Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 6, 060403(2023)
Degradation of patulin and effect of flavor component in apple juice by glow discharge plasma (GDP)
Figures & Tables(11)
Fig. 3. High performance liquid chromatography of patuli and apple juice
Fig. 4. Effects of pH on degradation rate of patulin in apple juice
Fig. 5. Total ion currentchromatogram of GC-MS of GDP treatment apple juice
Fig. 6. Effects of GDP treatment on the total phenolic content of apple juice
Fig. 7. Effect of GDP treatment on the quality of apple juice: (a) soluble solid content, (b) conductivity, (c) redox potential, and (d) pH
Table 1. Oualitative and quantitative analysis results of Flavor Substances in apple juice
View tableView in ArticleTable 1. Oualitative and quantitative analysis results of Flavor Substances in apple juice
序号
No.
CAS号
CAS No.
化合物
Compounds
分子式
Chemical formula
相对分子质量
Relative mole-
cular mass
相对含量
Relative content / %
0 5 10 15 20 醇类Alcohols 1 71-36-3 正丁醇 1-Butanol C4H10O 74.12 – – – – 0.3 2 78-70-6 芳樟醇 Linalool C10H18O 154.25 0.09 0.13 0.17 – – 3 111-87-5 辛醇 1-Octanol C8H18O 130.23 – 0.11 – 0.05 – 4 34995-77-2 反-Α,Α-5-三甲基-5-
乙烯基四氢化-2-呋喃甲醇
Tetrahydro-alpha,alpha,5-
trimethyl-5-vinylfuran-2-methanol
C10H18O2 170.25 – 0.04 – – – 5 15356-70-4 DL-薄荷醇 D,1-menthol C10H20O 156.27 0.06 – – – – 6 5989-33-3 顺-Alpha,Alpha-5-三甲基-5-乙烯基四氢化呋喃-2-甲醇
Cis-alpha,alpha,5-trimethyl-5-vinyltetrahydrofuran-2-methanol
C10H18O2 170.25 – – – 0.10 0.09 7 137-32-6 2-甲基丁醇 2-methyl-1-butano C5H12O 88.15 2.34 3.29 3.11 3.43 3.67 8 111-27-3 正己醇 1-Hexanol C6H14O 102.17 3.76 5.09 5.21 5.24 5.49 9 104-76-7 2-乙基乙醇 2-Ethylhexanol C8H18O 130.23 0.19 0.18 – – – 10 03913-2-8 2-丁基-1-辛醇 2-Butyl-1-octanol C12H26O 186.33 0.04 – – – – 11 619-1-2 二氢香芹醇 Dihydrocarvol C10H18O 154.25 – 0.10 – – – 12 6909-21-3 [1S，3R，5S，6R，（-）-胡萝卜素-5-醇
[1S,3R,5S,6R,(-)]-Carane-5-ol
C10H18O 154.25 0.11 – – – – 总计 Total 6.59 8.94 8.49 8.82 9.55 醛类Aldehyde 1 66-25-1 正己醛Hexanal C6H12O 100.16 6.17 6.41 6.06 8.79 3.48 2 6728-26-3 反式-2-己烯醛 Trans-Hex-2-enal C6H10O 98.14 0.13 – – – – 3 112-31-2 癸醛 Decyl aldehyde C10H20O 156.27 0.32 0.21 0.13 0.17 0.24 4 15764-16-6 2,4-二甲基苯甲醛
2,4-Dimethylbenzaldehyde
C9H10O 134.18 – 0.06 – 0.04 – 5 112-54-9 十二醛 Dodecyl aldehyde C12H24O 184.32 – 0.04 0.06 0.04 – 6 17540-75-9 6-溴吲哚-3-甲醛
-Bromo indole-3-formaldehyde
