High-Entropy Electrode Materials: Synthesis, Properties and Outlook

Dongxiao Li; Chang Liu; Shusheng Tao; Jieming Cai; Biao Zhong; Jie Li; Wentao Deng; Hongshuai Hou; Guoqiang Zou; Xiaobo Ji

doi:10.1007/s40820-024-01504-3

Nano-Micro Letters, Volume. 17, Issue 1, 022(2025)

High-Entropy Electrode Materials: Synthesis, Properties and Outlook

Dongxiao Li1... Chang Liu2,*, Shusheng Tao1, Jieming Cai1, Biao Zhong1, Jie Li1, Wentao Deng1, Hongshuai Hou1, Guoqiang Zou1,** and Xiaobo Ji1 |Show fewer author(s)

Author Affiliations

¹College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China

²School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, People’s Republic of China

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References(231)

[1] [1] Y.S. Meng, Introduction: beyond Li-ion battery chemistry. Chem. Rev. 120, 6327 (2020). 10.1021/acs.chemrev.0c00412

[2] [2] P.R. Vasudeva Rao, Materials for nuclear industry: some historical perspectives. J. Chem. Sci. 131, 97 (2019). 10.1007/s12039-019-1669-7

[3] [3] M.A. Little, A.I. Cooper, The chemistry of porous organic molecular materials. Adv. Funct. Mater. 30, 1909842 (2020). 10.1002/adfm.201909842

[4] [4] X. Zhou, W.-S. Lee, M. Imada, N. Trivedi, P. Phillips et al., High-temperature superconductivity. Nat. Rev. Phys. 3, 462–465 (2021). 10.1038/s42254-021-00324-3

[5] [5] E.P. George, D. Raabe, R.O. Ritchie, High-entropy alloys. Nat. Rev. Mater. 4, 515–534 (2019). 10.1038/s41578-019-0121-4

[6] [6] C. Oses, C. Toher, S. Curtarolo, High-entropy ceramics. Nat. Rev. Mater. 5, 295–309 (2020). 10.1038/s41578-019-0170-8

[7] [7] G. Pacchioni, High-entropy materials go nano. Nat. Rev. Mater. 7, 156 (2022). 10.1038/s41578-022-00429-w

[8] [8] C. Lu, X. Zhang, X. Chen, Advanced materials and technologies toward carbon neutrality. Acc. Mater. Res. 3, 913–921 (2022). 10.1021/accountsmr.2c00084

[9] [9] B. Lei, G.-R. Li, P. Chen, X.-P. Gao, A solar rechargeable battery based on hydrogen storage mechanism in dual-phase electrolyte. Nano Energy 38, 257–262 (2017). 10.1016/j.nanoen.2017.06.001

[10] [10] J. Nowotny, C. Sorrell, L. Sheppard, T. Bak, Solar-hydrogen: Environmentally safe fuel for the future. Int. J. Hydrog. Energy 30, 521–544 (2005). 10.1016/j.ijhydene.2004.06.012

[11] [11] W. Chen, G. Li, A. Pei, Y. Li, L. Liao et al., A manganese–hydrogen battery with potential for grid-scale energy storage. Nat. Energy 3, 428–435 (2018). 10.1038/s41560-018-0147-7

[12] [12] H. Lee, O. Gwon, C. Lim, J. Kim, O. Galindev et al., Advanced electrochemical properties of PrBa0.5Sr0.5Co1.9Ni0.1O5+δ as a bifunctional catalyst for rechargeable zinc-air batteries. ChemElectroChem 6, 3154–3159 (2019). 10.1002/celc.201900633

[13] [13] D.R. Egan, C. Ponce de León, R.J.K. Wood, R.L. Jones, K.R. Stokes et al., Developments in electrode materials and electrolytes for aluminium–air batteries. J. Power. Sources 236, 293–310 (2013). 10.1016/j.jpowsour.2013.01.141

[14] [14] S.R. Narayanan, G.K.S. Prakash, A. Manohar, B. Yang, S. Malkhandi et al., Materials challenges and technical approaches for realizing inexpensive and robust iron–air batteries for large-scale energy storage. Solid State Ion. 216, 105–109 (2012). 10.1016/j.ssi.2011.12.002

[15] [15] C. Lim, C. Kim, O. Gwon, H.Y. Jeong, H.-K. Song et al., Nano-perovskite oxide prepared via inverse microemulsion mediated synthesis for catalyst of lithium-air batteries. Electrochim. Acta 275, 248–255 (2018). 10.1016/j.electacta.2018.04.121

[16] [16] S.S. Shinde, J.Y. Jung, N.K. Wagh, C.H. Lee, D.-H. Kim et al., Ampere-hour-scale zinc–air pouch cells. Nat. Energy 6, 592–604 (2021). 10.1038/s41560-021-00807-8

[17] [17] G. Wang, J. Chang, S. Koul, A. Kushima, Y. Yang, CO2 bubble-assisted Pt exposure in PtFeNi porous film for high-performance zinc-air battery. J. Am. Chem. Soc. 143, 11595–11601 (2021). 10.1021/jacs.1c04339

[18] [18] R. Xiao, J. Chen, K. Fu, X. Zheng, T. Wang et al., Hydrolysis batteries: generating electrical energy during hydrogen absorption. Angew. Chem. Int. Ed. 57, 2219–2223 (2018). 10.1002/anie.201711666

[19] [19] C. Zhang, Y. Yang, X. Liu, M. Mao, K. Li et al., Mobile energy storage technologies for boosting carbon neutrality. Innov. Camb 4, 100518 (2023). 10.1016/j.xinn.2023.100518

[20] [20] E. Pomerantseva, F. Bonaccorso, X. Feng, Y. Cui, Y. Gogotsi, Energy storage: The future enabled by nanomaterials. Science 366, eaan8285 (2019). 10.1126/science.aan8285

[21] [21] Z. Hu, Z. Song, Z. Huang, S. Tao, B. Song et al., Reconstructing hydrogen bond network enables high voltage aqueous zinc-ion supercapacitors. Angew. Chem. Int. Ed. 62, e202309601 (2023). 10.1002/anie.202309601

[22] [22] N.T. Aristote, K. Zou, A. Di, W. Deng, B. Wang et al., Methods of improving the initial Coulombic efficiency and rate performance of both anode and cathode materials for sodium-ion batteries. Chin. Chem. Lett. 33, 730–742 (2022). 10.1016/j.cclet.2021.08.049

[23] [23] L. Tian, Z. Li, P. Wang, X. Zhai, X. Wang et al., Carbon quantum dots for advanced electrocatalysis. J. Energy Chem. 55, 279–294 (2021). 10.1016/j.jechem.2020.06.057

[24] [24] G. Zhao, G. Zou, H. Hou, P. Ge, X. Cao et al., Sulfur-doped carbon employing biomass-activated carbon as a carrier with enhanced sodium storage behavior. J. Mater. Chem. A 5, 24353–24360 (2017). 10.1039/c7ta07860a

[25] [25] S. Li, Z. Luo, H. Tu, H. Zhang, W. Deng et al., N, S-codoped carbon dots as deposition regulating electrolyte additive for stable lithium metal anode. Energy Storage Mater. 42, 679–686 (2021). 10.1016/j.ensm.2021.08.008

[26] [26] Y. Cai, X. Chen, Y. Xu, Y. Zhang, H. Liu et al., Ti3C2Tx MXene/carbon composites for advanced supercapacitors: Synthesis, progress, and perspectives. Carbon Energy 6, e501 (2024). 10.1002/cey2.501

[27] [27] W. Fan, Q. Wang, K. Rong, Y. Shi, W. Peng et al., MXene enhanced 3D needled waste denim felt for high-performance flexible supercapacitors. Nano-Micro Lett. 16, 36 (2023). 10.1007/s40820-023-01226-y

[28] [28] G. Zou, H. Hou, P. Ge, Z. Huang, G. Zhao et al., Metal–organic framework-derived materials for sodium energy storage. Small 14, 1702648 (2018). 10.1002/smll.201702648

[29] [29] X. Xiao, X. Deng, Y. Tian, S. Tao, Z. Song et al., Ultrathin two-dimensional nanosheet metal-organic frameworks with high-density ligand active sites for advanced lithium-ion capacitors. Nano Energy 103, 107797 (2022). 10.1016/j.nanoen.2022.107797

[30] [30] Z. Cao, H. Zhang, B. Song, D. Xiong, S. Tao et al., Angstrom-level ionic sieve 2D-MOF membrane for high power aqueous zinc anode. Adv. Funct. Mater. 33, 2300339 (2023). 10.1002/adfm.202300339

