Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 5, 050203(2023)
Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile
Fig. 1. FTIR spectra of the P(AN-co-IA)samples (a) and partial enlarged image (b) (color online)
Fig. 2. Content of IA as a function of ratio of intensities of-COOH to-C≡N
Fig. 3. Different samples were heat treated at 220 ℃ for 30 min: (a) FTIR spectra of P0~P5 samples; (b) FTIR spectra of P0~P5 samples after pretreatment with an absorbed dose of 75 kGy; (c) FTIR spectra of P3 samples after irradiation with different absorbed doses; (d) EOR result chart of all samples
Fig. 4. DSC curves of P(AN-co-IA)powder irradiated at various doses in nitrogen atmosphere(a) 0 kGy; (b) 25 kGy; (c) 50 kGy; (d) 75 kGy; (e) 100 kGy; (f) 200 kGy
Fig. 5. DSC results of samples with different absorbed doses and IA contents: (a) released heat; (b) difference between initiation temperature and termination temperature; (c) velocity of releasing heat
Fig. 6. Influence coefficient of two modification methods on the cyclization reaction of P(AN-co-IA)
Fig. 7. TG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 100 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
Fig. 8. DTG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 75 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
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Wanfeng HONG, Fan ZHANG, Wanning REN, Zhi XIONG, Yarui AN, Wenli ZHANG, Guozhong WU. Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(5): 050203
Category: Research Articles
Received: Nov. 9, 2022
Accepted: Feb. 27, 2023
Published Online: Dec. 27, 2023
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