C18H30O 262.43 – – – – 0.05 7 1620-98-0 3,5-二叔丁基-4-羟基苯甲醛
3,5-Di-tert-butyl-4-hydroxybenzaldehyde
C15H22O2 234.33 – – 0.08 – – 8 124-13-0 正辛醛 Octanal C8H16O 128.21 – – 0.16 0.09 0.08 9 23074-10-4 5-乙基-2-糠醛
5-Ethyl-2-furfural
C7H8O2 124.14 – – 0.05 0.14 – 10 2548-87-0 E-2-辛烯醛 (E)-2-Octenal C8H14O 126.20 – – – 0.33 0.28 11 20407-84-5 反-2-十二烯醛 (E)-dodec-2-enal C12H22O 182.30 – – – – 0.71 12 529-20-4 2-甲基甲苯甲醛
2-Methylbenzaldehyde
C8H8O 120.15 – – – 0.08 – 13 620-23-5 3-甲基苯甲醛
3-Methyl-benzaldehyd
C8H8O 120.15 – – – – 0.21 14 124-19-6 壬醛 1-Nonanal C9H18O 142.24 – 0.37 – – – 15 505-57-7 2-己烯醛 hex-2-enal C6H10O 98.14 13.18 13.71 12.01 10.47 7.58 16 620-2-0 5-甲基呋喃醛
5-Methyl furfural
C6H6O2 110.11 – 0.86 1.74 2.98 5.72 17 28785-6-0 4-丙基苯甲醛
4-Propylbenzaldehyde
C10H12O 148.20 – 0.04 0.06 – – 18 75853-51-9 13-甲基十四醛
13-Methyltetradecanal
C15H30O 226.40 0.08 – – – – 总计 Total 19.88 21.7 20.35 23.13 18.35 酯类Esters 1 123-86-4 乙酸丁酯 Butyl acetate C6H12O2 116.16 10.92 10.27 9.98 8.79 5.55 2 624-41-9 2-甲基丁基乙酸酯
2-Methylbutyl acetate
C7H14O2 130.18 25.34 24.51 22.94 20.81 13.01 3 105-66-8 丁酸丙酯 Propyl butyrate C7H14O2 130.18 1.07 0.92 0.78 0.69 13.01 4 109-21-7 丁酸丁酯 Butyl butyrate C8H16O2 144.21 – – 2.20 1.44 1.08 5 25415-84-3 丁酸2-乙基己酯
2-Ethylhexyl butanoate
C12H24O2 200.32 – – 0.22 – – 6 2438-20-2 丙酸2-甲基丁酯
2-Methylbutyl propionate
C8H16O2 144.21 – 0.07 – – – 7 109-21-7 丁酸丁酯 Butyl butyrate C8H16O2 144.21 3.26 2.41 – – – 8 5048-26-0 乙酸5-己烯基酯
5-Hexen-1-ol, 1-acetate
C8H14O2 142.20 0.18 0.15 – – – 9 142-92-7 乙酸正己酯 Hexyl acetate C8H16O2 144.21 15.52 11.40 – 7.89 5.28 10 590-1-2 丙酸丁酯 Butyl propionate C7H14O2 130.18 0.39 0.39 0.35 0.39 – 11 628-63-7 乙酸戊酯 Amyl acetate C7H14O2 130.18 1.45 1.40 1.25 1.13 0.9 12 37064-20-3 2-甲基丁酸丙酯
2-Methyl-butanoicacipropylester
C8H16O2 144.21 0.32 0.21 0.17 – – 13 539-90-2 丁酸异丁酯 Isobutyl butyrate C8H16O2 144.21 – 0.08 – – – 14 112-32-3 甲酸辛酯 1-octylformate C9H18O2 158.24 – – 0.09 – – 15 37064-20-3 2-甲基丁酸丙酯
2-Methylbutyric acid propyl ester
C8H16O2 144.21 – 1.02 – – – 16 2445-69-4 异丁酸异戊酯
2-Methylpropanoic acid 2-methylbutyl ester
C9H18O2 158.24 – 0.18 – – – 17 6846-50-0 2,2,4-三甲基-1,3-戊二醇二异丁酸酯 Bisisobutyric acid 2,2,4-trimethyl-1,3-pentanediyl C16H30O4 286.41 0.13 – – – – 18 110-27-0 肉豆蔻酸异丙酯
Isopropyl myristate
C17H34O2 270.45 0.50 0.23 0.19 0.24 0.28 19 15706-73-7 3-甲基丁酸丁酯
Butyl 2-methylbutyrate
C9H18O2 158.24 1.45 – – – – 20 51115-64-1 丁酸-2-甲基丁酯