[31] [31] D. Xiong, L. Yang, Z. Cao, F. Li, W. Deng et al., In situ construction of high-density solid electrolyte interphase from MOFs for advanced Zn metal anodes. Adv. Funct. Mater. 33, 2301530 (2023). 10.1002/adfm.202301530

[32] [32] T.B. Schon, B.T. McAllister, P.-F. Li, D.S. Seferos, The Rise of organic electrode materials for energy storage. Chem. Soc. Rev. 45, 6345–6404 (2016). 10.1039/c6cs00173d

[33] [33] Z. Song, G. Zhang, X. Deng, K. Zou, X. Xiao et al., Ultra-low-dose pre-metallation strategy served for commercial metal-ion capacitors. Nano-Micro Lett. 14, 53 (2022). 10.1007/s40820-022-00792-x

[34] [34] J. Ma, J. Qin, S. Zheng, Y. Fu, L. Chi et al., Hierarchically structured Nb2O5 microflowers with enhanced capacity and fast-charging capability for flexible planar sodium ion micro-supercapacitors. Nano-Micro Lett. 16, 67 (2024). 10.1007/s40820-023-01281-5

[35] [35] X. Deng, K. Zou, R. Momen, P. Cai, J. Chen et al., High content anion (S/Se/P) doping assisted by defect engineering with fast charge transfer kinetics for high-performance sodium ion capacitors. Sci. Bull. 66, 1858–1868 (2021). 10.1016/j.scib.2021.04.042

[36] [36] Y. Zhu, W. Zhong, W. Chen, Z. Hu, Y. Xie et al., Crystallographic types depended energy storage mechanism for zinc storage. Nano Energy 125, 109524 (2024). 10.1016/j.nanoen.2024.109524

[37] [37] Z. Song, G. Zhang, X. Deng, Y. Tian, X. Xiao et al., Strongly coupled interfacial engineering inspired by robotic arms enable high-performance sodium-ion capacitors. Adv. Funct. Mater. 32, 2205453 (2022). 10.1002/adfm.202205453

[38] [38] L. Yang, M. Liu, Y. Xiang, W. Deng, G. Zou et al., Carbon skeleton confined Sb chalcogenides nanodots for stable sodium storage. Carbon 197, 341–349 (2022). 10.1016/j.carbon.2022.06.043

[39] [39] S. Tao, J. Cai, Z. Cao, B. Song, W. Deng et al., Revealing the valence evolution of metal element in heterostructures for ultra-high power Li-ion capacitors. Adv. Energy Mater. 13, 2301653 (2023). 10.1002/aenm.202301653

[40] [40] I.S. Kim, M.J. Pellin, A.B.F. Martinson, Acid-compatible halide perovskite photocathodes utilizing atomic layer deposited TiO2 for solar-driven hydrogen evolution. ACS Energy Lett. 4, 293–298 (2019). 10.1021/acsenergylett.8b01661

[41] [41] H. Su, S. Jaffer, H. Yu, Transition metal oxides for sodium-ion batteries. Energy Storage Mater. 5, 116–131 (2016). 10.1016/j.ensm.2016.06.005

[42] [42] X. Pu, K. Yang, Z. Pan, C. Song, Y. Lai et al., Extending the solid solution range of sodium ferric pyrophosphate: off-stoichiometric Na3Fe2.5(P2O7)2 as a novel cathode for sodium-ion batteries. Carbon Energy 6, e449 (2024). 10.1002/cey2.449

[43] [43] Y. Wang, H. Li, S. Di, B. Zhai, P. Niu et al., Constructing long-cycling crystalline C3N4-based carbonaceous anodes for sodium-ion battery via N configuration control. Carbon Energy 6, e388 (2024). 10.1002/cey2.388

[44] [44] S.-J. Kwon, T.-H. Han, T.Y. Ko, N. Li, Y. Kim et al., Extremely stable graphene electrodes doped with macromolecular acid. Nat. Commun. 9, 2037 (2018). 10.1038/s41467-018-04385-4

[45] [45] P. Dong, Z. Xu, X. Ma, Y. Gu, J. Zhang et al., Simple preparation of monolithic N-doped electrode for efficient EF remediation of petrochemical wastewater: performance, degradation pathways, and mechanism of different N-doped positions. Chem. Eng. J. 473, 145237 (2023). 10.1016/j.cej.2023.145237

[46] [46] F. Wang, J.Y. Cheong, Q. He, G. Duan, S. He et al., Phosphorus-doped thick carbon electrode for high-energy density and long-life supercapacitors. Chem. Eng. J. 414, 128767 (2021). 10.1016/j.cej.2021.128767

[47] [47] W. Liu, X. Wang, J. Qu, X. Liu, Z. Zhang et al., Tuning Ni dopant concentration to enable co-deposited superhydrophilic self-standing Mo2C electrode for high-efficient hydrogen evolution reaction. Appl. Catal. B Environ. Energy 307, 121201 (2022). 10.1016/j.apcatb.2022.121201

[48] [48] G. Liang, Z. Wu, C. Didier, W. Zhang, J. Cuan et al., A long cycle-life high-voltage spinel lithium-ion battery electrode achieved by site-selective doping. Angew. Chem. Int. Ed. 59, 10594–10602 (2020). 10.1002/anie.202001454

[49] [49] Y. Tian, M. Ju, Y. Luo, X. Bin, X. Lou et al., In situ oxygen doped Ti3C2Tx MXene flexible film as supercapacitor electrode. Chem. Eng. J. 446, 137451 (2022). 10.1016/j.cej.2022.137451

[50] [50] Y. Xiang, X. Hu, X. Zhong, W. Deng, G. Zou et al., Mechanism of fast storage of Li/Na in complex Sb-based hybrid system. Adv. Funct. Mater. 34, 2311478 (2024). 10.1002/adfm.202311478

[51] [51] X. Xiao, X. Duan, Z. Song, X. Deng, W. Deng et al., High-throughput production of cheap mineral-based heterostructures for high power sodium ion capacitors. Adv. Funct. Mater. 32, 2110476 (2022). 10.1002/adfm.202110476

[52] [52] A. Wang, W. Hong, L. Li, R. Guo, Y. Xiang et al., Hierarchical bismuth composite for fast lithium storage: carbon dots tuned interfacial interaction. Energy Storage Mater. 44, 145–155 (2022). 10.1016/j.ensm.2021.10.019

[53] [53] W. Zhou, Y. Tang, X. Zhang, S. Zhang, H. Xue et al., MOF derived metal oxide composites and their applications in energy storage. Coord. Chem. Rev. 477, 214949 (2023). 10.1016/j.ccr.2022.214949

[54] [54] X. Zhong, J. Duan, Y. Xiang, X. Hu, Y. Huang et al., Constructing rich interfacial structure by carbon dots to improve the sodium storage capacity of Sb/C composite. Adv. Funct. Mater. 33, 2306574 (2023). 10.1002/adfm.202306574

[55] [55] C. Liu, Z. Song, X. Deng, S. Xu, R. Zheng et al., Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chin. Chem. Lett. 35, 109081 (2024). 10.1016/j.cclet.2023.109081

[56] [56] C. Liu, B. Wang, Z. Song, X. Xiao, Z. Cao et al., Enabling electron delocalization by conductor heterostructure for highly reversible sodium storage. Adv. Funct. Mater. 34, 2312905 (2024). 10.1002/adfm.202312905

[57] [57] L. Cao, S. Fang, B. Xu, B. Zhang, C. Wang et al., Enabling reversible reaction by uniform distribution of heterogeneous intermediates on defect-rich SnSSe/C layered heterostructure for ultralong-cycling sodium storage. Small 18, e2202134 (2022). 10.1002/smll.202202134

[58] [58] Y. Gao, S. Liang, B. Liu, C. Jiang, C. Xu et al., Subtle tuning of nanodefects actuates highly efficient electrocatalytic oxidation. Nat. Commun. 14, 2059 (2023). 10.1038/s41467-023-37676-6

[59] [59] C. Fu, T. Wu, G. Sun, G. Yin, C. Wang et al., Dual-defect enhanced piezocatalytic performance of C3N5 for multifunctional applications. Appl. Catal. B Environ. 323, 122196 (2023). 10.1016/j.apcatb.2022.122196

[60] [60] S. Wu, Y. Yang, M. Sun, T. Zhang, S. Huang et al., Dilute aqueous-aprotic electrolyte towards robust Zn-ion hybrid supercapacitor with high operation voltage and long lifespan. Nano-Micro Lett. 16, 161 (2024). 10.1007/s40820-024-01372-x

