Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 6, 060201(2023)

Synthesis of functional nonwoven fabric using radiation grafting for the selective adsorption of Au(Ⅲ) in an acidic solution

Xinxin FENG1...2, Xuanzhi MAO1,2, Mingxing ZHANG1, Lijun HU1, Hongwei HAN1, Zhe XING1, Rong LI1,*, and Guozhong WU13,** |Show fewer author(s)
Author Affiliations
  • 1Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2University of Chinese Academy of Sciences, Beijing 100049, China
  • 3School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
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    Figures & Tables(15)
    Synthetic route for NWF-bif
    FTIR spectra of NWF samples before and after modification
    TG and DTG curves of NWF samples before and after modification (color online)
    Water contact angles of NWF samples before and after modification
    SEM images of (a) PE/PP NWF, (b) NWF-g-P(AN-co-AA), (c) NWF-bif, and (d) Au@NWF-bif
    Effect of pH on the Au(Ⅲ) adsorption (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; time, 240 h )(color online)
    (a) Effect of adsorption time on Au(Ⅲ) adsorption capacity; fitting results of (b) pseudo-first-order and (c) pseudo-second-order models (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; pH, 2)
    (a) Adsorption isotherm curve of NWF-bif to Au(III); Fitting results of (b) Langmuir and (c) Freundlich isotherm models (sorbent dosage, 0.1 g/L; time, 240 h; pH, 2)
    Selectivity of NWF-bif in mixed metal ion solution (initial concentration of each ion, 10 mg/L; sorbent dosage, 1 g/L; time, 120 h; pH, 2)
    Optical photos of Au@NWF-bif before and after high-temperature treatment
    Elements distribution of NWF-bif before and after Au(III) adsorption
    (a) XPS spectra of NWF-bif before and after adsorption; (b) Au 4f fine spectra of Au@NWF-bif; (c) XRD spectra of pristine PE/PP NWF, NWF-bif, and Au@NWF-bif; (d) O 1s, (e) N 1s, and (f) S 2p XPS fine spectra of NWF-bif before and after adsorption
    • Table 1. Fitting parameters of kinetic models

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      Table 1. Fitting parameters of kinetic models

      准一级动力学模型 Pseudo-first-order model准二级动力学模型 Pseudo-second-order model
      Qe / mg·g-1k1 / h-1Qecal / mg·g-1R12k2×10-4 / g·(mg·h)-1Qecal / mg·g-1R22
      125.150.03184.780.9851.32153.850.996
    • Table 2. Fitting parameters of isotherm models

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      Table 2. Fitting parameters of isotherm models

      Langmuir等温模型 Langmuir isotherm modelFreundlich等温模型 Freundlich isotherm model
      T/ KQm/ (mg·g-1)KL/ (L·mg-1)RL2T/ KKF/ (g(1-1/n)·(g·L1/n)-1)1/nRF2
      298135.320.851.00029833.890.330.882
    • Table 3. Distribution coefficient (K) of tested metal ions and selectivity coefficient (β) of Au(III)

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      Table 3. Distribution coefficient (K) of tested metal ions and selectivity coefficient (β) of Au(III)

      金属离子 Heavy metal ionsAu(III)Cr(VI)Pt(IV)Cd(II)Co(II)Pb(II)
      分配系数Kdistribution coefficient63.731.160.580.110.100.03
      选择系数βselectivity coefficient/55.00110.78571.60653.542 429.17
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    Xinxin FENG, Xuanzhi MAO, Mingxing ZHANG, Lijun HU, Hongwei HAN, Zhe XING, Rong LI, Guozhong WU. Synthesis of functional nonwoven fabric using radiation grafting for the selective adsorption of Au(Ⅲ) in an acidic solution[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(6): 060201

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    Paper Information

    Category: Research Articles

    Received: Aug. 29, 2023

    Accepted: Oct. 23, 2023

    Published Online: Jan. 3, 2024

    The Author Email: LI Rong (李荣), WU Guozhong (吴国忠)

    DOI:10.11889/j.1000-3436.2023-0071

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