2-Methylbutyl butyrate
C9H18O2 158.24 0.21 – – – – 21 626-77-7 己酸丙酯 Caproic acid propyl ester C9H18O2 158.24 0.43 0.15 - - - 22 68039-26-9 2-甲基丁酸戊酯
2-Methyl-butanoicacipentylester
C10H20O2 172.26 0.06 – – – – 23 02349-7-7 异丁酸己酯 Hexyl isobutyrate C10H20O2 172.26 0.07 – – – – 24 2639-63-6 丁酸己酯 Hexyl butyrate C10H20O2 172.26 2.58 – 0.21 0.12 – 26 10032-15-2 异戊酸己酯 Hexyl 2-methylbutyrate C11H22O2 186.29 1.99 0.14 0.13 – – 27 626-77-7 己酸丙酯 Caproic acid propyl ester C9H18O2 158.24 – – 0.12 – – 28 77-68-9 3-羟基-2,2,4-三甲基戊基异丁酸酯
3-Hydroxy-2,2,4-trimethylpentyl isobutyrate
C12H24O3 216.32 0.07 0.05 0.04 – – 29 2601-13-0 2-甲基丁基己酸酯
2-Methylbutyl caproate
C11H22O2 186.29 0.11 – – – – 30 4887-30-3 辛基己酸酯
Caproic acid octyl ester
C14H28O2 228.37 0.12 – – – – 31 6378-65-0 己酸己酯 Hexyl hexanoate C12H24O2 200.32 0.98 – – – – 32 84-69-5 邻苯二甲酸二异丁酯
Diisobutyl phthalate
C16H22O4 278.34 0.28 0.05 0.04 0.05 – 33 84-74-2 邻苯二甲酸二丁酯
Dibutyl phthalate
C16H22O4 278.34 0.07 – – – – 34 70969-70-9 己酸-3,5,5-三甲基-2-乙基酯 2-Ethylhexyl 3,5,5-trimethylhexanoate C17H34O2 270.45 0.33 – – – – 35 609-8-5 甲基丙二酸二乙酯
Diethyl methylmalonate
C8H14O4 174.19 – – 0.04 – – 总计 Total 67.83 53.94 38.75 41.55 39.11 酮类Ketones 1 585-74-0 3-甲基苯乙酮
3-Methylacetophenone
C9H10O 134.18 – – – – 0.18 2 118-93-4 2-羟基苯乙酮
2-Hydroxyacetophenone
C8H8O2 136.15 – – – – 0.29 3 93-55-0 苯丙酮 Propiophenone C9H10O 134.18 – – – – 0.11 4 98-86-2 苯乙酮 Acetophenone C8H8O 120.15 – 0.07 0.18 0.33 0.73 5 13019-20-0 2-甲基-3-庚酮
2-methylheptan-3-one
C8H16O 128.21 – – – – 1.6 6 110-93-0 6-甲基-5-庚烯-2-酮
6-Methyl-5-hepten-2-one
C8H14O 126.20 – – – 0.06 – 7 37112-31-5 左旋葡萄糖酮
Levoglucone
C6H6O3 126.11 – – 0.05 0.06 – 8 93-55-0 苯丙酮 Propiophenone C9H10O 134.18 – – – 0.06 – 9 689-67-8 6,10-二甲基-5,9-十一双烯-2-酮
6,10-Dimethyl-5,9-undecadien-2-one
C13H22O 194.31 – 0.04 0.03 0.04 0.06 10 10396-80-2 2,6-二(叔丁基)-4-羟基-4-甲基-2,5-环己二烯-1-酮
2,6-Di(tert-butyl)-4-hydroxy-4-methyl-2,5-cyclohexadien-1-one
C15H24O2 236.35 0.62 0.24 0.16 0.11 0.11 11 81944-8-3 反式 -3-丁内酯-4,5-
二氢异苯并呋喃-1（3H）-酮
Trans-3-butanolactone-4,5-dihydroisobenzofuran-1 (3H)-one
C12H14O2 190.24 0.89 0.85 0.22 – – 12 10408-15-8 2-甲基-1-庚烯-6-酮
2-Methyl-1-heptene-6-one
C8H14O 126.20 – – – – 0.07 13 136230-43-8 10-甲基-3,4,5,8,9,10-六氢-2H-氧辛-2-酮 10-Methyl-3,4,5,8,9,10-hexahydro-2H-oxecin-2-one C8H14O 126.20 – – – – 0.05 14 122-0-9 对甲基苯乙酮
Methylacetophenone
