5.0	3.2	2.9	1.3
0.52	9.8	6.6	7.8	4.7	6.7	3.8	4.3	1.7	3.8	1.4
0.70	8.2	4.2	6.2	2.4	5.0	1.5	3.2	-0.2	5.7	2.5

Table 3. Deviation of NaClO₄ analysis results under different concentrations of NaNO₃

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Table 3. Deviation of NaClO₄ analysis results under different concentrations of NaNO₃

$c_{NaN O_{3}}$ /(mol·L^-1)	$c_{NaCl O_{4}}$ /(mol·L^-1)
	0.17		0.35		0.52		0.70
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
1.6	3.0	-1.8	3.7	-1.4	3.4	-1.6	3.7	-1.4
3.0	7.7	-1.8	9.7	-0.6	8.5	-1.5	8.4	-1.8
4.2	31.3	14.3	27.2	10.4	19.2	3.6	19.9	4.0
5.3	41.7	17.4	36.4	13.4	23.6	3.0	27.2	5.7

Table 4. Deviation of Na₂SO₄ analysis results under different concentrations of NaClO₄

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Table 4. Deviation of Na₂SO₄ analysis results under different concentrations of NaClO₄

$c_{NaCl O_{4}}$ /(mol·L^-1)	$c_{N a_{2} S O_{4}}$ /(mol·L^-1)
	0.4		0.7		1.0		1.3		1.5
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
0.20	-2.2	-3.2	-0.6	-1.5	-2.4	-3.3	-2.2	-3.1	-3.8	-4.1
0.39	-0.9	-2.8	-3.2	-5.0	-2.6	-4.4	-1.9	-3.7	4.7	2.9
0.58	-3.6	-6.3	-2.7	-5.4	-0.8	-3.6	-0.2	-2.9	-2.8	-5.4
0.76	-4.2	-7.7	-3.1	-6.6	-2.4	-6.0	-1.9	-5.5	-1.4	-4.9

Table 5. Deviation of NaClO₄ analysis results under different concentrations of Na₂SO₄

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Table 5. Deviation of NaClO₄ analysis results under different concentrations of Na₂SO₄

$c_{N a_{2} S O_{4}}$ /(mol·L^-1)	$c_{NaCl O_{4}}$ /(mol·L^-1)
	0.20		0.39		0.58		0.76
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
0.4	-4.2	-6.1	0.4	-1.6	-2.1	-4.0	-0.4	-2.2
0.7	-0.8	-4.2	-1.2	-4.4	-1.2	-4.4	0.4	-2.9
1.0	-1.9	-6.4	0.5	-4.1	0.3	-3.9	1.0	-3.6
1.3	-2.3	-8.0	0.1	-5.8	0.7	-5.3	1.6	-4.4
1.5	-2.3	-9.0	-6.2	-13.2	-0.7	-7.5	1.9	-5.3

Table 6. Deviation of Na₂SO₄ analysis results under different concentrations of NaNO₃

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Table 6. Deviation of Na₂SO₄ analysis results under different concentrations of NaNO₃

$c_{NaN O_{3}}$ /(mol·L^-1)	$c_{N a_{2} S O_{4}}$ /(mol·L^-1)
	0.4		0.7		1.0		1.3		1.6
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
0.20	-1.8	-2.4	-1.7	-2.2	-0.9	-1.5	-0.7	-1.4	-4.0	-4.6
0.49	0.2	-1.2	1.3	-2.7	-0.1	-1.5	-1.5	-2.9	-1.8	-3.2
0.78	-2.7	-4.9	4.4	1.9	-1.8	-4.1	-2.2	-4.5	-0.7	-3.0
1.03	-4.1	-6.8	-1.9	-4.8	0.1	-2.9	0.2	-2.9	-1.6	-4.6

Table 7. Deviation of NaNO₃ analysis results under different concentrations of Na₂SO₄

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Table 7. Deviation of NaNO₃ analysis results under different concentrations of Na₂SO₄

$c_{N a_{2} S O_{4}}$ /(mol·L^-1)	$c_{NaCl O_{4}}$ /(mol·L^-1)
	0.20		0.49		0.78		1.03
	(4)	(8)	(4)	(8)	(4)	(8)	(4)	(8)
0.4	19.5	17.1	14.0	11.6	3.0	1.1	4.7	2.7
0.7	20.3	16.2	9.3	5.7	7.0	3.4	3.9	0.5
1.0	25.7	19.7	13.4	8.1	2.2	-2.2	7.7	2.6
1.3	39.3	30.7	17.9	10.9	6.3	0.3	11.0	4.3
1.6	44.4	33.9	20.8	11.9	11.0	3.2	12.1	3.9

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Gan-lin WANG, Qian LIU, Ding-ming LI, Su-liang YANG, Guo-xin TIAN. Quantitative Analysis of ${NO}_{3}^{-}$ , ${SO}_{4}^{2 -}$ , ${ClO}_{4}^{-}$ With Water as Internal Standard by Raman Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2022, 42(6): 1855

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Paper Information

Category: Research Articles

Received: Apr. 29, 2021

Accepted: --

Published Online: Nov. 14, 2022

The Author Email: WANG Gan-lin (cglwang@163.com)

DOI:10.3964/j.issn.1000-0593(2022)06-1855-07

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. Working curves curve of NaNO3, Na2SO4, NaClO4

Table 1. Working curves curve of NaNO3, Na2SO4, NaClO4

Table 2. Deviation of NaNO3 analysis results under different concentrations of NaClO4

Table 2. Deviation of NaNO3 analysis results under different concentrations of NaClO4

Table 3. Deviation of NaClO4 analysis results under different concentrations of NaNO3

Table 3. Deviation of NaClO4 analysis results under different concentrations of NaNO3

Table 4. Deviation of Na2SO4 analysis results under different concentrations of NaClO4

Table 4. Deviation of Na2SO4 analysis results under different concentrations of NaClO4

Table 5. Deviation of NaClO4 analysis results under different concentrations of Na2SO4

Table 5. Deviation of NaClO4 analysis results under different concentrations of Na2SO4

Table 6. Deviation of Na2SO4 analysis results under different concentrations of NaNO3

Table 6. Deviation of Na2SO4 analysis results under different concentrations of NaNO3

Table 7. Deviation of NaNO3 analysis results under different concentrations of Na2SO4

Table 7. Deviation of NaNO3 analysis results under different concentrations of Na2SO4

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Table 1. Working curves curve of NaNO₃, Na₂SO₄, NaClO₄

Table 1. Working curves curve of NaNO₃, Na₂SO₄, NaClO₄

Table 2. Deviation of NaNO₃ analysis results under different concentrations of NaClO₄

Table 2. Deviation of NaNO₃ analysis results under different concentrations of NaClO₄

Table 3. Deviation of NaClO₄ analysis results under different concentrations of NaNO₃

Table 3. Deviation of NaClO₄ analysis results under different concentrations of NaNO₃

Table 4. Deviation of Na₂SO₄ analysis results under different concentrations of NaClO₄

Table 4. Deviation of Na₂SO₄ analysis results under different concentrations of NaClO₄

Table 5. Deviation of NaClO₄ analysis results under different concentrations of Na₂SO₄

Table 5. Deviation of NaClO₄ analysis results under different concentrations of Na₂SO₄

Table 6. Deviation of Na₂SO₄ analysis results under different concentrations of NaNO₃

Table 6. Deviation of Na₂SO₄ analysis results under different concentrations of NaNO₃

Table 7. Deviation of NaNO₃ analysis results under different concentrations of Na₂SO₄

Table 7. Deviation of NaNO₃ analysis results under different concentrations of Na₂SO₄