[1] [1] Zhang S Y, Wojtas L, Zaworotko M J. Structural insight into guest binding sites in a porous homochiral metal-organic material［J］.J.Am.Chem.Soc.,2015,137: 12045-12049.

[2] [2] Lun D J, Waterhouse G I N, Telfer S G. A general thermolabile protecting group strategy for organocatalytic metal-organic frameworks［J］.J.Am.Chem.Soc.,2011,133: 5806-5809.

[3] [3] Yang Y, Pei X L, Wang Q M. Postclustering dynamic covalent modification for chirality control and chiral sensing［J］.J.Am.Chem.Soc.,2013,135: 16184-16191.

[4] [4] Wang C, Zhang T, Lin W B. Rational synthesis of noncentrosymmetric metal-organic frameworks for second-order nonlinear optics［J］.Chem.Rev.,2012,112: 1084-1104.

[5] [5] Zhang W, Xiong R G. Ferroelectric metal-organic frameworks［J］.Chem.Rev.,2012,112: 1163-1195.

[6] [6] Song B Q, Chen D Q, Ji Z G, et al. Control of bulk homochirality and proton conductivity in isostructural chiral metal-organic frameworks［J］.Chem.Commun.,2017,53: 1892-1895.

[7] [7] Yu Y D, Luo C, Liu B Y, et al. Spontaneous symmetry breaking of Co(ii) metal-organic frameworks from achiral precursors via asymmetrical crystallization［J］.Chem.Commun.,2015,51: 14489-14492.

[8] [8] Han Y H, Liu Y C, Xing X S, et al. Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange［J］.Chem.Commun.,2015,51: 14481-14484.

[9] [9] Yang X J, Bao S S, Zheng T, et al. An enantioenriched vanadium phosphonate generated via asymmetric chiral amplification of crystallization from achiral sources showing a single-crystal-to-single-crystal dehydration process［J］.Chem.Commun.,2012,48: 6565-6567.

[10] [10] Lin Z J, Slawin A M Z, Morris R E. Chiral induction in the ionothermal synthesis of a 3-D coordination polymer［J］.J.Am.Chem.Soc.,2007,129: 4880-4881.

[11] [11] Zhang S Y, Li D, Guo D, et al. Synthesis of a chiral crystal form of MOF-5, CMOF-5, by chiral induction［J］.J.Am.Chem.Soc.,2015,137: 15406-15409.

[12] [12] Kowalczyk D, Albrecht . An organocatalytic biomimetic approach to α-aminophosphonates［J］.Chem.Commun.,2015,51: 3981-3984.

[13] [13] Hou S Z, Cao D K, Li Y Z, et al. Chiral layered metal phosphonate formed via spontaneous resolution showing dehydration-induced antiferromagnetic to ferromagnetic transformation［J］.Inorg.Chem.,2008,47: 10211-10213.

[14] [14] Liu X G, Bao S S, Zheng L M. Polymorphism of homochiral zinc phosphonates［J］.Inorg.Chem.,2008,47: 5525-5527.

[15] [15] Liu X G, Zhou K, Dong J, et al. Homochiral lanthanide phosphonates with brick-wall shaped layer structures showing chiroptical and catalytical properties［J］. Inorg.Chem.,2009,48(5): 1901-1905.

[16] [16] Liu X G, Huang J, Bao S S, et al. Homochiral zinc phosphonates with layered and open framework structures using polycarboxylate as second linkers［J］.Dalton Trans.,2009,9837-9842.

[17] [17] Cai Z S, Bao S S, Ren M, et al. Homochiral cobalt phosphonates containing delta-type chains showing tunable interlayer distance and field-induced phase transition［J］.Chem.Eur.J.,2014,20: 17137-17142.

[18] [18] Liu X G, Bao S S, Huang J, et al. Homochiral metal phosphonate nanotubes［J］.Chem.Commun.2015,51: 15141-15144.

[19] [19] Feng J S, Bao S S, Ren M, et al. Chirality- and pH-controlled supramolecular isomerism in metal phosphonates［J］.Chem.Eur.J.,2015,21: 17336-17343.

[20] [20] Liu M, Feng J S, Bao S S, et al. Formation mechanism and reversible expansion and shrinkage of Mg-based homochiral metal-organic nanotubes［J］.Chem.Eur.J.,2017,23: 1086-1092.

[21] [21] Huang J, Ding H M, Xu Y, et al. Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers［J］.Nat.Commun.,2017,8: 2131-2144.

[22] [22] Xu Y, Huang X D, Bao S S, et al. Homochiral erbium coordination polymers: salt-assisted conversion from triple to quadruple helices［J］.Cryst. Growth Des.,2018,18: 4045-4053.

[23] [23] Xu Y, Yu Y S, Huang X D, et al. Counter-anion modulated crystal growth and function of one-dimensional homochiral coordination polymers: morphology, structures and magnetic properties［J］.Inorg.Chem.,2018,57: 12143-12154.

[24] [24] SAINT.Program for data extraction and reduction;Siemens analytical X-ray instruments,Madison,WI,1994-1996.

[25] [25] SHELXTL (version 5.0). Reference manual; siemens industrial automation, analytical instruments: Madison,WI,1995.