Chinese Physics B, Volume. 29, Issue 10, (2020)

Synthesis of black phosphorus structured polymeric nitrogen

Ying Liu1,†... Haipeng Su1, Caoping Niu2,3, Xianlong Wang2,3, Junran Zhang4, Zhongxue Ge1 and Yanchun Li4 |Show fewer author(s)
Author Affiliations
  • 1Xi’an Modern Chemistry Research Institute, Xi’an 70065, China
  • 2Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 30031, China
  • 3University of Science and Technology of China, Hefei 20026, China
  • 4Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 10009, China
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    Figures & Tables(5)
    (a) Raman spectra of nitrogen heated at 143 GPa from run I (black) compared with the experimental spectra for BP-structured polymeric nitrogen (red bars) at 138 GPa, 2200 K.[16] Inset shows the microscopic images of the sample under illumination with both reflected and transmitted light before and after laser heating. (b) Crystal structure of BP-N under 140 GPa.
    Raman spectra of nitrogen before and after heating at 130 GPa using TiN and Pb as laser absorber, respectively.
    (a) Raman spectra of BP-N during the decompression. (b) Measured pressure dependence of Raman shift (run III) of BP-N and (run II) of CG-N compared with calculations and previously reported values[10,13,15,16] of polymeric nitrogen. All measurements were performed during decompression.
    (a) The equation of state, (b) formation enthalpy, and (c) energy density of CH-N, BP-N, and cg-N. The values of CH-N, BP-N, and cg-N phases are shown in red triangle, red circle, and blue square, respectively. The red vertical dotted line indicates the pressure (20 GPa), where CH-N becomes stable.
    • Table 1. Experimental details of the five experimental runs, including the experimental conditions and major results.

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      Table 1. Experimental details of the five experimental runs, including the experimental conditions and major results.

      #Pressure/GPaTemperature/KAbsorberResults
      I∼ 143∼ 2500BP-N
      II∼ 130∼ 1800cg-N
      III∼ 130∼ 2500TiNBP-N
      IV∼ 130∼ 2500PbBP-N
      V∼ 120∼ 2500TiN
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    Ying Liu, Haipeng Su, Caoping Niu, Xianlong Wang, Junran Zhang, Zhongxue Ge, Yanchun Li. Synthesis of black phosphorus structured polymeric nitrogen[J]. Chinese Physics B, 2020, 29(10):

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    Paper Information

    Received: Jun. 23, 2020

    Accepted: --

    Published Online: Apr. 21, 2021

    The Author Email: Liu Ying (liuying8912@aliyun.com)

    DOI:10.1088/1674-1056/aba9bd

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