Photonics Research, Volume. 9, Issue 2, 131(2021)
Elucidating the photoluminescence-enhancement mechanism in a push-pull conjugated polymer induced by hot-electron injection from gold nanoparticles
Fig. 1. (a) Left, chemical structure of PBDB-T and, right, a schematic representing the plasmonic hybrid system of a PBDB-T matrix and P3HT-Au NPs. 2D GI-XRD patterns of (b) a neat PBDB-T film and hybrid films with PBDB-T/P3HT-Au NPs mass ratios of (c) 3:1 and (d) 1:1. (e)
Fig. 2. Peak-normalized absorption spectra of a neat PBDB-T film (dotted) and hybrid films with PBDB-T/P3HT-Au NPs mass ratios of 3:1 (dotted–dashed) and 1:1 (solid).
Fig. 3. PL enhancement factor of the hybrid film with the 1:1 ratio compared to the neat PBDB-T film: (a) the experimental value and (b) the simulation value obtained by a finite-difference time-domain (FDTD) method.
Fig. 4. Transient absorption (TA) spectra of (a) a neat PBDB-T film and hybrid films with PBDB-T/P3HT-Au NPs mass ratios of (b) 3:1 and (c) 1:1.
Fig. 5. TAS of the neat film (solid) and a blend film of PBDB-
Fig. 6. Pump-intensity-dependent TA kinetics of the neat PBDB-T film pumped with 620 nm and probed at 1180 nm. Dotted lines are best-fitted curves to extract decay constants.
Fig. 7. (a) Transient-absorption (TA) spectra and (b) kinetics of the neat PBDB-T film and the hybrid films. The samples were excited at 520 nm of
Fig. 8. Decay-associated difference spectra obtained from the TA data fitted globally to an exponential decay equation described in Eq. (
Fig. 10. Decay-associated difference spectra obtained from the TA data of the neat films fitted globally to an exponential decay equation described in Eq. (
Fig. 11. (a), (b) Species-associated spectra and (c), (d) model population kinetics of the given species. (e), (f) The selective wavelengths kinetics of the TA data fitted globally to the nonlinear kinetic equations described in Eq. (
Fig. 12. Schematic representing the excited-state dynamics of the neat PBDB-T system (left) and schematic representing the changed excited-state dynamics of the hybrid system by the hot-electron injection (HEI) from the P3HT-coated Au NPs to the PBDB-T matrix (right; the HEI-induced PL enhancement mechanism and the suppression of back charge-transfer from PBDB-T to the Au NPs by the P3HT chains tethered to the Au NPs).
Fig. 13. TA spectra of the neat P3HT and P3HT-Au NPs films. The samples were excited at 520 nm.
Fig. 14. PL spectra of the neat PBDB-T (solid) and blend P3HT/PBDB-T films. The samples were excited at 520 nm.
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Dongki Lee, Se Gyo Han, Jungho Mun, Kihyuk Yang, Sung Hyuk Kim, Junsuk Rho, Kilwon Cho, Dongyeop X. Oh, Mun Seok Jeong, "Elucidating the photoluminescence-enhancement mechanism in a push-pull conjugated polymer induced by hot-electron injection from gold nanoparticles," Photonics Res. 9, 131 (2021)
Category: Optical and Photonic Materials
Received: Sep. 9, 2020
Accepted: Nov. 9, 2020
Published Online: Jan. 29, 2021
The Author Email: Dongyeop X. Oh (dongyeop@krict.re.kr), Mun Seok Jeong (mjeong@skku.edu)