Chinese Optics Letters, Volume. 14, Issue 5, 051603(2016)

Fabrication and characteristics of silicon-rich oxide thin films with controllable compositions

Shiyu Zhang, Quanjun Pan, Xu Fang, Kening Mao, and Hui Ye*
Author Affiliations
  • State Key Laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, China
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    Figures & Tables(5)
    (a) O/Si atomic ratio x of #A samples obtained from the XPS measurements as a function of the OFR. (b) The ratio x of #B samples as a function of the argon flow rate. (c) The ratio x and (d) the deposition rate of #A and #B samples as a function of the oxygen content [O2/(Ar+O2) ratio].
    (a) Transmittance and (b) the refractive indices of SiOx films (#A samples) with various O/Si atomic ratios x values. (c) The refractive index and the extinction coefficient of SiOx films (#A samples) as a function of ratio x at 550 nm wavelength.
    XPS spectra of sample #A1, #A3, #A4, #A5, and #A9, corresponding to the O/Si atomic ratios x of 0.12, 0.63, 0.80, 1.42, and 1.84, respectively. On the left side, the red hollow circles represent the experimental data and the black solid lines are the fitted components (Si0, Si1+, Si2+, Si3+, and Si4+ peaks) of the Si 2p core level and the sum line of the peaks. On the right side, the red dots represent the relative intensities of the components in the Si 2p core level and the black squares are the components calculated according to the RBM model.
    • Table 1. Sets of Sputtering Parameters

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      Table 1. Sets of Sputtering Parameters

      Parameter#A samples#B samples
      O2 flow rate (sccm)0, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.01.0
      Ar flow rate (sccm)2010, 20, 40, 100
      Work pressure (Pa)0.10.1
      RF power (W)500500
    • Table 2. Parameters of Deposited Samples

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      Table 2. Parameters of Deposited Samples

      LabelOxygen content (%)OFR (sccm)Ratio x
      #A22.440.50.28
      #B22.441.00.39
      #A59.092.01.42
      #B49.091.01.30
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    Shiyu Zhang, Quanjun Pan, Xu Fang, Kening Mao, Hui Ye. Fabrication and characteristics of silicon-rich oxide thin films with controllable compositions[J]. Chinese Optics Letters, 2016, 14(5): 051603

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    Paper Information

    Category: Materials

    Received: Jan. 12, 2016

    Accepted: Mar. 4, 2016

    Published Online: Aug. 6, 2018

    The Author Email: Hui Ye (huiye@zju.edu.cn)

    DOI:10.3788/COL201614.051603

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