Infrared and Laser Engineering, Volume. 54, Issue 1, 20240440(2025)

Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited)

Nan ZHA1...2, Junhu CAI1,2, Yun YE1,2, Sheng XU1,2, Tailiang GUO1,2, and Enguo CHEN12 |Show fewer author(s)
Author Affiliations
  • 1College of Physics and Information Engineering, Fuzhou University, Fuzhou 350108, China
  • 2Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou 350108, China
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    Figures & Tables(6)
    (a)-(b) TEM images of Initial CsPbI3 and Zn:CsPbI3 quantum dots and their physical images irradiated by ultraviolet lamps; (c)-(d) Particle size distribution of Initial CsPbI3 and Zn:CsPbI3 quantum dots; (e) Schematic diagram of the Zn ion doping principle of CsPbI3 quantum dots; (f) XRD spectra of Initial CsPbI3 and Zn:CsPbI3 quantum dots; (g) Elemental mapping of Cs, Pb, Zn, I elements in Zn:CsPbI3 quantum dots
    (a) XPS spectra of Initial CsPbI3 and Zn:CsPbI3 quantum dots; (b)-(d) High-resolution XPS spectra of Pb 4f, Zn 2p, I 3d of Initial CsPbI3 and Zn:CsPbI3 quantum dots
    (a) Normalized absorption spectra and PL spectra of CsPbI3 quantum dots with different ZnI2/PbI2 molar ratios; (b) PLQY of CsPbI3 quantum dots with different ZnI2/PbI2 molar ratios; (c) Comparison of PL spectra of Initial CsPbI3 and Zn:CsPbI3 quantum dot; (d) PLQY of the Initial CsPbI3 and Zn:CsPbI3 quantum dots solution over time; (e) TRPL decay curves of Initial CsPbI3 and Zn:CsPbI3 quantum dots
    (a) Schematic diagram of a backlight LED device composed of Zn: CsPbI3/PDMS, CsPbBr3/PDMS, CsPbCl3/PDMS color conversion film and UV LED chip; (b)-(d) Spectrum of red, green and blue LEDs and working photos; (e) Comparison of CIE chromaticity of LED devices with NTSC standards
    • Table 1. Fitting parameters of TRPL spectrum

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      Table 1. Fitting parameters of TRPL spectrum

      Fitting parameters/nsInitial CsPbI3Zn:CsPbI3
      τ117.1312.72
      τ2159.56118.62
      τav138.44102.61
    • Table 2. Comparison of color coordinates, Gamma, and PLQY between Zn:CsPbI3 and other red quantum dot LEDs

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      Table 2. Comparison of color coordinates, Gamma, and PLQY between Zn:CsPbI3 and other red quantum dot LEDs

      Quantum dot materialsColor coordinatesColor gamutPLQYReference
      Zn:CsPbI30.729,0.272135.22%98%Our work
      Initial:CsPbI30.65,0.34120.49%56%Our work
      K2SiF6:Mn4+red phosphor0.686,0.319128.32%94.9%[46]
      CdSe0.68,0.32126.98%99%[47]
      InP0.69,0.31129.12%95%[47]
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    Nan ZHA, Junhu CAI, Yun YE, Sheng XU, Tailiang GUO, Enguo CHEN. Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited)[J]. Infrared and Laser Engineering, 2025, 54(1): 20240440

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    Paper Information

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    Received: Sep. 24, 2024

    Accepted: --

    Published Online: Feb. 12, 2025

    The Author Email:

    DOI:10.3788/IRLA20240440

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