[61] [61] X.-Y. Feng, W.-T. Wu, Q.-Q. Huang, Y.-C. Liu, C. Ni et al., Medium entropy stabilized disordered LiNi0.5Mn1.5O4 cathode with enhanced electrochemical performance. J. Alloys Compd. 948, 169768 (2023). 10.1016/j.jallcom.2023.169768

[62] [62] W. Wang, W. Song, Y. Li, Y. Guo, K. Yang et al., Mesocrystallinely stabilized lithium storage in high-entropy oxides. Nano Energy 124, 109482 (2024). 10.1016/j.nanoen.2024.109482

[63] [63] F. Qian, L. Peng, D. Cao, W. Jiang, C. Hu et al., Asymmetric active sites originate from high-entropy metal selenides by joule heating to boost electrocatalytic water oxidation. Joule (2024). 10.1016/j.joule.2024.06.004

[64] [64] H. Zheng, Y. Liu, Z. Ma, E. Debroye, J. Ye et al., High-entropy perovskite oxides as a family of electrocatalysts for efficient and selective nitrogen oxidation. ACS Nano 18, 17642–17650 (2024). 10.1021/acsnano.4c02231

[65] [65] Z. Xia, Y. Zhang, X. Xiong, J. Cui, Z. Liu et al., Realizing B-site high-entropy air electrode for superior reversible solid oxide cells. Appl. Catal. B Environ. Energy 357, 124314 (2024). 10.1016/j.apcatb.2024.124314

[66] [66] J.-W. Yeh, S.-K. Chen, S.-J. Lin, J.-Y. Gan, T.-S. Chin et al., Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299–303 (2004). 10.1002/adem.200300567

[67] [67] Y.F. Ye, Q. Wang, J. Lu, C.T. Liu, Y. Yang, High-entropy alloy: challenges and prospects. Mater. Today 19, 349–362 (2016). 10.1016/j.mattod.2015.11.026

[68] [68] Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen et al., Microstructures and properties of high-entropy alloys. Prog. Mater. Sci. 61, 1–93 (2014). 10.1016/j.pmatsci.2013.10.001

[69] [69] C.M. Rost, E. Sachet, T. Borman, A. Moballegh, E.C. Dickey et al., Entropy-stabilized oxides. Nat. Commun. 6, 8485 (2015). 10.1038/ncomms9485

[70] [70] J. Baek, M.D. Hossain, P. Mukherjee, J. Lee, K.T. Winther et al., Synergistic effects of mixing and strain in high entropy spinel oxides for oxygen evolution reaction. Nat. Commun. 14, 5936 (2023). 10.1038/s41467-023-41359-7

[71] [71] D. Liu, Y. Liu, P. Huang, C. Zhu, Z. Kang et al., Highly tunable heterojunctions from multimetallic sulfide nanoparticles and silver nanowires. Angew. Chem. Int. Ed. 57, 5374–5378 (2018). 10.1002/anie.201800848

[72] [72] Z. Du, C. Wu, Y. Chen, Z. Cao, R. Hu et al., High-entropy atomic layers of transition-metal carbides (MXenes). Adv. Mater. 33, 2101473 (2021). 10.1002/adma.202101473

[73] [73] W. Xu, H. Chen, K. Jie, Z. Yang, T. Li et al., Entropy-driven mechanochemical synthesis of polymetallic zeolitic imidazolate frameworks for CO2 fixation. Angew. Chem. Int. Ed. 58, 5018–5022 (2019). 10.1002/anie.201900787

[74] [74] Z. Deng, A. Olvera, J. Casamento, J.S. Lopez, L. Williams et al., Semiconducting high-entropy chalcogenide alloys with ambi-ionic entropy stabilization and ambipolar doping. Chem. Mater. 32, 6070–6077 (2020). 10.1021/acs.chemmater.0c01555

[75] [75] S.K. Nemani, B. Zhang, B.C. Wyatt, Z.D. Hood, S. Manna et al., High-entropy 2D carbide MXenes: TiVNbMoC3 and TiVCrMoC3. ACS Nano 15, 12815–12825 (2021). 10.1021/acsnano.1c02775

[76] [76] H.-J. Qiu, G. Fang, Y. Wen, P. Liu, G. Xie et al., Nanoporous high-entropy alloys for highly stable and efficient catalysts. J. Mater. Chem. A 7, 6499–6506 (2019). 10.1039/c9ta00505f

[77] [77] G. Fang, J. Gao, J. Lv, H. Jia, H. Li et al., Multi-component nanoporous alloy/(oxy)hydroxide for bifunctional oxygen electrocatalysis and rechargeable Zn-air batteries. Appl. Catal. B Environ. 268, 118431 (2020). 10.1016/j.apcatb.2019.118431

[78] [78] Z.-X. Cai, H. Goou, Y. Ito, T. Tokunaga, M. Miyauchi et al., Nanoporous ultra-high-entropy alloys containing fourteen elements for water splitting electrocatalysis. Chem. Sci. 12, 11306–11315 (2021). 10.1039/D1SC01981C

[79] [79] P. Zhou, D. Liu, Y. Chen, M. Chen, Y. Liu et al., Corrosion engineering boosting bulk Fe50Mn30Co10Cr10 high-entropy alloy as high-efficient alkaline oxygen evolution reaction electrocatalyst. J. Mater. Sci. Technol. 109, 267–275 (2022). 10.1016/j.jmst.2021.09.003

[80] [80] Y. Wang, B. Yu, M. He, Z. Zhai, K. Yin et al., Eutectic-derived high-entropy nanoporous nanowires for efficient and stable water-to-hydrogen conversion. Nano Res. 15, 4820–4826 (2022). 10.1007/s12274-021-4059-7

[81] [81] L. Tao, M. Sun, Y. Zhou, M. Luo, F. Lv et al., A general synthetic method for high-entropy alloy subnanometer ribbons. J. Am. Chem. Soc. 144, 10582–10590 (2022). 10.1021/jacs.2c03544

[82] [82] R. Li, X. Liu, W. Liu, Z. Li, K.C. Chan et al., Design of hierarchical porosity via manipulating chemical and microstructural complexities in high-entropy alloys for efficient water electrolysis. Adv. Sci. 9, e2105808 (2022). 10.1002/advs.202105808

[83] [83] H. Li, Y. Han, H. Zhao, W. Qi, D. Zhang et al., Fast site-to-site electron transfer of high-entropy alloy nanocatalyst driving redox electrocatalysis. Nat. Commun. 11, 5437 (2020). 10.1038/s41467-020-19277-9

[84] [84] H. Li, M. Sun, Y. Pan, J. Xiong, H. Du et al., The self-complementary effect through strong orbital coupling in ultrathin high-entropy alloy nanowires boosting pH-universal multifunctional electrocatalysis. Appl. Catal. B Environ. 312, 121431 (2022). 10.1016/j.apcatb.2022.121431

[85] [85] D. Zhang, Y. Shi, H. Zhao, W. Qi, X. Chen et al., The facile oil-phase synthesis of a multi-site synergistic high-entropy alloy to promote the alkaline hydrogen evolution reaction. J. Mater. Chem. A 9, 889–893 (2021). 10.1039/d0ta10574k

[86] [86] Y. Kang, O. Cretu, J. Kikkawa, K. Kimoto, H. Nara et al., Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites. Nat. Commun. 14, 4182 (2023). 10.1038/s41467-023-39157-2

[87] [87] Z. Chen, J. Wen, C. Wang, X. Kang, Convex cube-shaped Pt34 Fe5 Ni20 Cu31 Mo9 Ru high entropy alloy catalysts toward high-performance multifunctional electrocatalysis. Small 18, e2204255 (2022). 10.1002/smll.202204255

[88] [88] W. Chen, S. Luo, M. Sun, X. Wu, Y. Zhou et al., High-entropy intermetallic PtRhBiSnSb nanoplates for highly efficient alcohol oxidation electrocatalysis. Adv. Mater. 34, e2206276 (2022). 10.1002/adma.202206276

[89] [89] G. Feng, F. Ning, J. Song, H. Shang, K. Zhang et al., Sub-2 nm ultrasmall high-entropy alloy nanoparticles for extremely superior electrocatalytic hydrogen evolution. J. Am. Chem. Soc. 143, 17117–17127 (2021). 10.1021/jacs.1c07643

