Chinese Physics B, Volume. 29, Issue 10, (2020)
Synthesis of black phosphorus structured polymeric nitrogen
Fig. 1. (a) Raman spectra of nitrogen heated at 143 GPa from run I (black) compared with the experimental spectra for BP-structured polymeric nitrogen (red bars) at 138 GPa, 2200 K.[
Fig. 2. Raman spectra of nitrogen before and after heating at 130 GPa using TiN and Pb as laser absorber, respectively.
Fig. 3. (a) Raman spectra of BP-N during the decompression. (b) Measured pressure dependence of Raman shift (run III) of BP-N and (run II) of CG-N compared with calculations and previously reported values[
Fig. 4. (a) The equation of state, (b) formation enthalpy, and (c) energy density of CH-N, BP-N, and cg-N. The values of CH-N, BP-N, and cg-N phases are shown in red triangle, red circle, and blue square, respectively. The red vertical dotted line indicates the pressure (20 GPa), where CH-N becomes stable.
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Ying Liu, Haipeng Su, Caoping Niu, Xianlong Wang, Junran Zhang, Zhongxue Ge, Yanchun Li. Synthesis of black phosphorus structured polymeric nitrogen[J]. Chinese Physics B, 2020, 29(10):
Received: Jun. 23, 2020
Accepted: --
Published Online: Apr. 21, 2021
The Author Email: Liu Ying (liuying8912@aliyun.com)