Spectroscopy and Spectral Analysis, Volume. 42, Issue 10, 3046(2022)

Pressure-Induced Phase and Isomer Transition of Dicyandiamide

Yu-rui TAO*, Hong-bo WANG*;, Hai-hua WANG*;, and Mi ZHOU*;
Author Affiliations
  • College of Physics, Jilin University, Changchun 130012, China
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    Figures & Tables(8)
    Crystal structure of dicyandiamide
    Raman spectrum of dicyandiamide
    Isomers structures of dicyandiamide(a): Imino form ; (b): Amino form
    High-pressure Raman spectra of dicyandiamide (0~2 300 cm-1)
    Raman spectra of dicyandiamide at 3 000~3 800 cm-1
    Plots for frequency-pressure relationships
    Intensity ratio-pressure curve of dicyandiamide (amino form to imino form)Iν1: Amino form; Iν2: Imino form
    • Table 1. Raman frequency and assignments of dicyandiamide

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      Table 1. Raman frequency and assignments of dicyandiamide

      频率/cm-1谱线归属
      150$\beta(C_1 \equiv N_2)$,β(N—H)
      502β(N—H)
      524$\beta(N_3 - C_1 \equiv N_2)$, β(N—H)
      669β(N5—H)
      934$\beta(C_4=N_3 - C_1)$
      1 097β(N6—H)
      1 527$v(C_4 = N_3)$,β(N—H)
      2 157$v(C_1 \equiv N_2)$
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    Yu-rui TAO, Hong-bo WANG, Hai-hua WANG, Mi ZHOU. Pressure-Induced Phase and Isomer Transition of Dicyandiamide[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3046

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    Paper Information

    Category: Research Articles

    Received: Sep. 28, 2021

    Accepted: Dec. 24, 2021

    Published Online: Nov. 23, 2022

    The Author Email: TAO Yu-rui (784396053@qq.com)

    DOI:10.3964/j.issn.1000-0593(2022)10-3046-06

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