Journal of Inorganic Materials, Volume. 35, Issue 3, 359(2020)

Construction of Novel Three Dimensionally Macroporous g-C3N4 for Efficient Adsorption/Photocatalytic Reduction of U(VI)

Li JIANG1, Huihui GAO1, Ruya CAO1,2, Shouwei ZHANG1、*, and Jiaxing LI2、*
Author Affiliations
  • 1School of Physics and Technology, University of Jinan, Jinan 250022, China
  • 2Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China
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    Figures & Tables(7)
    XRD patterns (a) and FT-IR spectra (b) of the bulk g-C3N4 and 3D macroporous g-C3N4
    UV-Vis diffuse reflectance spectra (a) and surface areas (b) of the bulk g-C3N4 and 3D macroporous g-C3N4
    SEM and TEM images of the bulk g-C3N4 (a, b) and 3D macroporous g-C3N4 (c, d)
    (a) Adsorption kinetics and (b) adsorption isotherms for U(VI) on bulk g-C3N4 and 3D macropoous g-C3N4
    (a) Dark adsorption and photocatalytic reduction of U(VI) and (b) the rate constant with bulk g-C3N4 and 3D macroporous g-C3N4, (c) cycling runs of 3D macroporous g-C3N4 for the photocatalytic reduction of U(VI) and (d) U4f specta of 3D macroporous g-C3N4 before and after U(VI) photoreduction
    (a) Transient photocurrent responses and (b) electrochemical impedance spectra of bulk g-C3N4 and 3D macroporous g-C3N4
    • Table 1. Fitting parameters of pseudo-first-order and pseudo-second-order kinetic models

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      Table 1. Fitting parameters of pseudo-first-order and pseudo-second-order kinetic models

      SamplePseudo-first-ordermodelPseudo-second-ordermodel
      k1/min-1R2k2/(g∙mg-1∙min-1)R2
      Bulk g-C3N40.07610.9830.04930.999
      3D macroporous g-C3N40.10870.9920.07210.999
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    Li JIANG, Huihui GAO, Ruya CAO, Shouwei ZHANG, Jiaxing LI. Construction of Novel Three Dimensionally Macroporous g-C3N4 for Efficient Adsorption/Photocatalytic Reduction of U(VI)[J]. Journal of Inorganic Materials, 2020, 35(3): 359

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    Paper Information

    Category: RESEARCH PAPER

    Received: Jul. 5, 2019

    Accepted: --

    Published Online: Jan. 27, 2021

    The Author Email: ZHANG Shouwei (sps_zhangsw@ujn.edu.cn), LI Jiaxing (lijx@ipp.ac.cn)

    DOI:10.15541/jim20190336

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