[90] [90] M. Li, C. Huang, H. Yang, Y. Wang, X. Song et al., Programmable synthesis of high-entropy nanoalloys for efficient ethanol oxidation reaction. ACS Nano 17, 13659–13671 (2023). 10.1021/acsnano.3c02762

[91] [91] X. Wang, Q. Peng, X. Zhang, X. Lv, X. Wang et al., Carbonaceous-assisted confinement synthesis of refractory high-entropy alloy nanocomposites and their application for seawater electrolysis. J. Colloid Interface Sci. 607, 1580–1588 (2022). 10.1016/j.jcis.2021.08.201

[92] [92] L. Banko, E.B. Tetteh, A. Kostka, T.H. Piotrowiak, O.A. Krysiak et al., Microscale combinatorial libraries for the discovery of high-entropy materials. Adv. Mater. 35, e2207635 (2023). 10.1002/adma.202207635

[93] [93] Y. Yao, Z. Huang, P. Xie, S.D. Lacey, R.J. Jacob et al., Carbothermal shock synthesis of high-entropy-alloy nanoparticles. Science 359, 1489–1494 (2018). 10.1126/science.aan5412

[94] [94] Z. Qiu, Y. Li, Y. Gao, Z. Meng, Y. Sun et al., 2D MOF-assisted Pyrolysis-displacement-alloying synthesis of high-entropy alloy nanoparticles library for efficient electrocatalytic hydrogen oxidation. Angew. Chem. Int. Ed. 62, 2306881 (2023). 10.1002/anie.202306881

[95] [95] T.X. Nguyen, J. Patra, J.-K. Chang, J.-M. Ting, High entropy spinel oxide nanoparticles for superior lithiation–delithiation performance. J. Mater. Chem. A 8, 18963–18973 (2020). 10.1039/d0ta04844e

[96] [96] D. Wang, S. Jiang, C. Duan, J. Mao, Y. Dong et al., Spinel-structured high entropy oxide (FeCoNiCrMn)3O4 as anode towards superior lithium storage performance. J. Alloys Compd. 844, 156158 (2020). 10.1016/j.jallcom.2020.156158

[97] [97] H.-Z. Xiang, H.-X. Xie, Y.-X. Chen, H. Zhang, A. Mao et al., Porous spinel-type (Al0.2CoCrFeMnNi)0.58O4-δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries. J. Mater. Sci. 56, 8127–8142 (2021). 10.1007/s10853-021-05805-5

[98] [98] C. Duan, K. Tian, X. Li, D. Wang, H. Sun et al., New spinel high-entropy oxides (FeCoNiCrMnXLi)3O4 (X = Cu, Mg, Zn) as the anode material for lithium-ion batteries. Ceram. Int. 47, 32025–32032 (2021). 10.1016/j.ceramint.2021.08.091

[99] [99] Y. Zheng, X. Wu, X. Lan, R. Hu, A spinel (FeNiCrMnMgAl)3O4 high entropy oxide as a cycling stable anode material for Li-ion batteries. Processes 10, 49 (2021). 10.3390/pr10010049

[100] [100] C. Liu, J. Bi, L. Xie, X. Gao, J. Rong, High entropy spinel oxides (CrFeMnNiCox)3O4 (x = 2, 3, 4) nanoparticles as anode material towards electrochemical properties. J. Energy Storage 71, 108211 (2023). 10.1016/j.est.2023.108211

[101] [101] C. Liu, J. Bi, L. Xie, X. Gao, L. Meng, Electrochemical properties of four novel high-entropy spinel oxides used as lithium-ion battery anodes synthesized by the glycine-nitrate scs method. J. Mater. Sci. 58, 8005–8021 (2023). 10.1007/s10853-023-08498-0

[102] [102] C. Liu, J. Bi, L. Xie, X. Gao, L. Meng, Preparation and electrochemical properties of two novel high entropy spinel oxides (MgTiZnNiFe)3O4 and (CoTiZnNiFe)3O4 by solid state reaction. Mater. Today Commun. 35, 106315 (2023). 10.1016/j.mtcomm.2023.106315

[103] [103] Z. Sun, Y. Zhao, C. Sun, Q. Ni, C. Wang et al., High entropy spinel-structure oxide for electrochemical application. Chem. Eng. J. 431, 133448 (2022). 10.1016/j.cej.2021.133448

[104] [104] B. Xiao, G. Wu, T. Wang, Z. Wei, Y. Sui et al., High-entropy oxides as advanced anode materials for long-life lithium-ion Batteries. Nano Energy 95, 106962 (2022). 10.1016/j.nanoen.2022.106962

[105] [105] J. Yan, D. Wang, X. Zhang, J. Li, Q. Du et al., A high-entropy perovskite titanate lithium-ion battery anode. J. Mater. Sci. 55, 6942–6951 (2020). 10.1007/s10853-020-04482-0

[106] [106] P. Zhou, Z. Che, J. Liu, J. Zhou, X. Wu et al., High-entropy P2/O3 biphasic cathode materials for wide-temperature rechargeable sodium-ion batteries. Energy Storage Mater. 57, 618–627 (2023). 10.1016/j.ensm.2023.03.007

[107] [107] C. Zhao, F. Ding, Y. Lu, L. Chen, Y.-S. Hu, High-entropy layered oxide cathodes for sodium-ion batteries. Angew. Chem. Int. Ed. 59, 264–269 (2020). 10.1002/anie.201912171

[108] [108] X. Liu, Y. Xing, K. Xu, H. Zhang, M. Gong et al., Kinetically accelerated lithium storage in high-entropy (LiMgCoNiCuZn)O enabled by oxygen vacancies. Small 18, e2200524 (2022). 10.1002/smll.202200524

[109] [109] L. Li, P. Ji, C. Geng, Y. Li, L. Meng et al., Facile synthesis of high-entropy (Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)3O4 nanopowders and their electrochemical properties as supercapacitor electrode. J. Energy Storage 73, 109182 (2023). 10.1016/j.est.2023.109182

[110] [110] D. Ma, B. Grabowski, F. Körmann, J. Neugebauer, D. Raabe, Ab initio thermodynamics of the CoCrFeMnNi high entropy alloy: Importance of entropy contributions beyond the configurational one. Acta Mater. 100, 90–97 (2015). 10.1016/j.actamat.2015.08.050

[111] [111] V.A. Mints, J.K. Pedersen, A. Bagger, J. Quinson, A.S. Anker et al., Exploring the composition space of high-entropy alloy nanoparticles for the electrocatalytic H2/CO oxidation with Bayesian optimization. ACS Catal. 12, 11263–11271 (2022). 10.1021/acscatal.2c02563

[112] [112] J.-W. Yeh, Recent progress in high-entropy alloys. Ann. Chim. Sci. Mat. 31, 633–648 (2006). 10.3166/acsm.31.633-648

[113] [113] C.-J. Tong, M.-R. Chen, J.-W. Yeh, S.-J. Lin, S.-K. Chen et al., Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 1263–1271 (2005). 10.1007/s11661-005-0218-9

[114] [114] M.-R. Chen, S.-J. Lin, J.-W. Yeh, M.-H. Chuang, S.-K. Chen et al., Effect of vanadium addition on the microstructure, hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metall. Mater. Trans. A 37, 1363–1369 (2006). 10.1007/s11661-006-0081-3

[115] [115] C.-J. Tong, Y.-L. Chen, J.-W. Yeh, S.-J. Lin, S.-K. Chen et al., Microstructure characterization of Alx CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall. Mater. Trans. A 36, 881–893 (2005). 10.1007/s11661-005-0283-0

[116] [116] T. Yang, S. Xia, S. Liu, C. Wang, S. Liu et al., Effects of AL addition on microstructure and mechanical properties of AlxCoCrFeNi High-entropy alloy. Mater. Sci. Eng. A 648, 15–22 (2015). 10.1016/j.msea.2015.09.034

[117] [117] M.-R. Chen, S.-J. Lin, J.-W. Yeh, S.-K. Chen, Y.-S. Huang et al., Microstructure and properties of Al0.5CoCrCuFeNiTix (x=0–2.0) high-entropy alloys. Mater. Trans. 47, 1395–1401 (2006). 10.2320/matertrans.47.1395

[118] [118] W.H. Liu, J.Y. He, H.L. Huang, H. Wang, Z.P. Lu et al., Effects of Nb additions on the microstructure and mechanical property of CoCrFeNi high-entropy alloys. Intermetallics 60, 1–8 (2015). 10.1016/j.intermet.2015.01.004

