Journal of Inorganic Materials, Volume. 36, Issue 12, 1323(2021)

Symmetrical La3+-doped Sr2Fe1.5Ni0.1Mo0.4O6-δ Electrode Solid Oxide Fuel Cells for Pure CO2 Electrolysis

Yue WANG*... Changsong CUI, Shiwei WANG and Zhongliang ZHAN |Show fewer author(s)
Figures & Tables(8)
(a) XRD patterns of LxSFNM (x=0-0.4) powder calcined at 1000 ℃ in air for 5 h and (b) corresponding magnified patterns within 2θ=31°-35°
TGA analysis of LxSFNM in air
Electricity conductivities of LxSFNM at 650-800 ℃ in (a) air and (b) 50% CO-50% CO2
(a) Cross-sectional SEM image of the tri-layer symmetrical structure of “porous|dense|porous” LSGM and (b) high magnification view of symmetrical cell, and (c) high-magnification view of impregnated L0.3SFNM catalyst
Nyquist plots of impedance data measured with LxSFNM at 800 ℃ in (a) air and (c) 50% CO-50% CO2; (b, d) DRT curves of impedance data shown in (a, c)
Measured polarization resistances versus the temperature reciprocal in (a) air and (b) 50% CO-50% CO2
(a) I-V curves and (b) impedance spectra measured at the 1.5 V of a single electrolyte-supported electrolysis cell with L0.3SFNM at different temperatures with inset in (b) showing corresponding enlarged spectrum of the cell with L0.3SFNM at 800 ℃, (c) current densities with varied LaxSFNM anodes at 1.5 V under different temperatures, and (d) short-term stability test of the symmetrical SOECs with L0.3SFNM electrode, operating under 800 ℃ at an applied voltage of 1.3 V
  • Table 1. Comparison of literature values of current densities achieved for pure CO2 electrolysis in electrolyte-supported cells at 1.5 V under 800 ℃

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    Table 1. Comparison of literature values of current densities achieved for pure CO2 electrolysis in electrolyte-supported cells at 1.5 V under 800 ℃

    ElectrodeElectrolytePerformance/(A∙cm-2) Ref.
    La0.3Sr0.7Fe0.7Ti0.3O3YSZ0.52 (2V)[27]
    La0.6Sr0.4Fe0.9Mn0.1O3-δ-GDC YSZ1.107 (2V)[25]
    La0.6Sr0.4Fe0.8Ni0.2O3-δ-GDC YSZ1.03[28]
    La0.4Sr0.6Co0.2Fe0.7Nb0.1O3-δYSZ0.442[29]
    La0.6Ca0.4Fe0.8Ni0.2O3-δ-GDC YSZ0.78[13]
    La0.75Sr0.25Cr0.5Mn0.5O3-δYSZ0.09[30]
    La0.3Sr0.7Cr0.3Fe0.7O3-δYSZ0.32[31]
    (PrBa)0.95(Fe0.9Mo0.1)2O5+δLSGM0.51 (1.3V)[32]
    La0.3Sr1.7Fe1.5Ni0.1Mo0.4O6-δLSGM1.17This work
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Yue WANG, Changsong CUI, Shiwei WANG, Zhongliang ZHAN. Symmetrical La3+-doped Sr2Fe1.5Ni0.1Mo0.4O6-δ Electrode Solid Oxide Fuel Cells for Pure CO2 Electrolysis[J]. Journal of Inorganic Materials, 2021, 36(12): 1323

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Paper Information

Category: EDITORIAL

Received: Mar. 26, 2021

Accepted: --

Published Online: Sep. 16, 2022

The Author Email: WANG Yue (wangyue@mail.sic.ac.cn)

DOI:10.15541/jim20210206

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