<trans-title xml:lang="en">Crystal Growth and Thermoelectric Properties of Zintl Phase Mg<sub>3</sub>X<sub>2</sub> (X=Sb, Bi) Based Materials: a Review </trans-title>

Siqi LIN; Airan LI; Chenguang FU; Rongbing LI; Min JIN

doi:10.15541/jim20220356

Journal of Inorganic Materials, Volume. 38, Issue 3, 270(2023)

Crystal Growth and Thermoelectric Properties of Zintl Phase Mg₃X₂ (X=Sb, Bi) Based Materials: a Review

Siqi LIN1...2,3, Airan LI4, Chenguang FU4, Rongbing LI1, and Min JIN13,* |Show fewer author(s)

Author Affiliations

¹1. College of Materials, Shanghai Dianji University, Shanghai 201306, China

²2. School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

³3. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

⁴4. School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

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Figures & Tables(8)

1. Crystal structure of Mg₃X₂ (X=Sb, Bi)^[33]

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2. Phase diagram of Mg₃X₂ compounds^[46-47]

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3. MgSb₂crystals grown by slow cooling method

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4. MgSb₂crystals grown by directional solidification method^[51]

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5. Mg₃Sb_2-_xBi_x crystals grown by flux method

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6. MgSb₂crystal grown by flux method^[56]

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7. Thermoelectric properties of Mg₃Sb_2-_xBi_x crystals

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Table 1. Growth results of Mg₃X₂crystal by different methods and their thermoelectric properties

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Table 1. Growth results of Mg₃X₂crystal by different methods and their thermoelectric properties

Method	Composition	Type	Shape and size	ZT_max	Year	Ref.
Temperature cooling	Mn-doped Mg₃Sb₂	n	Flake, 6-7 mm	0.11 (//ab plane, 500 K)	2014	[48]
	Mg₃Sb_2-_xBi_x	p	Flake, 6-7 mm	0.006 (//ab plane, 300 K)	2015	[49]
	Ag-doped Mg₃Sb₂	p	Bulk, 3 mm×6 mm×10 mm	0.03 (//ab plane, 300 K)0.12 (┴ab plane, 300 K)	2021	[50]
Flux method	Mg₃Sb₂ (Sb Flux)	p	Flake, 6-7 mm	-	2018	[53]
	Mg₃Bi₂ (Bi Flux)	p	Flake, 6-7 mm	-	2018	[53]
	Y-doped Mg₃Sb₂(Mg Flux)	n	Flake, 3-8 mm	-	2020	[55]
	Y-doped Mg₃Bi₂(Mg Flux)	n/p	Flake, 3-8 mm	-	2020	[55]
	Y-doped Mg₃Bi_1.25Sb_0.75(Mg Flux)	n	Flake, 3-10 mm	0.82 (//ab plane, 325 K)	2020	[55]
	Te-doped Mg₃Sb₂ (Sb Flux)	n	Flake, 5-10 mm	0.78 (//ab plane, 600 K)	2020	[54]
Directional solidification	Ag-doped Mg₃Sb₂	p	Ingot, ϕ 10 mm×50 mm	0.62 (//ab plane, 800 K)0.68 (┴ab plane, 800 K)	2020	[51]
Flux Bridgman	Y-doped Mg₃Sb₂(Sb/Bi Flux)	n	Bulk, 8 mm×10 mm×25 mm	0.60 (//ab plane, 700 K)0.48 (┴ab plane, 700 K)	2021	[56]

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Siqi LIN, Airan LI, Chenguang FU, Rongbing LI, Min JIN. Crystal Growth and Thermoelectric Properties of Zintl Phase Mg₃X₂ (X=Sb, Bi) Based Materials: a Review [J]. Journal of Inorganic Materials, 2023, 38(3): 270

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Paper Information

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Received: Jun. 24, 2022

Accepted: --

Published Online: Oct. 16, 2023

The Author Email: JIN Min (jmaish@aliyun.com)

DOI:10.15541/jim20220356

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. Growth results of Mg3X2 crystal by different methods and their thermoelectric properties

Table 1. Growth results of Mg3X2 crystal by different methods and their thermoelectric properties

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Table 1. Growth results of Mg₃X₂crystal by different methods and their thermoelectric properties

Table 1. Growth results of Mg₃X₂crystal by different methods and their thermoelectric properties