Journal of Inorganic Materials, Volume. 38, Issue 10, 1237(2023)

Adsorption Mechanism of NaY Zeolite Molecular Adsorber Coating on Typical Space Contaminations

Jieyan DAI1...2, Aihu FENG2,*, Le MI2, Yang YU2, Yuanyuan CUI3, and Yun YU12,* |Show fewer author(s)
Author Affiliations
  • 11. College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China
  • 22. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 33. School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China
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    Figures & Tables(11)
    Three different contaminant models(a) C7H8; (b) C10H10O4; (c) C8H24O4Si4
    Three NaY models(a) NaY2.6 opt1; (b) NaY2.6 opt2; (c) NaY2.6 opt3
    Comparison between simulated and experimental results of X-ray diffraction patterns
    Adsorption isotherms of NaY zeolite on toluene at 298 K(a) Simulated data; (b) Experimental data
    Simulated toluene adsorption isotherms of NaY zeolite at different pressures(a) 10-3 kPa-101 kPa; (b) 10-10 kPa-10-3 kPa; (c) Adsorption heat of NaY zeolites
    Density distribution of toluene in NaY zeolite at different pressures(a1, b1) 10-6 Pa; (a2, b2) 10-4 Pa; (c1, c2) 1 Pa
    Density distribution of toluene in NaY zeolite at pressure of 1 Pa(a1) Density distribution image with different visual angle compared with Fig. 6(a3); (a2) Density distribution in β cage; (a3) Density distribution in super-cage
    Simulated adsorption isotherms of NaY zeolites at different pressures(a) C10H10O4; (b) C8H24O4Si4
    Adsorption heat of NaY zeolites at different temperatures(a) C10H10O4; (b) C8H24O4Si4
    Density distributions of C10H10O4 (a) and C8H24O4Si4 (b) in NaY zeolite at pressure of 1 Pa (298 K)(a1, b1) Original density distributions; (a2, b2) Density distributions in β cage; (a3, b3) Density distribution in the super-cage
    • Table 1.

      Comparison of adsorption capacity of different FAU zeolite on toluene

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      Table 1.

      Comparison of adsorption capacity of different FAU zeolite on toluene

      NumberTypeZeoliteAdsorbatePressure/kPaTemperature/KAdsorption amountRef.
      1SimulationFAUToluene0.002229828 per cell[36]
      2SimulationFAUToluene10029830 per cell[20]
      SimulationFAUToluene10035030 per cell
      3SimulationFAU-NaYToluene1.5300~2.5 mmol/g (248 mg/g)[37]
      4SimulationFAU-NaYToluene101298~36 per cell (260 mg/g)This work
      SimulationFAU-NaYToluene101373~36 per cell
      ExperimentFAU-NaYToluene3.629836.3 per cell (262 mg/g)
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    Jieyan DAI, Aihu FENG, Le MI, Yang YU, Yuanyuan CUI, Yun YU. Adsorption Mechanism of NaY Zeolite Molecular Adsorber Coating on Typical Space Contaminations[J]. Journal of Inorganic Materials, 2023, 38(10): 1237

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    Paper Information

    Category:

    Received: Feb. 25, 2023

    Accepted: --

    Published Online: Mar. 6, 2024

    The Author Email: FENG Aihu (fengaihu@mail.sic.ac.cn), YU Yun (yunyush@mail.sic.ac.cn)

    DOI:10.15541/jim20230095

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