Spectroscopy and Spectral Analysis, Volume. 42, Issue 6, 1674(2022)

Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques

Xiang ZHU1、1; 2; *;, Chao-sheng YUAN1、1;, Xue-rui CHENG1、1;, Tao LI1、1;, Song ZHOU1、1;, Xin ZHANG1、1;, Xing-bang DONG1、1;, Yong-fu LIANG2、2;, and Zheng WANG2、2;
Author Affiliations
  • 11. College of Physics and Electronic Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
  • 22. Henan Key Laboratory of Magnetoelectronic Information Functional Materials, Zhengzhou University of Light Industry, Zhengzhou 450001, China
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    Figures & Tables(7)
    Molecular structure of [C4mim][BF4]
    Sketch of diamond anvil cell
    Fluorescence spectra of ruby
    Relation of FWHM of ruby R1 line and pressure
    Raman spectra (a) and relationship between Raman peak and pressure (b) of [C4mim][BF4]
    • Table 1. R1 line of ruby with pressure

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      Table 1. R1 line of ruby with pressure

      No.R1/nmP/GPaNo.R1/nmP/GPa
      1694.03013697.599.93
      2694.260.6214697.9110.84
      3694.471.2015698.2111.70
      4694.711.8816698.5612.71
      5694.862.2817698.9113.69
      6695.123.0018699.1514.39
      7695.574.2719699.4515.27
      8696.015.4920699.7916.25
      9696.296.2621700.2617.60
      10696.637.2222700.7018.91
      11697.098.5323701.1220.13
      12697.299.0824701.5721.43
    • Table 2. Function relations of pressure and ν(B-F) and ν(ring) at different pressure ranges

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      Table 2. Function relations of pressure and ν(B-F) and ν(ring) at different pressure ranges

      P/GPaν(B-F)ν(ring)
      峰位/cm-1)测压函数峰位/cm-1)测压函数
      0
      0.62
      1.20
      1.88
      766.9
      769.2
      771.3
      774.1
      P=-193.8+0.252 8×ν(B-F)
      (R2=0.986, μ=0.13 GPa)
      (0<P<2.28 GPa)
      1 024.7
      1 026.9
      1 028.2
      1 030.1
      P=-436.5+0.425 6×ν(ring)
      (R2=0.985, μ=0.17 GPa)
      (0<P<2.28 GP)
      2.28
      3.00
      4.27
      5.49
      775.7
      778.0
      782.0
      785.5
      P=-251.4+0.326 9×ν(B-F)
      (R2=0.999, μ=0.16 GPa)
      (2.28<P<6.26 GPa)
      1 031.1
      1 032.8
      1 035.9
      1 038.8
      P=-427.7+0.417 0×ν(ring)
      (R2=0.999, μ=0.21 GPa)
      (2.28<P<6.26 GPa)
      6.26
      7.22
      8.53
      9.08
      9.93
      10.84
      11.70
      12.71
      13.69
      788.0
      792.3
      796.2
      798.8
      801.9
      804.6
      807.8
      810.9
      813.0
      P=-224.5+0.292 6×ν(B-F)
      (R2=0.994, μ=0.15 GPa)
      (6.26<P<14.39 GP)
      1 040.8
      1 044.5
      1 047.6
      1 049.6
      1 052.0
      1 054.1
      1 056.5
      1 059.1
      1 060.7
      P=-379.0+0.369 9×ν(ring)
      (R2=0.993, μ=0.19 GPa)
      (6.26<P<14.39 GPa)
      14.39
      15.27
      16.25
      17.60
      18.91
      20.13
      21.43
      814.4
      817.4
      820.7
      822.7
      827.0
      830.1
      832.6
      P=-299.7+0.385 5×ν(B-F)
      (R2=0.991, μ=0.19 GPa)
      (14.39<P<21.43 GPa)
      1 062.0
      1 064.3
      1 066.4
      1 068.0
      1 070.8
      1 072.8
      1 074.2
      P=-596.6+0.574 9×ν(ring)
      (R2=0.988, μ=0.29 GPa)
      (14.39<P<21.43 GPa)
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    Xiang ZHU, Chao-sheng YUAN, Xue-rui CHENG, Tao LI, Song ZHOU, Xin ZHANG, Xing-bang DONG, Yong-fu LIANG, Zheng WANG. Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques[J]. Spectroscopy and Spectral Analysis, 2022, 42(6): 1674

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    Paper Information

    Category: Research Articles

    Received: Apr. 22, 2021

    Accepted: --

    Published Online: Nov. 14, 2022

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2022)06-1674-05

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