Journal of Inorganic Materials, Volume. 35, Issue 3, 345(2020)

Adsorption of Iodine by ZIF Materials

Rong LIU, Wei ZHANG, Yuantao CHEN*, Yuanrui FAN, Guangzhang HU, Cheng XU, and Zheng HAN
Author Affiliations
  • School of Chemistry and Chemical Engineering, Qinghai Normal University, Xining 810008, China
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    Figures & Tables(11)
    Standard curve of iodine-cyclohexane after extraction of iodine from water with cyclohexane
    Simulated and experimental XRD patterns of ZIF-8 and ZIF-67
    SEM images of ZIF-8 and ZIF-67 before and after iodine adsorption
    Mapping images and EDS patterns of ZIF-8 and ZIF-67
    TGA curves of ZIF-8 (a) and ZIF-67 (b)
    Nitrogen adsorption and desorption curves of ZIF-8 (a) and ZIF-67 (b)
    ZIF-8 (a) and ZIF-67 (b) adsorption capacity dependences of the initial concentration of the solution
    Iodine adsorption capacity dependence of the adsorption time by ZIF-8 and ZIF-67
    Adsorption mechanism of iodine on ZIF-8 and ZIF-67
    • Table 1. Langmuir and Freundlich parameters for adsorption of iodine by ZIF-8 and ZIF-67

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      Table 1. Langmuir and Freundlich parameters for adsorption of iodine by ZIF-8 and ZIF-67

      ZIF-8ZIF-67
      Langmuir equationQm/(mg·g-1)64416.7177747.64
      kL/(L·mg-1)1.59×10-41.30×10-4
      R20.990.99
      Freundlich equationkF/(mg·g-1)10.0010.84
      n1.000.98
      R21.000.99
    • Table 2. Pseudo first and pseudo second order kinetics parameters for the adsorption of iodine by ZIF-8 and ZIF-67

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      Table 2. Pseudo first and pseudo second order kinetics parameters for the adsorption of iodine by ZIF-8 and ZIF-67

      ZIF-8ZIF-67
      Psedo-first-order kinetics equationQe/(mg·g-1)1010.541047.37
      k1/(L·mg-1)1.30×10-41.49×10-4
      R20.970.93
      Psedo-second-order kinetics equationQe/(mg·g-1)947.61916.08
      k2/(g·min-1·mg-1)0.080.12
      R20.990.96
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    Rong LIU, Wei ZHANG, Yuantao CHEN, Yuanrui FAN, Guangzhang HU, Cheng XU, Zheng HAN. Adsorption of Iodine by ZIF Materials[J]. Journal of Inorganic Materials, 2020, 35(3): 345

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    Paper Information

    Category: RESEARCH PAPER

    Received: Jul. 15, 2019

    Accepted: --

    Published Online: Jan. 27, 2021

    The Author Email: CHEN Yuantao (chenyt@qhnu.edu.cn)

    DOI:10.15541/jim20190351

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