[119] [119] W. Wu, L. Jiang, H. Jiang, X. Pan, Z. Cao et al., Phase evolution and properties of Al2CrFeNiMox High-entropy alloys coatings by laser cladding. J. Therm. Spray Technol. 24, 1333–1340 (2015). 10.1007/s11666-015-0303-6

[120] [120] Y.-J. Hsu, W.-C. Chiang, J.-K. Wu, Corrosion behavior of FeCoNiCrCux high-entropy alloys in 3.5% sodium chloride solution. Mater. Chem. Phys. 92, 112–117 (2005). 10.1016/j.matchemphys.2005.01.001

[121] [121] C.P. Lee, Y.Y. Chen, C.Y. Hsu, J.W. Yeh, H.C. Shih, The effect of boron on the corrosion resistance of the high entropy alloys Al0.5CoCrCuFeNiBx. J. Electrochem. Soc. 154, C424 (2007). 10.1149/1.2744133

[122] [122] C.P. Lee, Y.Y. Chen, C.Y. Hsu, J.W. Yeh, H.C. Shih, Enhancing pitting corrosion resistance of AlxCrFe1.5MnNi0.5 high-entropy alloys by anodic treatment in sulfuric acid. Thin Solid Films 517, 1301–1305 (2008). 10.1016/j.tsf.2008.06.014

[123] [123] Y.L. Chou, J.W. Yeh, H.C. Shih, The effect of molybdenum on the corrosion behaviour of the high-entropy alloys Co1.5CrFeNi1.5Ti0.5Mox in aqueous environments. Corros. Sci. 52, 2571–2581 (2010). 10.1016/j.corsci.2010.04.004

[124] [124] F.J. Wang, Y. Zhang, Effect of Co addition on crystal structure and mechanical properties of Ti0.5CrFeNiAlCo high entropy alloy. Mater. Sci. Eng. A 496, 214–216 (2008). 10.1016/j.msea.2008.05.020

[125] [125] S.F. Zhao, Y. Shao, X. Liu, N. Chen, H.Y. Ding et al., Pseudo-quinary Ti20Zr20Hf20Be20(Cu20-xNix) high entropy bulk metallic glasses with large glass forming ability. Mater. Des. 87, 625–631 (2015). 10.1016/j.matdes.2015.08.067

[126] [126] Y.-S. Huang, L. Chen, H.-W. Lui, M.-H. Cai, J.-W. Yeh, Microstructure, hardness, resistivity and thermal stability of sputtered oxide films of AlCoCrCu0.5NiFe high-entropy alloy. Mater. Sci. Eng. A 457, 77–83 (2007). 10.1016/j.msea.2006.12.001

[127] [127] Z. An, H. Jia, Y. Wu, P.D. Rack, A.D. Patchen et al., Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter deposition. Mater. Res. Lett. 3, 203–209 (2015). 10.1080/21663831.2015.1048904

[128] [128] T.-W. Lu, C.-S. Feng, Z. Wang, K.-W. Liao, Z.-Y. Liu et al., Microstructures and mechanical properties of CoCrFeNiAl0.3 high-entropy alloy thin films by pulsed laser deposition. Appl. Surf. Sci. 494, 72–79 (2019). 10.1016/j.apsusc.2019.07.186

[129] [129] C.-Z. Yao, P. Zhang, M. Liu, G.-R. Li, J.-Q. Ye et al., Electrochemical preparation and magnetic study of Bi–Fe–Co–Ni–Mn high entropy alloy. Electrochim. Acta 53, 8359–8365 (2008). 10.1016/j.electacta.2008.06.036

[130] [130] V. Soare, M. Burada, I. Constantin, D. Mitrică, V. Bădiliţă et al., Electrochemical deposition and microstructural characterization of AlCrFeMnNi and AlCrCuFeMnNi high entropy alloy thin films. Appl. Surf. Sci. 358, 533–539 (2015). 10.1016/j.apsusc.2015.07.142

[131] [131] W.-B. Liao, Z.-X. Wu, W. Lu, M. He, T. Wang et al., Microstructures and mechanical properties of CoCrFeNiMn high-entropy alloy coatings by detonation spraying. Intermetallics 132, 107138 (2021). 10.1016/j.intermet.2021.107138

[132] [132] T.A.A. Batchelor, J.K. Pedersen, S.H. Winther, I.E. Castelli, K.W. Jacobsen et al., High-entropy alloys as a discovery platform for electrocatalysis. Joule 3, 834–845 (2019). 10.1016/j.joule.2018.12.015

[133] [133] T.A.A. Batchelor, T. Löffler, B. Xiao, O.A. Krysiak, V. Strotkötter et al., Complex-solid-solution electrocatalyst discovery by computational prediction and high-throughput experimentation. Angew. Chem. Int. Ed. 60, 6932–6937 (2021). 10.1002/anie.202014374

[134] [134] T. Yu, Y. Zhang, Y. Hu, K. Hu, X. Lin et al., Twelve-component free-standing nanoporous high-entropy alloys for multifunctional electrocatalysis. ACS Mater. Lett. 4, 181–189 (2022). 10.1021/acsmaterialslett.1c00762

[135] [135] Q. Sang, S. Hao, J. Han, Y. Ding, Dealloyed nanoporous materials for electrochemical energy conversion and storage. EnergyChem 4, 100069 (2022). 10.1016/j.enchem.2022.100069

[136] [136] H. Xu, R. Hu, Y. Zhang, H. Yan, Q. Zhu et al., Nano high-entropy alloy with strong affinity driving fast polysulfide conversion towards stable lithium sulfur batteries. Energy Storage Mater. 43, 212–220 (2021). 10.1016/j.ensm.2021.09.003

[137] [137] Y. Chida, T. Tomimori, T. Ebata, N. Taguchi, T. Ioroi et al., Experimental study platform for electrocatalysis of atomic-level controlled high-entropy alloy surfaces. Nat. Commun. 14, 4492 (2023). 10.1038/s41467-023-40246-5

[138] [138] M. Fu, X. Ma, K. Zhao, X. Li, D. Su, High-entropy materials for energy-related applications. iScience 24, 102177 (2021). 10.1016/j.isci.2021.102177

[139] [139] Y. Xu, X. Xu, L. Bi, A high-entropy spinel ceramic oxide as the cathode for proton-conducting solid oxide fuel cells. J. Adv. Ceramics 11, 794–804 (2022). 10.1007/s40145-022-0573-7

[140] [140] A. Sarkar, C. Loho, L. Velasco, T. Thomas, S.S. Bhattacharya et al., Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency. Dalton Trans. 46, 12167–12176 (2017). 10.1039/c7dt02077e

[141] [141] A. Esmaeilzaei, J. Vahdati Khaki, S.A. Sajjadi, S. Mollazadeh, Synthesis and crystallization of (Co, Cr, Fe, Mn, Ni)3O4 high entropy oxide: The role of fuel and fuel-to-oxidizer ratio. J. Solid State Chem. 321, 123912 (2023). 10.1016/j.jssc.2023.123912

[142] [142] X. Yang, H. Wang, Y. Song, K. Liu, T. Huang et al., Low-temperature synthesis of a porous high-entropy transition-metal oxide as an anode for high-performance lithium-ion batteries. ACS Appl. Mater. Interfaces 14, 26873–26881 (2022). 10.1021/acsami.2c07576

[143] [143] B. Cheng, H. Lou, A. Sarkar, Z. Zeng, F. Zhang et al., Lattice distortion and stability of (Co0.2Cu0.2Mg0.2Ni0.2Zn0.2)O high-entropy oxide under high pressure. Mater. Today Adv. 8, 100102 (2020). 10.1016/j.mtadv.2020.100102

[144] [144] M. Biesuz, J. Chen, M. Bortolotti, G. Speranza, V. Esposito et al., Ni-free high-entropy rock salt oxides with Li superionic conductivity. J. Mater. Chem. A 10, 23603–23616 (2022). 10.1039/d2ta06101e

[145] [145] L. Su, J. Ren, T. Lu, K. Chen, J. Ouyang et al., Deciphering structural origins of highly reversible lithium storage in high entropy oxides with in situ transmission electron microscopy. Adv. Mater. 35, e2205751 (2023). 10.1002/adma.202205751

[146] [146] H. He, P. Kou, Z. Zhang, D. Wang, R. Zheng et al., Coupling high entropy oxide with hollow carbon spheres by rapid microwave solvothermal strategy for boosting oxygen evolution reaction. J. Colloid Interface Sci. 653, 179–188 (2024). 10.1016/j.jcis.2023.09.063

