Journal of Inorganic Materials, Volume. 38, Issue 5, 544(2023)

Corrosion Behavior and Mechanism of Aluminum-rich CMAS on Rare-earth Silicate Environmental Barrier Coatings:

Dong FAN1...2, Xin ZHONG1,*, Yawen WANG1, Zhenzhong ZHANG2,*, Yaran NIU1, Qilian LI3, Le ZHANG3 and Xuebin ZHENG1 |Show fewer author(s)
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
  • 33. Avic Manufacturing Technology Institute, Beijing 100024, China
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    Figures & Tables(13)
    XRD patterns of powders and as-sprayed coatings
    XRD pattern of CMAS powders
    XRD patterns of coatings after CMAS corrosion for 4 and 25 h
    Surface microstructures of coatings after corrosion for 4 and 25 h
    Cross-sectional microstructures of coatings after CMAS corrosion for 4 h
    Surface and cross-sectional microstructures of as-sprayed coatings
    Cross-sectional microstructures of the X1-Gd2SiO5 coating after corrosion for 25 h
    Schematic diagrams of different coatings under CMAS molten salt corrosion at 1400 ℃
    • Table 1. Technical parameters used for plasma spraying

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      Table 1. Technical parameters used for plasma spraying

      ParameterRE2SiO5 (RE=Gd, Y, Er)
      Primary Ar/(L·min-1)43
      Secondary H2/(L·min-1)12
      Carrier Ar/(L·min-1)2.3
      Spray distance/mm230
    • Table 2. Chemical compositions of CMAS powders

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      Table 2. Chemical compositions of CMAS powders

      XRF/(%,in mol)CaOMgOAlO1.5SiO2
      CMAS27.878.7926.2238.52
    • Table 3. EDS elemental compositions of the marked regions in Fig. 3

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      Table 3. EDS elemental compositions of the marked regions in Fig. 3

      EDS/(%, in atom) GdYErSiOCaAlMg
      Point 120.6019.6251.738.02
      Point 226.0417.5550.575.83
      Point 326.9515.1650.787.10
      Point 414.035.7252.274.0120.313.66
    • Table 4. EDS elemental compositions of the marked regions in Fig. 4

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      Table 4. EDS elemental compositions of the marked regions in Fig. 4

      EDS/(%, in atom)GdYErSiOCaAlMg
      Point 119.21—-11.7060.658.44
      Point 21.1613.0659.3713.7810.182.45
      Point 315.2916.0061.826.89
      Point 47.1815.5050.179.5812.145.43
      Point 50.9613.5659.6213.0310.402.42
      Point 620.2712.1161.126.50
      Point 78.7010.9559.158.0910.954.65
      Point 80.923.2958.7419.613.292.07
    • Table 5. EDS elemental compositions of the marked regions in Fig. 5

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      Table 5. EDS elemental compositions of the marked regions in Fig. 5

      EDS/(%, in atom) GdYErSiOCaAlMg
      Point 124.4816.2251.617.68
      Point 21.0512.6259.6314.259.782.66
      Point 326.7015.7850.127.40
      Point 417.108.2351.252.9216.414.09
      Point 50.9414.2357.3613.9411.981.54
      Point 628.8012.7752.226.22
      Point 77.1213.0549.267.0818.265.24
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    Dong FAN, Xin ZHONG, Yawen WANG, Zhenzhong ZHANG, Yaran NIU, Qilian LI, Le ZHANG, Xuebin ZHENG. Corrosion Behavior and Mechanism of Aluminum-rich CMAS on Rare-earth Silicate Environmental Barrier Coatings:[J]. Journal of Inorganic Materials, 2023, 38(5): 544

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    Paper Information

    Category:

    Received: Sep. 13, 2022

    Accepted: --

    Published Online: Oct. 17, 2023

    The Author Email: ZHONG Xin (zhongxin@mail.sic.ac.cn), ZHANG Zhenzhong (njutzhangzz@126.com)

    DOI:10.15541/jim20220532

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