Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 4, 040202(2023)

Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation

Wenhui YU1...2, Jialong TIAN2,3, Jiang PAN2, Chenchen JIANG2, Zhenming QI2, Chuanfeng ZANG1 and Chunxia WANG2,* |Show fewer author(s)
Author Affiliations
  • 1School of Textile and Garment, Nantong University, Nantong 226019, China
  • 2School of Textile and Garment, Yancheng Institute of Technology, Yancheng 224001, China
  • 3School of Textile and Garment, Xi'an Polytechnic University, Xi'an 710000, China
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    Figures & Tables(14)
    Synthesis of DA
    Chemical reaction of cotton fabric and DA
    1HNMR spectrum of DA
    SEM images: (a) cotton fabric (×5 000); (b) flame resistant cotton fabric (×5 000); (c) char layer of flame resistant cotton fabric after burning (×5 000), and (d) char layer of flame resistant cotton fabric after burning (×500)
    EDS: (a) cotton fabric, (b) flame resistant cotton fabric (500 g/L) and (c) char layer of flame resistant cotton fabric after burning
    FTIR spectra: (a) DA; (b) cotton fabric; (c) flame resistant cotton fabric (500 g/L)
    Effects of DA mass concentration on WG and LOI of cotton fabric
    Effects of MBA mass concentration on WG and LOI of cotton fabric
    Vertical burning photos: (a) cotton fabric; (b) flame resistant cotton fabric (300g/l); (c) flame resistant cotton fabric (400g/l); (d) flame resistant cotton fabric (500g/l)
    Effect of washing cycles on LOI of cotton fabric
    TG and DTG curves of cotton fabric and flame resistant cotton fabric: (a) TG in N2, (b) DTG in N2, (c) TG in air and (d) DTG in air
    Effects of DA mass concentration on tensile breaking strength of cotton fabric
    • Table 1. Vertical burning data of different DA mass concentration finishing cotton fabrics

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      Table 1. Vertical burning data of different DA mass concentration finishing cotton fabrics

      样品

      Sample

      原棉

      Cotton fabric

      阻燃棉织物

      Flame resistant cotton

      fabric

      DA质量浓度 / (g‧L-1)

      DA mass concentration

      0300400500

      续燃时间 / s

      Afterflame time

      16.60.00.00.0

      阴燃时间 / s

      Afterglow time

      49.950.00.00.0

      炭长 / cm

      Char length

      >308.54.23.9
    • Table 2. TG data of cotton fabrics in N2 and air

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      Table 2. TG data of cotton fabrics in N2 and air

      样品

      Samples

      气氛

      Atmosphere

      T5% / ℃Tmax1 / ℃Tmax2 / ℃

      600 ℃时的残余质量 / %

      Residual mass at 600 ℃

      棉织物

      Cotton fabric

      氮气

      N2

      26037814.28

      阻燃棉织物 (500 g/L)

      Flame resistant cotton fabric (500 g/L)

      9334434

      棉织物

      Cotton fabric

      空气

      Air

      2783284610.51

      阻燃棉织物 (500 g/L)

      Flame resistant cotton fabric (500 g/L)

      11928211.54
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    Wenhui YU, Jialong TIAN, Jiang PAN, Chenchen JIANG, Zhenming QI, Chuanfeng ZANG, Chunxia WANG. Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(4): 040202

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    Paper Information

    Category: Research Articles

    Received: Dec. 8, 2022

    Accepted: Feb. 20, 2023

    Published Online: Sep. 21, 2023

    The Author Email:

    DOI:10.11889/j.1000-3436.2022-0133

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