[147] [147] H. Wu, Q. Lu, Y. Li, J. Wang, Y. Li et al., Rapid joule-heating synthesis for manufacturing high-entropy oxides as efficient electrocatalysts. Nano Lett. 22, 6492–6500 (2022). 10.1021/acs.nanolett.2c01147

[148] [148] K. Wang, W. Hua, X. Huang, D. Stenzel, J. Wang et al., Synergy of cations in high entropy oxide lithium ion battery anode. Nat. Commun. 14, 1487 (2023). 10.1038/s41467-023-37034-6

[149] [149] R.-Z. Zhang, F. Gucci, H. Zhu, K. Chen, M.J. Reece, Data-driven design of ecofriendly thermoelectric high-entropy sulfides. Inorg. Chem. 57, 13027–13033 (2018). 10.1021/acs.inorgchem.8b02379

[150] [150] B. Jiang, Y. Yu, J. Cui, X. Liu, L. Xie et al., High-entropy-stabilized chalcogenides with high thermoelectric performance. Science 371, 830–834 (2021). 10.1126/science.abe1292

[151] [151] L. Hu, Y. Zhang, H. Wu, J. Li, Y. Li et al., Entropy engineering of SnTe: multi-principal-element alloying leading to ultralow lattice thermal conductivity and state-of-the-art thermoelectric performance. Adv. Energy Mater. 8, 1802116 (2018). 10.1002/aenm.201802116

[152] [152] Y.-J. Liao, W.-W. Shen, C.-B. Chang, H.-Y. Tuan, High-entropy transition metal disulfide colloid clusters: synergistic atomic scale interaction and interconnected network for ultra-stable potassium ion storage. Chem. Eng. J. 469, 143942 (2023). 10.1016/j.cej.2023.143942

[153] [153] Y. Li, J. Li, M. Wang, Y. Liu, H. Cui, High rate performance and stabilized cycle life of Co2+-doped nickel sulfide nanosheets synthesized by a scalable method of solid-state reaction. Chem. Eng. J. 366, 33–40 (2019). 10.1016/j.cej.2019.02.066

[154] [154] B.C. Steimle, J.L. Fenton, R.E. Schaak, Rational construction of a scalable heterostructured nanorod megalibrary. Science 367, 418–424 (2020). 10.1126/science.aaz1172

[155] [155] L. Zhou, M.K. Tufail, L. Yang, N. Ahmad, R. Chen et al., Cathode-doped sulfide electrolyte strategy for boosting all-solid-state lithium batteries. Chem. Eng. J. 391, 123529 (2020). 10.1016/j.cej.2019.123529

[156] [156] Z. Jiang, H. Peng, Y. Liu, Z. Li, Y. Zhong et al., A versatile Li6.5In0.25P0.75S5I sulfide electrolyte triggered by ultimate-energy mechanical alloying for all-solid-state lithium metal batteries. Adv. Energy Mater. 11, 2101521 (2021). 10.1002/aenm.202101521

[157] [157] F. Li, Y. Ma, H. Wu, Q. Zhai, J. Zhao et al., Sub-3-nm high-entropy metal sulfide nanoparticles with synergistic effects as promising electrocatalysts for enhanced oxygen evolution reaction. J. Phys. Chem. C 126, 18323–18332 (2022). 10.1021/acs.jpcc.2c05666

[158] [158] L. Lin, Z. Ding, G. Karkera, T. Diemant, M.V. Kante et al., High-entropy sulfides as highly effective catalysts for the oxygen evolution reaction. Small Struct. 4, 2370023 (2023). 10.1002/sstr.202370023

[159] [159] T.X. Nguyen, Y.-H. Su, C.-C. Lin, J.-M. Ting, Self-reconstruction of sulfate-containing high entropy sulfide for exceptionally high-performance oxygen evolution reaction electrocatalyst. Adv. Funct. Mater. 31, 2106229 (2021). 10.1002/adfm.202106229

[160] [160] Y. Xu, L. Wang, Z. Shi, N. Su, C. Li et al., Peroxide-mediated selective conversion of biomass polysaccharides over high entropy sulfides via solar energy catalysis. Energy Environ. Sci. 16, 1531–1539 (2023). 10.1039/d2ee03357g

[161] [161] M. Cui, C. Yang, B. Li, Q. Dong, M. Wu et al., High-entropy metal sulfide nanoparticles promise high-performance oxygen evolution reaction. Adv. Energy Mater. 11, 2002887 (2021). 10.1002/aenm.202002887

[162] [162] P. Wang, G. Wang, K. Chen, W. Pan, L. Yi et al., High-power hybrid alkali-acid fuel cell for synchronous glycerol valorization implemented by high-entropy sulfide electrocatalyst. Nano Energy 118, 108992 (2023). 10.1016/j.nanoen.2023.108992

[163] [163] H. Yao, Y. Wang, Y. Zheng, X. Yu, J. Ge et al., High-entropy selenides: a new platform for highly selective oxidation of glycerol to formate and energy-saving hydrogen evolution in alkali-acid hybrid electrolytic cell. Nano Res. 16, 10832–10839 (2023). 10.1007/s12274-023-5842-4

[164] [164] Z. Jiang, Y. Yuan, L. Tan, M. Li, K. Peng, Self-reconstruction of (CoNiFeCuCr)Se high-entropy selenide for efficient oxygen evolution reaction. Appl. Surf. Sci. 627, 157282 (2023). 10.1016/j.apsusc.2023.157282

[165] [165] W. Cheng, J. Liu, J. Hu, W. Peng, G. Niu et al., Pressure-stabilized high-entropy (FeCoNiCuRu)S2 sulfide anode toward simultaneously fast and durable lithium/sodium ion storage. Small 19, e2301915 (2023). 10.1002/smll.202301915

[166] [166] C.R. McCormick, R.E. Schaak, Simultaneous multication exchange pathway to high-entropy metal sulfide nanoparticles. J. Am. Chem. Soc. 143, 1017–1023 (2021). 10.1021/jacs.0c11384

[167] [167] J. Zhao, Y. Zhang, X. Chen, G. Sun, X. Yang et al., Entropy-change driven highly reversible sodium storage for conversion-type sulfide. Adv. Funct. Mater. 32, 2206531 (2022). 10.1002/adfm.202206531

[168] [168] J. Cavin, A. Ahmadiparidari, L. Majidi, A.S. Thind, S.N. Misal et al., 2D high-entropy transition metal dichalcogenides for carbon dioxide electrocatalysis. Adv. Mater. 33, e2100347 (2021). 10.1002/adma.202100347

[169] [169] P.-W. Chien, C.-B. Chang, H.-Y. Tuan, High-entropy two-dimensional metal phosphorus trichalcogenides boost high-performance potassium ion storage devices via electrochemical reconstruction. Energy Storage Mater. 61, 102853 (2023). 10.1016/j.ensm.2023.102853

[170] [170] C.-B. Chang, Y.-R. Lu, H.-Y. Tuan, High-entropy NaCl-type metal chalcogenides as K-ion storage materials: role of the cocktail effect. Energy Storage Mater. 59, 102770 (2023). 10.1016/j.ensm.2023.102770

[171] [171] Y. Lei, L. Zhang, W. Xu, C. Xiong, W. Chen et al., Carbon-supported high-entropy Co–Zn–Cd–Cu–Mn sulfide nanoarrays promise high-performance overall water splitting. Nano Res. 15, 6054–6061 (2022). 10.1007/s12274-022-4304-8

[172] [172] Y. Lee, J. Jeong, H.J. Lee, M. Kim, D. Han et al., Lithium argyrodite sulfide electrolytes with high ionic conductivity and air stability for all-solid-state Li-ion batteries. ACS Energy Lett. 7, 171–179 (2022). 10.1021/acsenergylett.1c02428

[173] [173] Z. Zhao, H. Zheng, S. Liu, J. Shen, W. Song et al., Low temperature synthesis of chromium carbide (Cr3C2) nanopowders by a novel precursor method. Int. J. Refract. Met. Hard Mater. 48, 46–50 (2015). 10.1016/j.ijrmhm.2014.07.026

[174] [174] D. Fray, C. Schwandt, Aspects of the application of electrochemistry to the extraction of titanium and its applications. Mater. Trans. 58, 306–312 (2017). 10.2320/matertrans.mk201619

[175] [175] G.Z. Chen, Interactions of molten salts with cathode products in the FFC Cambridge Process. Int. J. Miner. Metall. Mater. 27, 1572–1587 (2020). 10.1007/s12613-020-2202-1

