Infrared and Laser Engineering, Volume. 53, Issue 4, 20240116(2024)

Silicon based hot electron short wave infrared detection technology (cover paper·invited)

Xinhao Wen1,2, Yu Jia1,2, Leyong Yu2, Li Shao2, Hui Chen2, Chaojie Xia1,2, Linlong Tang2, and Haofei Shi2、*
Author Affiliations
  • 1School of Optoelectronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing 400065, China
  • 2Chongqing Key Laboratory of Multi-scale Manufacturing Technology, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
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    Figures & Tables(17)
    Schematic diagram of the formation principle of metal-silicon Schottky junction. (a) Energy band diagram before the contact between metal and silicon; (b) Energy band diagram of Schottky junction after the contact between metal and N-type silicon; (c) Energy band diagram of Schottky junction after the contact between metal and P-type silicon; (d) Typical current-voltage characteristic curve of Schottky junction
    The process of energy transfer and loss in the three stages of hot electron generation, transport, and injection
    Effect of metal material type on initial energy distribution of hot electrons
    (a) The scattering process and time scale of hot electrons; (b) the relationship between the mean free path of hot electrons scattered by electrons and phonons and the energy of hot electron
    The conical distribution of the momentum of hot electrons that can be injected into silicon
    (a), (b) Schematic diagram of a photodetector based on a one - and two-dimensional metamaterial perfect absorber; (b), (c) and (e), (f) are the absorption and response curves corresponding to the detectors in figure (a) and (b), respectively
    (a) Schematic diagram of the Tamm plasmon enhanced thermal electron detector; (b) Comparison diagram of its responsiveness with the grating coupled enhanced thermionic detector
    (a) Schematic diagram of a random structure enhanced thermionic detector; (b) Absorption spectra of Au/SiNH structures prepared at different annealing temperatures; (c) The responsiveness of Au/SiNH devices with different Au coating thicknesses; (d) Responsiveness under different lighting modes; (e) Scanning electron microscopy (SEM) images of Au/SiNH prepared by annealing at different temperatures
    The frequency variation of the percentage of heat loss, geometrical assist, phonon assist and direct transition to the total absorbed energy in (a) semi-infinite surface, (b) 40 nm, (c) 20 nm and (d) 10 nm diameter spheres
    (a) Structure diagram of silver nanorod array detector; (b) The initial position of hot electron generation in the detector
    (a) The channel antenna structure detector in the front light (left) back light (right) detection diagram; (b) Response curves of gold-silicon microcone detectors in front and back irradiation modes
    (a) The proportion of three main thermoelectronic loss mechanisms of Au and Pt Schottky detectors at 1510 nm; (b) Quantitative comparison of the external quantum efficiency of six metal Schottky detectors with a thickness of 20 nm; (c) The five metals Cu, Ni, Ag, Au, Pt pair absorption rate, injection probability, mean free path and quantum efficiency
    (a) From left to right, the band structure of aluminum, silver, copper and gold and the relationship between the hot carrier energy distribution and the incident photon energy are shown (The above figure shows the position of the possible transition of hot electrons in the energy band, and the following figure shows the energy distribution of hot carriers); (b) From left to right are the directional distributions of energy and momentum for aluminum, silver, copper and gold (The above figure shows the direction distribution of energy and momentum of hot electrons, and the following figure shows the direction distribution of energy and momentum of holes)
    The relationship between the energy distribution of (a) aluminum, (b) silver, (c) copper and (d) gold and the energy of incident photons(Among them, the above figure shows the position of the possible transition of hot electrons in the energy band, and the following figure shows the energy distribution of hot carriers)
    (a) Metal/TiO2−x/p-Si detector structure and its effect on photoelectric response; (b) Rough interface diagram; (c) The relationship between the probability of hot electron injection and electron energy under different roughness of metal semiconductor interface, the smaller Λ indicates the larger roughness. (d) Band diagram of metal-semiconductor junction after introduction of quantum well. The dashed line is the Schottky barrier, and the quasi-discrete energy levels in the quantum well are represented by the thick red line
    (a) Nanowire structures made of silicon with gold-silicon Schottky junction; (b) Schematic diagram of band structure at the silicon nanowire/gold antenna interface
    • Table 1. Summary of silicon-based hot electron shortwave infrared detectors in recent years

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      Table 1. Summary of silicon-based hot electron shortwave infrared detectors in recent years