C9H10O 134.18 – – – 0.08 0.02 总计 Total 1.51 1.2 0.64 0.74 3.22 其他 Others 1 271-89-6 2,3-苯并呋喃 Benzofuran C8H6O 118.14 – – – 0.48 0.76 2 1197-40-6 2-(呋喃-2-基甲基)呋喃
2,2-Methylenebisfuran
C9H8O2 148.16 – – 0.10 0.06 – 3 13678-51-8 5-甲基-2-糠基呋喃
2-Furfuryl-5-methylfuran
C10H10O2 162.19 – – 0.05 0.11 0.22 4 13679-43-1 氰化四乙基铵
Tetraethyl ammonium cyanide
C11H12O2 176.21 – – 0.03 – – 5 719-22-2 2,6-二叔丁基苯醌
2,6-Di-tert-butyl-p-benzoquinone
C14H20O2 220.31 - - - 0.05 0.04 6 2460-77-7 2,5-二叔丁基-1,4-苯醌
2,5-Di-tert-butyl-1,4-benzoquinone
C14H20O2 220.31 – 0.06 0.05 0.04 0.05 7 96-76-4 2,4-二叔丁基苯酚
2,4-Di-tert-butylphenol
C14H22O 206.32 – – – – 0.12 8 128-37-0 2,6-二叔丁基对甲酚
2,6-Di-tert-butyl-4-methylphenol
C15H24O 220.35 3.72 1.14 0.94 1.27 0.66 9 72917-31-8 Z-亚丁基苯酞
(Z)-Butylidenephthalide
C12H12O2 188.22 0.35 0.22 – – – 10 10522-34-6 2-甲基壬酯丙酸
Propanoic acid, 2-methyl-, nonyl ester
C13H26O2 214.34 – 0.17 – – – 总计 Total 4.07 1.59 1.17 2.09 1.87
Table 2. Effect of GDP treatment on the color of apple juice and apple blocks
View tableView in ArticleTable 2. Effect of GDP treatment on the color of apple juice and apple blocks
处理时间 / min
Processing time
亮度
Brightness
色调
Tone
色度
Chrominance
色差
Chromatism
苹果块Apple chunks
0
5
10
15
20
25
30
70.09±0.03
70.10±0.03
70.16±0.02
70.19±0.02
70.24±0.01
70.30±0.02
70.31±0.02
94.23±0.01
94.16±0.01
93.89±0.01
93.75±0.02
93.65±0.01
93.85±0.02
93.56±0.01
36.54±0.03
36.17±0.02
37.69±0.02
36.41±0.01
39.80±0.01
40.82±0.01
40.51±0.01
0
2.04±0.02
2.96±0.01
1.18±0.01
2.06±0.01
1.15±0.01
1.18±0.01
苹果汁Apple juice
0
5
10
15
20
25
30
62.12±0.02
64.90±0.03
65.12±0.02
65.37±0.01
65.73±0.01
67.59±0.02
69.53±0.01
95.33±0.01
94.83±0.01
94.09±0.01
93.05±0.02
92.95±0.01
92.82±0.02
90.47±0.01
30.89±0.03
34.61±0.03
35.27±0.03
36.46±0.03
36.77±0.03
37.80±0.03
37.85±0.03
0
3.32±0.02
4.09±0.02
4.24±0.01
5.47±0.01
5.74±0.01
5.83±0.01
Tools
Get Citation
Copy Citation Text
Zhaodi LI, Ting WANG, Wan LI, Hongsheng TANG, Haitao LONG, Weibing XU, Lumei PU. Degradation of patulin and effect of flavor component in apple juice by glow discharge plasma (GDP)[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(6): 060403
Paper Information
Category: Research Articles
Received: May. 30, 2023
Accepted: Aug. 12, 2023
Published Online: Jan. 3, 2024
The Author Email: PU Lumei (蒲陆梅)
© Copyright 2018-2021 | Chinese Laser Press.
All Rights Reserved 沪ICP备15018463号-20