[176] [176] Y. Li, J. Lu, M. Li, K. Chang, X. Zha et al., Multielemental single–atom-thick A layers in nanolaminated V2(Sn, A) C (A = Fe Co, Ni, Mn) for tailoring magnetic properties. Proc. Natl. Acad. Sci. U.S.A. 117, 820–825 (2020). 10.1073/pnas.1916256117

[177] [177] J. Sure, D. Sri Maha Vishnu, H.-K. Kim, C. Schwandt, Facile electrochemical synthesis of nanoscale (TiNbTaZrHf)C high-entropy carbide powder. Angew. Chem. Int. Ed. 59, 11830–11835 (2020). 10.1002/anie.202003530

[178] [178] Y. Yang, B. Chen, J. Chen, L. Hu, M. Hu, Preparation of (VNbTaZrHf)C high-entropy carbide nanoparticles via electro-deoxidation in molten salt and their supercapacitive behaviour. Can. Metall. Q. 61, 389–397 (2022). 10.1080/00084433.2022.2058151

[179] [179] S. Niu, Z. Yang, F. Qi, Y. Han, Z. Shi et al., Electrical discharge induced bulk-to-nanoparticle transformation: nano high-entropy carbide as catalysts for hydrogen evolution reaction. Adv. Funct. Mater. 32, 2203787 (2022). 10.1002/adfm.202203787

[180] [180] W. Ma, M. Wang, Q. Yi, D. Huang, J. Dang et al., A new Ti2V0.9Cr0.1C2Tx MXene with ultrahigh gravimetric capacitance. Nano Energy 96, 107129 (2022). 10.1016/j.nanoen.2022.107129

[181] [181] J. Sun, B. Liu, Q. Zhao, C.H. Kirk, J. Wang, MAX, MXene, or MX: what are they and which one is better? Adv. Mater. 35, 2306072 (2023). 10.1002/adma.202306072

[182] [182] T.J. Harrington, J. Gild, P. Sarker, C. Toher, C.M. Rost et al., Phase stability and mechanical properties of novel high entropy transition metal carbides. Acta Mater. 166, 271–280 (2019). 10.1016/j.actamat.2018.12.054

[183] [183] J. Zhou, Q. Tao, B. Ahmed, J. Palisaitis, I. Persson et al., High-entropy laminate metal carbide (MAX phase) and its two-dimensional derivative MXene. Chem. Mater. 34, 2098–2106 (2022). 10.1021/acs.chemmater.1c03348

[184] [184] A.S. Etman, J. Zhou, J. Rosen, Ti1.1V0.7CrxNb1.0Ta0.6C3Tz high-entropy MXene freestanding films for charge storage applications. Electrochem. Commun. 137, 107264 (2022). 10.1016/j.elecom.2022.107264

[185] [185] S. Wu, X. Li, Y. Zhang, Q. Guan, J. Wang et al., Interface engineering of MXene-based heterostructures for lithium-sulfur batteries. Nano Res. 16, 9158–9178 (2023). 10.1007/s12274-023-5532-2

[186] [186] Z. Du, C. Wu, Y. Chen, Q. Zhu, Y. Cui et al., High-entropy carbonitride MAX phases and their derivative MXenes. Adv. Energy Mater. 12, 2103228 (2022). 10.1002/aenm.202103228

[187] [187] V. Kamysbayev, A.S. Filatov, H. Hu, X. Rui, F. Lagunas et al., Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science 369, 979–983 (2020). 10.1126/science.aba8311

[188] [188] H.K. Chae, D.Y. Siberio-Pérez, J. Kim, Y. Go, M. Eddaoudi et al., A route to high surface area, porosity and inclusion of large molecules in crystals. Nature 427, 523–527 (2004). 10.1038/nature02311

[189] [189] U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt et al., Metal–organic frameworks—prospective industrial applications. J. Mater. Chem. 16, 626–636 (2006). 10.1039/b511962f

[190] [190] M. Gharibeh, G.A. Tompsett, K.S. Yngvesson, W.C. Conner, Microwave synthesis of zeolites: effect of power delivery. J. Phys. Chem. B 113, 8930–8940 (2009). 10.1021/jp900400d

[191] [191] A. Pichon, A. Lazuen-Garay, S.L. James, Solvent-free synthesis of a microporous metal–organic framework. CrystEngComm 8, 211–214 (2006). 10.1039/B513750K

[192] [192] A. Carné-Sánchez, I. Imaz, M. Cano-Sarabia, D. Maspoch, A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures. Nat. Chem. 5, 203–211 (2013). 10.1038/nchem.1569

[193] [193] X. Zhao, Z. Xue, W. Chen, X. Bai, R. Shi et al., Ambient fast, large-scale synthesis of entropy-stabilized metal–organic framework nanosheets for electrocatalytic oxygen evolution. J. Mater. Chem. A 7, 26238–26242 (2019). 10.1039/c9ta09975a

[194] [194] Z. Liu, J. Xu, F. Zhang, L. Ji, Z. Shi, Defect-rich high-entropy oxide nanospheres anchored on high-entropy MOF nanosheets for oxygen evolution reaction. Int. J. Hydrog. Energy 48, 14622–14632 (2023). 10.1016/j.ijhydene.2022.12.333

[195] [195] Y. Sun, W. Wu, L. Yu, S. Xu, Y. Zhang et al., Asymmetric acidic/alkaline N2 electrofixation accelerated by high-entropy metal–organic frameworkderivatives. Carbon Energy 5, e263 (2023). 10.1002/cey2.263

[196] [196] S. Xu, M. Li, H. Wang, Y. Sun, W. Liu et al., High-entropy metal–organic framework arrays boost oxygen evolution electrocatalysis. J. Phys. Chem. C 126, 14094–14102 (2022). 10.1021/acs.jpcc.2c05083

[197] [197] P. Hu, X. Liang, M. Yaseen, X. Sun, Z. Tong et al., Preparation of highly-hydrophobic novel N-coordinated UiO-66(Zr) with dopamine via fast mechano-chemical method for (CHO-/Cl-)-VOCs competitive adsorption in humid environment. Chem. Eng. J. 332, 608–618 (2018). 10.1016/j.cej.2017.09.115

[198] [198] J.M. Gonçalves, J.G. Ruiz-Montoya, Emerging high-entropy coordination compounds and their derivatives for energy application. J. Mater. Chem. A 11, 20872–20885 (2023). 10.1039/d3ta03500j

[199] [199] J. Hu, L. Cao, Z. Wang, J. Liu, J. Zhang et al., Hollow high-entropy metal organic framework derived nanocomposite as efficient electrocatalyst for oxygen reduction reaction. Compos. Commun. 27, 100866 (2021). 10.1016/j.coco.2021.100866

[200] [200] W. Dong, Q. Pan, Z. Liu, H. Sun, Z. Shi et al., Electrodeposition of defect-rich high entropy ZIF and its application in water oxidation. Int. J. Hydrog. Energy 48, 35493–35501 (2023). 10.1016/j.ijhydene.2023.05.333

[201] [201] R. Li, X. Ren, H. Ma, X. Feng, Z. Lin et al., Nickel-substituted zeolitic imidazolate frameworks for time-resolved alcohol sensing and photocatalysis under visible light. J. Mater. Chem. A 2, 5724–5729 (2014). 10.1039/c3ta15058e

[202] [202] C. Zhao, W. Cai, N. Sun, S. Chen, W. Jing et al., Facile preparation of porous high-entropy alloy FeCoNiCuMn and its OER performance. J. Phys. Chem. Solids 184, 111668 (2024). 10.1016/j.jpcs.2023.111668

[203] [203] H. Raza, J. Cheng, C. Lin, S. Majumder, G. Zheng et al., High-entropy stabilized oxides derived via a low-temperature template route for high-performance lithium-sulfur batteries. EcoMat 5, e12324 (2023). 10.1002/eom2.12324

[204] [204] Y. Zhou, L. Gao, H. Chen, H. Wang, J. Zhang et al., Fabrication of amorphous FeCoNiCuMnPx high-entropy phosphide/carbon composites with a heterostructured fusiform morphology for efficient oxygen evolution reaction. J. Mater. Sci. Technol. 168, 62–70 (2024). 10.1016/j.jmst.2023.05.054

[205] [205] Y. Ma, Y. Ma, S.L. Dreyer, Q. Wang, K. Wang et al., High-entropy metal-organic frameworks for highly reversible sodium storage. Adv. Mater. 33, e2101342 (2021). 10.1002/adma.202101342

