Spectroscopy and Spectral Analysis, Volume. 41, Issue 2, 454(2021)

Determination of Sodium Hexametaphosphate by Ratiometric Fluorescence Method Based on Formaldehyde Functionalized Polyethyleneimine/Eosin Y System

Chuan-xiao YANG*, Wei-bin GONG, Fan TANG, and Xiang-ying SUN
Author Affiliations
  • College of Materials Sciences and Engineering, Huaqiao University, Xiamen 361021, China
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    Figures & Tables(12)
    Scheme of the reaction between FPEI/EY and SHMP
    UV-Vis absorption and Fluorescence emission spectra of FPEI under different excitation wavelengths
    Fluorescence spectra of the reaction between FPEI/EY (a) and SHMP (b) Concentration: EY: 4.0 μmol·L-1; FPEI, 1.0 mL; pH 3.93; λex=340 nm
    FTIR spectra of FPEI (a) and absorption spectra of the reaction between FPEI/EY and SHMP (b)
    Effect of excitation wavelength on the fluorescence intensityFPEI: 1.0 mL; EY: 4 μmol·L-1; pH 3.93
    Effect of pH on the reaction between FPEI/EY and SHMPFPEI: 1.0 mL; EY: 4 μmol·L-1; SHMP: 4 μmol·L-1; λex=340 nm
    Effect of formaldehyde on the fluorescence increasing of EY by SHMPFPEI: 1.0 mL; EY: 4 μmol·L-1; SHMP: 2.4 μmol·L-1; pH 3.93
    Effect of EY on the reaction between FPEI/EY and SHMPFPEI: 1.0 mL; EY: 4 μmol·L-1; SHMP: 2.4 μmol·L-1; λex=340 nm; pH 3.93
    Plots of fluorescence intensity at 540 nm and F540/F470via the concentrations of SHMPFPEI: 1.0 mL; pH 3.93, λex=340 nm
    • Table 1. Effect of EY on analytical parameters for determination

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      Table 1. Effect of EY on analytical parameters for determination

      cEY/
      (μmol·L-1)
      线性方程(c, μmol·L-1)线性范围(c,
      μmol·L-1)
      R2
      2.0F540/F470=0.49+0.18c0.2~3.60.993 8
      3.0F540/F470=0.63+0.27c0.1~3.60.989 4
      4.0F540/F470=0.82+0.30c0.1~4.20.995 3
      5.0F540/F470=0.86+0.32c0.1~4.20.989 3
      6.0F540/F470=0.99+0.36c0.1~4.20.991 9
    • Table 2. Analytical parameters for determination

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      Table 2. Analytical parameters for determination

      方法线性方程(c, μmol·L-1)线性范围(c, μmol·L-1)R2检出限(3σ, nmol·L-1)
      比率荧光F540/F470=0.82+0.30c0.1~4.20.995 438
      单荧光F540=243.2+81.3c0.1~3.60.988 346
    • Table 3. Results for the determination of SHMP in drink samples

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      Table 3. Results for the determination of SHMP in drink samples

      样品测得量/(μmol·L-1)SHMP加入量/(μmol·L-1)测得值/(μmol·L-1)回收率/%
      12.380.202.59105.0
      21.480.602.13108.3
      31.760.201.9595.0
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    Chuan-xiao YANG, Wei-bin GONG, Fan TANG, Xiang-ying SUN. Determination of Sodium Hexametaphosphate by Ratiometric Fluorescence Method Based on Formaldehyde Functionalized Polyethyleneimine/Eosin Y System[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 454

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    Paper Information

    Category: Research Articles

    Received: Mar. 20, 2016

    Accepted: Dec. 6, 2016

    Published Online: Apr. 8, 2021

    The Author Email: YANG Chuan-xiao (cxyang@hqu.edu.cn)

    DOI:10.3964/j.issn.1000-0593(2021)02-0454-06

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