Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 5, 050203(2023)

Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile

Wanfeng HONG1, Fan ZHANG2, Wanning REN3, Zhi XIONG2, Yarui AN1, Wenli ZHANG2、*, and Guozhong WU2,3、**
Author Affiliations
  • 1University of Shanghai Science and Technology, Shanghai 200093, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3ShanghaiTech University, Shanghai 200031, China
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    Figures & Tables(9)
    FTIR spectra of the P(AN-co-IA)samples (a) and partial enlarged image (b) (color online)
    Content of IA as a function of ratio of intensities of-COOH to-C≡N
    Different samples were heat treated at 220 ℃ for 30 min: (a) FTIR spectra of P0~P5 samples; (b) FTIR spectra of P0~P5 samples after pretreatment with an absorbed dose of 75 kGy; (c) FTIR spectra of P3 samples after irradiation with different absorbed doses; (d) EOR result chart of all samples
    DSC curves of P(AN-co-IA)powder irradiated at various doses in nitrogen atmosphere(a) 0 kGy; (b) 25 kGy; (c) 50 kGy; (d) 75 kGy; (e) 100 kGy; (f) 200 kGy
    DSC results of samples with different absorbed doses and IA contents: (a) released heat; (b) difference between initiation temperature and termination temperature; (c) velocity of releasing heat
    Influence coefficient of two modification methods on the cyclization reaction of P(AN-co-IA)
    TG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 100 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
    DTG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 75 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
    • Table 1. Aggregate acquired PAN-co-IA samples

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      Table 1. Aggregate acquired PAN-co-IA samples

      聚合物

      Polymer

      丙烯腈 / mL

      AN

      丙烯腈 / g

      AN

      衣康酸 / g

      IA

      IA质量分数 / %

      IA mass fraction

      过硫酸铵 / g

      APS

      转化率 / %

      Conversion ratio

      P041.033.00000.3390.33
      P140.532.600.330 21.00.3391.14
      P240.332.450.495 01.50.3389.98
      P340.132.300.660 12.00.3390.60
      P439.732.100.990 23.00.3389.70
      P539.331.681.320 64.00.3391.35
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    Wanfeng HONG, Fan ZHANG, Wanning REN, Zhi XIONG, Yarui AN, Wenli ZHANG, Guozhong WU. Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(5): 050203

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    Paper Information

    Category: Research Articles

    Received: Nov. 9, 2022

    Accepted: Feb. 27, 2023

    Published Online: Dec. 27, 2023

    The Author Email:

    DOI:10.11889/j.1000-3436.2022-0123

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