Journal of Inorganic Materials, Volume. 37, Issue 12, 1337(2022)

In-situ Modification of Carbon Nanotubes with Metallic Bismuth Nanoparticles for Uniform Lithium Deposition

Jia CAI*... Gaoxu HUANG, Xiaopan JIN, Chi WEI, Jiayi MAO and Yongsheng LI |Show fewer author(s)
Figures & Tables(6)
Schematic diagram for the synthesis of Bi@CNT
Microstructure characterization of samples
Coulombic efficiencies of Li|Cu cells based on Bi@CNT/Cu, CNT/Cu and Cu current collectors at (a) 1 mA·cm-2, 1 mAh·cm-2 and (b) 3 mA·cm-2, 1 mAh·cm-2; Capacity-voltage curves of Li|Cu cells based on (c) Bi@CNT/Cu, (d) CNT/Cu, and (e) Cu current collectors at 1 mA·cm-2, 1 mAh·cm-2Colorful figures are available on website
SEM images of (a) Bi@CNT/Cu, (b) CNT/Cu, and (c) Cu current collectors in Li|Cu cells after 50 cycles; (d) First cyclic EIS plots of Li|Cu cells based on Bi@CNT/Cu, CNT/Cu and Cu current collectors, and voltage-time curves of symmetric cells based on Li@Bi@CNT/Cu, Li@CNT/Cu and Li@Cu anodes at (e) 1 mA·cm-2, 1 mAh·cm-2 and (f) 2 mA·cm-2, 1 mAh·cm-2
(a) Cycling performances and (b) rate performances of LFP full cells based on Li@Bi@CNT/Cu, Li@CNT/Cu, and Li@Cu anodes, and (c-e) capacity-voltage profiles of LFP full cells based on (c) Li@Bi@CNT/Cu, (d) Li@CNT/Cu, and (e) Li@Cu anodes at 1C
  • Table 1. Comparison of electrochemical properties of copper foils modified by different materials

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    Table 1. Comparison of electrochemical properties of copper foils modified by different materials

    Symmetric cellLi|Cu cell
    Current collectorCurrentdensity/(mA·cm-2)Planting/strippingcapacity/(mAh·cm-2)Cyclingtime/hCurrentdensity/(mA·cm-2)Planting capacity/(mAh·cm-2)Cycle number, nCoulombicefficiency/%Ref.
    Bi@CNT1110001130098This work
    212603110096
    SMC-2112200.5121097[21]
    PDA0.10.28001110096[22]
    3D-CuZn114501115095[23]
    Li-MMT317020.2510097.9[24]
    LHCE117001120099.1[25]
    NMPC0.50.54001120098[26]
    Duplex Cu118801130097.3[27]
    Ti3C2Tx115001125098.4[28]
    q-PET311001110098[29]
    SF333501120096[30]
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Jia CAI, Gaoxu HUANG, Xiaopan JIN, Chi WEI, Jiayi MAO, Yongsheng LI. In-situ Modification of Carbon Nanotubes with Metallic Bismuth Nanoparticles for Uniform Lithium Deposition[J]. Journal of Inorganic Materials, 2022, 37(12): 1337

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Paper Information

Category: EDITORIAL

Received: Apr. 12, 2022

Accepted: --

Published Online: Jan. 12, 2023

The Author Email: CAI Jia (caijia0902@163.com)

DOI:10.15541/jim20220208

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