Journal of Inorganic Materials, Volume. 39, Issue 1, 61(2024)

Ablation Resistance of High-entropy Oxide Coatings on C/C Composites

Lingxiang GUO, Ying TANG, Shiwei HUANG, Bolan XIAO, Donghao XIA, and Jia SUN*
Author Affiliations
  • State Key Laboratory of Ultra High Temperature Composite Materials, Shaanxi Key Laboratory of Fiber Reinforced Light Composite Materials, Northwestern Polytechnical University, Xi’an 710072, China
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    Figures & Tables(19)
    Phase characterizations of high-entropy oxide powders
    TEM analyses of M2R3O powders
    Surface and cross-section morphologies of high-entropy oxide coatings
    XRD patterns of high-entropy oxide coatings
    Binary phase diagrams of HfO2-RE2O3 and ZrO2-RE2O3 (RE=Sm, Er and Y)[30]
    Surface temperature curves of high-entropy oxide coatings during ablation
    Macro morphologies of high-entropy oxide coatings after ablation
    Mass ablation ratios and line ablation ratios of high- entropy oxide coatings
    XRD patterns of high-entropy oxide coatings after ablation
    Cross-section morphologies and EDS analyses of high-entropy oxide coatings after cyclic ablation for 180 s(a-c) M1R3O; (d-f) M2R3O; (g-i) M3R3O
    Comparison of ablation resistances between high-entropy oxide coatings and other coatings in the same ablation environment
    TEM analysis of M1R3O powders
    TEM analysis of M3R3O powders
    XRD refinement patterns of high-entropy oxide powders
    Thermal conductivities of high-entropy oxides
    Surface microstructures of high-entropy oxide coatings after ablation (a-c) M2R3O coatings; (d-f) M3R3O coatings
    • Table 1. EDS element point scanning analysis

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      Table 1. EDS element point scanning analysis

      HfZrSmErYSiO
      Spot A/(%, in atom)10.55.69.38.58.457.7
      Spot B/(%, in atom)5.64.75.18.710.43.861.7
    • Table 1. Compositions and component molar ratios of high-entropy oxides in this study

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      Table 1. Compositions and component molar ratios of high-entropy oxides in this study

      LabelConstituent$\frac{n(\text{Hf}+\text{Zr})}{n(\text{Sm}+\text{Er}+\text{Y})}$
      M1R3O(Hf0.125Zr0.125Sm0.25Er0.25Y0.25)O2-δ1/3
      M2R3O(Hf0.2Zr0.2Sm0.2Er0.2Y0.2)O2-δ2/3
      M3R3O(Hf0.25Zr0.25Sm0.167Er0.167Y0.167)O2-δ3/3
    • Table 2. Parameters of SAPS for high-entropy oxide coatings

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      Table 2. Parameters of SAPS for high-entropy oxide coatings

      ParameterValue
      Current/A410-430
      Voltage/V100-120
      Primary gas Ar/(L·min-1)65-70
      Second gas H2/(L·min-1)3.5-5.0
      Powder flow Ar/(L·min-1)5-7
      Spray distance/mm100
      Powder feed rate/(g·min-1)5-6
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    Lingxiang GUO, Ying TANG, Shiwei HUANG, Bolan XIAO, Donghao XIA, Jia SUN. Ablation Resistance of High-entropy Oxide Coatings on C/C Composites[J]. Journal of Inorganic Materials, 2024, 39(1): 61

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    Paper Information

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    Received: Aug. 14, 2023

    Accepted: --

    Published Online: Mar. 28, 2024

    The Author Email: SUN Jia (j.sun@nwpu.edu.cn)

    DOI:10.15541/jim20230370

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