[206] [206] Y. Wei, Y. Zhao, Y. Chen, M. Zhang, Z. Zhang et al., Lithium storage characteristic of nanoporous high-entropy alloy@high-entropy oxide with spin-dependent synergism of cations. Chem. Eng. J. 476, 146881 (2023). 10.1016/j.cej.2023.146881

[207] [207] Y. Yuan, Z. Xu, P. Han, Z. Dan, F. Qin et al., MnO2-decorated metallic framework supercapacitors fabricated from duplex-phase FeCrCoMnNiAl0.75 Cantor high entropy alloy precursors through selective phase dissolution. J. Alloys Compd. 870, 159523 (2021). 10.1016/j.jallcom.2021.159523

[208] [208] H. Guo, J. Shen, T. Wang, C. Cheng, H. Yao et al., Design and fabrication of high-entropy oxide anchored on graphene for boosting kinetic performance and energy storage. Ceram. Int. 48, 3344–3350 (2022). 10.1016/j.ceramint.2021.10.109

[209] [209] S. Wang, W. Huo, F. Fang, Z. Xie, J.K. Shang et al., High entropy alloy/C nanoparticles derived from polymetallic MOF as promising electrocatalysts for alkaline oxygen evolution reaction. Chem. Eng. J. 429, 132410 (2022). 10.1016/j.cej.2021.132410

[210] [210] V. Jishnu, S.S. Mishra, M.B. Kusuma Urs, S.P. Thomas, C.S. Tiwary et al., Highly sensitive and selective triethylamine sensing through high-entropy alloy (Ti–Zr–Cr–V–Ni) nanoparticle-induced Fermi energy control of MoS2 nanosheets. ACS Appl. Mater. Interfaces 14, 13653–13664 (2022). 10.1021/acsami.2c00531

[211] [211] H. Fan, Y. Si, Y. Zhang, F. Zhu, X. Wang et al., Grapevine-like high entropy oxide composites boost high-performance lithium sulfur batteries as bifunctional interlayers. Green Energy Environ. 9, 565–572 (2024). 10.1016/j.gee.2022.11.001

[212] [212] J. Gild, Y. Zhang, T. Harrington, S. Jiang, T. Hu et al., High-entropy metal diborides: a new class of high-entropy materials and a new type of ultrahigh temperature ceramics. Sci. Rep. 6, 37946 (2016). 10.1038/srep37946

[213] [213] J. Gild, J. Braun, K. Kaufmann, E. Marin, T. Harrington et al., A high-entropy silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2. J. Materiomics 5, 337–343 (2019). 10.1016/j.jmat.2019.03.002

[214] [214] H. Fu, Y. Jiang, M. Zhang, Z. Zhong, Z. Liang et al., High-entropy rare earth materials: synthesis, application and outlook. Chem. Soc. Rev. 53, 2211–2247 (2024). 10.1039/d2cs01030e

[215] [215] L. Wang, Z. Gao, K. Su, N.T. Nguyen, R.-T. Gao et al., Stacked high-entropy hydroxides promote charge transfer kinetics for photoelectrochemical water splitting. Adv. Funct. Mater. (2024). 10.1002/adfm.202403948

[216] [216] T. Zhang, Y.-L. Meng, Y.-H. Zhao, J.-C. Ni, Y. Pan et al., Boosting the oxygen evolution electrocatalysis of high-entropy hydroxides by high-valence nickel species regulation. Chem. Commun. 58, 7682–7685 (2022). 10.1039/d2cc02367a

[217] [217] T.G. Ritter, A.H. Phakatkar, M.G. Rasul, M.T. Saray, L.V. Sorokina et al., Electrochemical synthesis of high entropy hydroxides and oxides boosted by hydrogen evolution reaction. Cell Rep. Phys. Sci. 3, 100847 (2022). 10.1016/j.xcrp.2022.100847

[218] [218] J. Pan, Y. Bao, H. Wang, F. Lyu, L. Liu et al., Amorphous high-entropy hydroxides of tunable wide solar absorption for solar water evaporation. Part. Part. Syst. Charact. 38, 2100094 (2021). 10.1002/ppsc.202100094

[219] [219] Z. Zhang, H. Li, Promoting the uptake of chloride ions by ZnCo–Cl layered double hydroxide electrodes for enhanced capacitive deionization. Environ. Sci. Nano 8, 1886–1895 (2021). 10.1039/D1EN00350J

[220] [220] K. Gu, X. Zhu, D. Wang, N. Zhang, G. Huang et al., Ultrathin defective high-entropy layered double hydroxides for electrochemical water oxidation. J. Energy Chem. 60, 121–126 (2021). 10.1016/j.jechem.2020.12.029

[221] [221] X. Wu, Z.-J. Zhao, X. Shi, L. Kang, P. Das et al., Multi-site catalysis of high-entropy hydroxides for sustainable electrooxidation of glucose to glucaric acid. Energy Environ. Sci. 17, 3042–3051 (2024). 10.1039/d4ee00221k

[222] [222] B.M. Hunter, W. Hieringer, J.R. Winkler, H.B. Gray, A.M. Müller, Effect of interlayer anions on [NiFe]-LDH nanosheet water oxidation activity. Energy Environ. Sci. 9, 1734–1743 (2016). 10.1039/c6ee00377j

[223] [223] R.S. Jayashree, P.V. Kamathm, Factors governing the electrochemical synthesis of α-nickel (ii) hydroxide. J. Appl. Electrochem. 29, 449–454 (1999). 10.1023/A:1003493711239

[224] [224] Z. Zhu, Y. Zhang, D. Kong, N. He, Q. Chen, A novel high entropy hydroxide electrode material for promoting energy density of supercapacitors and its efficient synthesis strategy. Small 20, e2307754 (2024). 10.1002/smll.202307754

[225] [225] Z. Jia, T. Yang, L. Sun, Y. Zhao, W. Li et al., A novel multinary intermetallic as an active electrocatalyst for hydrogen evolution. Adv. Mater. 32, e2000385 (2020). 10.1002/adma.202000385

[226] [226] A. Ostovari Moghaddam, A. Abdollahzadeh, M. Samodurova, N. Shaburova, D. Mikhailov et al., Novel high entropy intermetallic compounds: Synthesis and detonation spraying. Intermetallics 146, 107591 (2022). 10.1016/j.intermet.2022.107591

[227] [227] Z. Lu, Y. Tan, Y. Huang, X. Tao, H. Chen et al., Synthesis and characterization of a novel Full-Heusler high entropy intermetallic compound-(FeCoNi)2TiSb. Intermetallics 171, 108343 (2024). 10.1016/j.intermet.2024.108343

[228] [228] S.S. Soliman, G.R. Dey, C.R. McCormick, R.E. Schaak, Temporal evolution of morphology, composition, and structure in the formation of colloidal high-entropy intermetallic nanoparticles. ACS Nano 17, 16147–16159 (2023). 10.1021/acsnano.3c05241

[229] [229] Y. Nakaya, E. Hayashida, H. Asakura, S. Takakusagi, S. Yasumura et al., High-entropy intermetallics serve ultrastable single-atom Pt for propane dehydrogenation. J. Am. Chem. Soc. 144, 15944–15953 (2022). 10.1021/jacs.2c01200

[230] [230] Y. Wang, N. Gong, H. Liu, W. Ma, K. Hippalgaonkar et al., Ordering-dependent hydrogen evolution and oxygen reduction electrocatalysis of high-entropy intermetallic Pt4FeCoCuNi. Adv. Mater. 35, e2302067 (2023). 10.1002/adma.202302067

[231] [231] Y. Wang, X.-Y. Zhang, H. He, J.-J. Chen, B. Liu, Ordered mesoporous high-entropy intermetallics for efficient oxygen reduction electrocatalysis. Adv. Energy Mater. 14, 2303923 (2024). 10.1002/aenm.202303923

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Dongxiao Li, Chang Liu, Shusheng Tao, Jieming Cai, Biao Zhong, Jie Li, Wentao Deng, Hongshuai Hou, Guoqiang Zou, Xiaobo Ji. High-Entropy Electrode Materials: Synthesis, Properties and Outlook[J]. Nano-Micro Letters, 2025, 17(1): 022

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Paper Information

Category: Research Articles

Received: Jun. 12, 2024

Accepted: Aug. 10, 2024

Published Online: Feb. 12, 2025

The Author Email: Liu Chang (21144@hnie.edu.cn), Zou Guoqiang (gq-zou@csu.edu.cn)

DOI:10.1007/s40820-024-01504-3

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

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