Journal of Inorganic Materials, Volume. 37, Issue 10, 1123(2022)

Mechanism of Mg-codoping in Improving the Time Performance of Gd3(Al,Ga)5O12:Ce Scintillator

Mingqing LI1...2, Linwei WANG2, Dongzhou DING2,* and He FENG1 |Show fewer author(s)
Author Affiliations
  • 11. School of Material Science and Engineering, Shanghai University, Shanghai 200444, China
  • 22. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
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    Figures & Tables(10)
    Photos of Gd3Al2.3Ga2.7O12:Ce,Mg crystals
    Transmission spectra of Gd3Al2.3Ga2.7O12:Ce, Mg crystals
    Energy spectra (a) and scintillation decay curves (b) of Mg co-doped GAGG:Ce crystals
    Schematic diagram of the scintillating procedure
    Absorption spectra (a) and PL excitation spectra (b) of GAGG:Ce,Mg crystals
    Concentration of antisite defect LuAl in single crystal LuAG:Ce vs Ce3+ concentration
    Schematic of the structure near the dodecahedral site (a), and the distortion of dodecahedral and octahedral sites caused by Ce doping (b)
    X-ray excited luminescence spectra of GAGG:Ce,Mg crystals with the inset showing the GdAl/Ga-related emission peak
    • Table 1. Relative light yield and scintillation decay time values of the Mg co-doped GAGG:Ce crystals. Scintillation decay is approximated by a single-exponential function

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      Table 1. Relative light yield and scintillation decay time values of the Mg co-doped GAGG:Ce crystals. Scintillation decay is approximated by a single-exponential function

      SampleLight yield/%Decay time/ns
      Mg-0100128.01
      Mg-190.191.79
      Mg-368.867.06
    • Table 2. Ionic radii of the cations (coordination number: 6[20])

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      Table 2. Ionic radii of the cations (coordination number: 6[20])

      CationIonic radii/nmCationIonic radii/nm
      Gd3+0.0938Na+0.1020
      Al3+0.0535Be2+0.0450
      Ga3+0.0620Mg2+0.0720
      Li+0.0760Ca2+0.1000
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    Mingqing LI, Linwei WANG, Dongzhou DING, He FENG. Mechanism of Mg-codoping in Improving the Time Performance of Gd3(Al,Ga)5O12:Ce Scintillator [J]. Journal of Inorganic Materials, 2022, 37(10): 1123

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Dec. 29, 2021

    Accepted: --

    Published Online: Jan. 12, 2023

    The Author Email: DING Dongzhou (dongzhou_ding@mail.sic.ac.cn)

    DOI:10.15541/jim20210804

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