Journal of Inorganic Materials, Volume. 39, Issue 9, 1053(2024)

Polyacrylate-calcium (cerium) Nanocluster Fluorescent Probes for Quantitative Detection of Inorganic Phosphorus

Jia CHEN... Yiran FAN, Wenxin YAN and Yingchao HAN* |Show fewer author(s)
Author Affiliations
  • State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
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    Figures & Tables(10)
    Morphology, size and structure of PAA-Ca(Ce) nanofluorescent probe
    Fluorescence stability of PAA-Ca(Ce) nanofluorescent probe for PO43-
    Fluorescence emission spectra of the reaction products between PAA-Ca(Ce) fluorescent probes and PO43- with different concentrations of (Ca2++Ce3+), and corresponding linear relationship of PO43- concentration-fluorescence intensity
    Relationship between PO43- concentration and fluorescence intensity at low PO43-concentration
    Influence of reaction time and temperature on fluorescence intensity
    Relationship between instrument response value and PO43- concentration
    Influence of different chemical environmental factors on PAA-Ca(Ce) nano-fluorescent probes
    Schematic of fluorescence probe method for sensing PO43-
    • Table 1. Recovery of PO43- detected by fluorescence probe (FP) method in contrast to that by molybdenum-antimony resistance spectrophotometry (MARSP)

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      Table 1. Recovery of PO43- detected by fluorescence probe (FP) method in contrast to that by molybdenum-antimony resistance spectrophotometry (MARSP)

      PO43- added /(mmol·L-1) FP methodMARSP
      PO43- detected/(mmol·L-1) Recovery/% PO43- detected/(mmol·L-1) Recovery/%
      109.63396.3269.09690.962
      2020.611103.05618.69493.472
      3028.85696.18626.63488.780
      4040.009100.02237.71994.299
      5048.63497.26947.77995.559
      6060.304100.50755.13491.891
      7068.46297.80266.39194.844
      8079.15998.94975.19193.989
      9087.96497.73787.08096.755
      100100.526100.52694.50594.505
      110110.024100.02299.92890.844
      120116.61497.178115.24996.041
      130131.590101.223122.93494.564
      140139.34899.534125.77589.839
      150145.31896.879140.96193.974
      160161.331100.832156.50097.813
      170171.033100.608164.87696.986
      180176.63098.128170.58894.771
      190191.582100.832178.27093.826
      200198.96699.483196.27598.138
      Average recovery (mean±SD)/%99.155±1.88094.093±2.566
    • Table 2. Determination of PO43- in mouse serum

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      Table 2. Determination of PO43- in mouse serum

      SampleFP methodMARSPp value
      12.6482.5520.9626
      22.3752.451
      32.5992.604
      Average±SD2.541±0.1192.536±0.064
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    Jia CHEN, Yiran FAN, Wenxin YAN, Yingchao HAN. Polyacrylate-calcium (cerium) Nanocluster Fluorescent Probes for Quantitative Detection of Inorganic Phosphorus[J]. Journal of Inorganic Materials, 2024, 39(9): 1053

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    Paper Information

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    Received: Dec. 25, 2023

    Accepted: --

    Published Online: Dec. 13, 2024

    The Author Email: HAN Yingchao (hanyingchao@whut.edu.cn)

    DOI:10.15541/jim20230596

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