      Device type/Enhancement strategyResponsivityDark current/Dark current densityDetectivity/JonesNEP/W·Hz−1/2Year
      Au film on Si nanobowl[35]Hot electron generation0.34 mA·W−1@1300 nm0.29 mA·W−1@1500 nm2.5×10−7 ANone8.3×10−102021
      Disordered Au/Si nanoneedles[50]Hot electron generation2.56 mA·W−1@1300 nm0.33 mA·W−1@1500 nm4×10−10 ANone4.4×10−12@1300 nm2023
      Au antennas/Ti/Si[51]Hot electron generation10 μA·W−1@1250 nm3 μA·W−1@1550 nmNoneNoneNone2011
      Deep-trench/thin Au/Si antenna[52]Hot electron generation3 mA·W−1@1300 nm1.25 mA·W−1@1400 nm0.5 mA·W−1@1550 nm8.7×10−9 A·cm−25.68 ×10102.37 ×10109.47 ×109None2014
      Metamaterial Au/Si[53]Hot electron generation3 mA·W−1@1300 nmNoneNoneNone2014
      Two distributed Bragg reflectors (DBRs)Al2O3/TiO2 Al2O3/TiO2/Au[54]Hot electron generation27 mA·W−1@813 nmNoneNoneNone2021
      Disordered Au Si NHs[55]Hot electron generation1.5-13 mA·W−1@1100-1500 nm1×10−6 ANone4.75×10−11-3.77×10−102018
      Au grating/Si[16]Hot electron generation0.6 mA·W−1@1460 nmNoneNoneNone2013
      Material-embeddedTrenchlike thin Au/Si[61]Hot electron generation5854 nA·mW−1@1310 nm693 nA·mW−1@1550 nmNoneNoneNone2019
      Au/Si pyramid [22]Hot electron generation5.2 mA·W−1@1200 nmNoneNoneNone2020
      Au NWs embedded in Si[66]Hot electron injection0.065 mA·W−1@1500 nm1×10−9 A3.63×1062.75×10−102013
      TiN/thin Au stripeembedded in Si[68]Hot electron injectionExceed 1.0 A·W−1@1550 nmNoneNoneNone2016
      Thin film TiN/p-Si[69]Hot electron injection1 mA·W−1@1250 nm3×10−10 A6.12×1089.8×10−122019
      Waveguide-based Al/Si[70]Hot electron injection12.5 mA·W−1@1550 nm (0.1 V)3×10−8 A(0.1 V)None7.84×10−122012
      Metasurface Au/Si[73]Hot electron transferand injection94.5 mA·W−1@1150 nm (1.5 V)1.45×10−7A·cm−24.38 ×1011None2019
      Partially metalizing thepyramid Al/SiO2/Si[34]Dark current suppressionNoneReduce by2 timesNoneNone2021
      Graphene/Al2O3/Ge[74]Dark current suppression1.2 A·W−1@1550 nm (2 V)1×10−6 ANoneNone2021
      Interface engineeringassisted graphene/Si[75]Dark current suppressionNone@890 nm7.2×10−10 A9.3×10121.8×10−122022
      ITO/ Thin Ag/n-Si[76]Dark current suppression0.05 A·W−1@1550 nm (2 V)2.4×10−6A/cm2 (−1 V)NoneNone2018
      Thin ITO/Au/Au Nanoparticle/n-Si[43]Dark current suppression2.82 mA·W−1@1310 nm(−1 V)4.4×10−5A/cm2 (−1 V)NoneNone2022
      Graphene withpolyethyleneimine/p-Si[77]Dark current suppression0.3 A·W−1@850 nm2.4×10−10 A5.9×1010None2021
      NanoalloysAu40Ag60/Si[78]Hot electron transfer7.3 mA·W−1@1310 nm1.9 mA·W−1@1550 nmNoneNoneNone2024
      Au/crystallized Ge/Si[79]Hot electron injection0.71 A·W−1@1310 nm0.64 A·W−1@1550 nm (1 V)NoneNoneNone2022
      TalrTe4/Si[80]Hot electron transfer14 mA·W−1@1310 nm1.32 mA·W−1@1550 nmNoneNoneNone2022
      Mo2C/MoGeSiN4/Si[81]Hot electron transfer176 mA·W−1@1550 nmNoneNoneNone2022
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    Xinhao Wen, Yu Jia, Leyong Yu, Li Shao, Hui Chen, Chaojie Xia, Linlong Tang, Haofei Shi. Silicon based hot electron short wave infrared detection technology (cover paper·invited)[J]. Infrared and Laser Engineering, 2024, 53(4): 20240116

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    Paper Information

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    Received: Mar. 14, 2024

    Accepted: --

    Published Online: Jun. 21, 2024

    The Author Email: Shi Haofei (shi@cigit.ac.cn)

    DOI:10.3788/IRLA20240116

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