Spectroscopy and Spectral Analysis, Volume. 42, Issue 9, 2679(2022)

Research Progress in the Application of Raman Spectroscopy in Petroleum Geology

Qiang LIU1;... Shao-bo LIU1; 2;, Xue-song LU1; 2; *;, Jun-jia FAN1; 2;, Hua TIAN1; 2;, Xing-zhi MA1; 2; and Li-li GUI1; 2; |Show fewer author(s)
Author Affiliations
  • 1. PetroChina Research Institute of Petroleum Exploration and Development, Beijing 100083, China
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    Figures & Tables(7)
    Raman spectrum of water (a), Relationship between NaCl molality and intensity ratio of characteristic peaks (I3 425/I3 260) (b) (Modified according to Caumon et al.[51])
    Raman spectrum of water (a) and the relationship of RBS and different kind of organic matter maturity (b)(Data from literature[11-12, 19, 21, 104])
    Raman spectrum of single phase fluid inclusion in fluorite (a) and the relationship of CH4 (C—H symmetric stretching) band positions and pressure (b)(Data from literature [30-32, 39, 105, 107-108])
    Relationship between CH4 concentrations (mol·kg-1 H2O) and characteristic Raman peak area ration (PAR) under different temperature and salinity condtions (Modified according to literature [55-56, 59, 62])
    • Table 1. Raman peak positions of common ions and minerals in fluid inclusion[1]

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      Table 1. Raman peak positions of common ions and minerals in fluid inclusion[1]

      物质拉曼位移/cm-1
      H2O液态w1 630, vs2 750~3 900
      SO42-w450, w620, vs980
      HSO4-w890, vs1 050
      HS-, H2S2 570~2 590
      NO3-w690, vs1 049
      CO32-w684, vs1 064, m1 380
      HCO3-m1 017, vs1 360
      NH4+vs3 040
      石墨1 355, 1 580
      石英128, 206, 464
      方解石s284, mw711, vs1 085, vw1 435
      白云石s299, w725, vs1 097, vw1 443
      萤石m322, vw641
      磷灰石w428, w578, vs960, w1 026
      硬石膏mw430, w611, vs1 018, mw1 131
      石膏s494, w621, vs1 008, w1 142
    • Table 2. Raman peak positions and the relative Raman cross section coefficient (RRSCS)(Σ and σ) of common gases in fluid inclusion[77, 88]

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      Table 2. Raman peak positions and the relative Raman cross section coefficient (RRSCS)(Σ and σ) of common gases in fluid inclusion[77, 88]

      物质拉曼位移
      /cm-1
      拉曼散射截面参数
      Σσ
      (488 nm)
      σ
      (514 nm)
      σ
      (532 nm)
      σ
      (633 nm)
      SO211514.035.185.265.325.64
      12CO2ν11 2850.8
      0.63
      1
      0.79
      1.01
      0.8
      1.02
      0.81
      1.08
      0.85
      13CO2 2ν21 3701.231.511.531.541.62
      12CO2 2ν21 3881.33
      0.88
      1.51
      1.08
      1.52
      1.09
      1.54
      1.10
      1.61
      1.15
      O21 5551.03
      0.83
      1.22
      0.98
      1.23
      0.99
      1.24
      1
      1.29
      1.04
      CO2 1430.9
      0.86
      0.94
      0.9
      0.94
      0.9
      0.94
      0.9
      0.95
      0.91
      H2S2 6116.86.396.376.356.25
      异构-C4H102 880
      794
      9.62
      1.96
      8.51
      2.71
      8.44
      2.76
      8.4
      2.8
      8.14
      3.02
      n-C4H102 890
      827
      17.9
      1.34
      15.8
      1.84
      15.68
      1.88
      15.6
      1.9
      15.12
      2.05
      C3H82 908
      2 890
      870
      22.6
      20.4
      1.14
      19.87
      18
      1.55
      19.71
      17.86
      1.58
      19.6
      17.77
      1.6
      18.98
      17.22
      1.72
      CH4ν33 0204.824.134.094.063.91
      CH4ν12 9178.63
      9.94
      8.56
      7.57
      8.72
      7.51
      7.51
      8.65
      7.45
      7.47
      8.6
      7.4
      7.22
      5.32
      7.16
      1 5350.090.090.10.10.1
      C2H62 954
      2 914
      993
      15
      17.3
      0.88
      13
      15.21
      1.17
      12.89
      15.09
      1.19
      12.81
      15
      1.2
      12.37
      14.52
      1.29
      NH33 3346.4
      6.32
      5.1
      5.03
      5.03
      4.96
      4.98
      4.91
      4.7
      4.63
      H2O3 6573.292.432.382.352.17
      H24 1563.54
      6.24
      4
      2.32
      4.09
      2.62
      2.26
      3.98
      2.55
      2.21
      3.9
      2.5
      1.98
      3.49
      2.24
    • Table 3. Main applications of Raman spectroscopy in petroleum geology research

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      Table 3. Main applications of Raman spectroscopy in petroleum geology research

      地质应用研究对象应用拉曼参数参考文献或应用实例
      矿物与流
      体包裹体
      分析
      岩矿鉴定矿物拉曼位移常见矿物数据库[1]、 矿物鉴定[86]、 流体包裹体二维与三维重构[84]
      流体包裹体组分分析气体、 溶质、 烃类、 子矿物拉曼位移、 拉曼特征峰强度或面积比值气体组成[1, 77]、 阴离子类型与含量[1, 42, 45, 48-49, 51, 53]、 阳离子类型与含量[43, 89]、 烃类[24, 25]
      水-岩相互作用过程矿物、 溶质拉曼位移、 拉曼特征峰强度比或面积比天然气水合物形成与分解[90,91]、 石英相变[6]、 碳酸盐岩溶蚀与沉淀作用[92]
      同位素研究气体、 离子、 矿物拉曼特征峰强度或面积比值CO2中C同位素[69]
      有机质成熟度沉积有机质、 干酪根、 煤、 沥青G-FWHM、 RBS、 R1、 D-FWHM、 半高宽比(D-FWHM /G-FWHM)、 D峰或G峰峰位沉积有机质[93]、 煤[11]、 沥青[12]、 笔石[14]、 干酪根[15]等成熟度
      流体包裹体压力恢复矿物、 溶液、 液烃类拉曼位移变化量石英[6]、 水[94]、 离子[95, 96]、 液态烃[97]
      气体拉曼位移变化量CO2[3738], CH4[39]
      气体溶解度拉曼特征峰强度比或面积比值CH4溶解度[62,63], CO2溶解度[64]
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    Qiang LIU, Shao-bo LIU, Xue-song LU, Jun-jia FAN, Hua TIAN, Xing-zhi MA, Li-li GUI. Research Progress in the Application of Raman Spectroscopy in Petroleum Geology[J]. Spectroscopy and Spectral Analysis, 2022, 42(9): 2679

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    Paper Information

    Category: Research Articles

    Received: Aug. 13, 2021

    Accepted: Dec. 27, 2021

    Published Online: Nov. 17, 2022

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2022)09-2679-10

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