Journal of Radiation Research and Radiation Processing, Volume. 43, Issue 1, 010201(2025)

Post-radiation oxidation reaction of three types of polyethylene films

Lei HAN1...2, Jing WANG1,2, Manli LU1, Wenli ZHANG1, Rongfang SHEN1, Weihua LIU1 and Mouhua WANG1,* |Show fewer author(s)
Author Affiliations
  • 1Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(8)
    Optical images of UHMWPE (a, d), HDPE (b, e), and LDPE (c, f) before and after post radiation oxidation (absorbed dose of 100 kGy, oxygen partial pressure of 5×105 Pa, oxidized at room temperature for 47 d)
    DSC images of UHMWPE (a), HDPE (b), and LDPE (c) before and after radiation and oxidation(absorbed dose of 100 kGy, oxygen partial pressure of 5×105 Pa, oxidized at room temperature for 47 d) (color online)
    FTIR spectra and OI values with time for the post radiation oxidation of UHMWPE (a, b), HDPE (c, d), and LDPE (e, f) under room temperature conditions (absorbed dose of 100 kGy, oxygen partial pressure of 5×105 Pa, oxidized at room temperature for 47 d) (color online)
    Images of OI values with time for the post radiation oxidation of UHMWPE (a) and HDPE (b) at different temperatures (room temperature, 50 °C, 70 °C, and 90 °C)(Absorbed dose of 100 kGy, oxygen partial pressure of 5×105 Pa, oxidized for 24 h)
    Images of OI values with time for the post radiation oxidation of UHMWPE (a, c, e) and HDPE (b, d, f) at different oxygen partial pressures (2×104 Pa, 1×105 Pa, 3×105 Pa, 5×105 Pa, and 9×105 Pa) and different temperatures (a, b) room temperature, (c, d) 50 °C, and (e, f) 70 ℃ (absorbed dose of 100 kGy, oxidized for 24 h)
    Images of OI values with time for the post radiation oxidation of UHMWPE (a, b) and HDPE (c, d) at different absorbed doses (50 kGy, 100 kGy, 150 kGy, 200 kGy, and 300 kGy) and at different temperatures (a, c) 50 ℃ and (b, d) 70 ℃ (oxygen partial pressure of 5×105 Pa, oxidized for 24 h)
    Mechanism of oxidation process by PE post-radiation
    • Table 1. DSC data of PE before and after radiation and oxidation

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      Table 1. DSC data of PE before and after radiation and oxidation

      样品

      Sample

      UHMWPEHDPELDPE

      结晶度 / %

      Crystallinity

      熔点 / ℃

      Melting point

      结晶度 / %

      Crystallinity

      熔点 / ℃

      Melting point

      结晶度 / %

      Crystallinity

      熔点 / ℃

      Melting point

      原始

      Original

      42.56132.1547.82132.4428.88110.21

      辐照后

      Afterradiation

      40.17129.1344.12129.4728.44109.49

      后辐射氧化后

      After post-radiation oxidation

      49.39129.8053.82130.3728.70107.91
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    Lei HAN, Jing WANG, Manli LU, Wenli ZHANG, Rongfang SHEN, Weihua LIU, Mouhua WANG. Post-radiation oxidation reaction of three types of polyethylene films[J]. Journal of Radiation Research and Radiation Processing, 2025, 43(1): 010201

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    Paper Information

    Category: RADIATION CHEMISTRY

    Received: Jun. 19, 2024

    Accepted: Jul. 15, 2024

    Published Online: Mar. 13, 2025

    The Author Email: WANG Mouhua (王谋华)

    DOI:10.11889/j.1000-3436.2024-0054

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