Spectroscopy and Spectral Analysis, Volume. 41, Issue 9, 2807(2021)

An EDXRF Quantitative Algorithm Based on Fundamental Parameters and Spectrum Unfolding

Ming-bo LIU1、*, Xue-liang LIAO2、2;, Da-wei CHENG1、1; 2;, Zi-yue NI1、1; 2;, and Hai-zhou WANG1、1; 2; *;
Author Affiliations
  • 11. Central Iron and Steel Research Institute, Beijing 100081, China
  • 22. NCS Testing Technology Co., Ltd., Beijing 100081, China
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    Figures & Tables(6)
    Comparation of origin spectrum and optimized by pure spectrums
    Flowchart of algorithm
    Comparation of pure spectrum and its updated
    Comparation of origin spectrum and optimized by updated pure spectrums
    • Table 1. Tested results and certified

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      Table 1. Tested results and certified

      样品名称La/%Ce/%Pr/%Nd/%
      标称值15.3353.8215.0715.78
      STD实测值15.6254.1314.9315.32
      偏差0.290.31-0.14-0.46
      标称值26.2273.78
      PN实测值26.6573.35
      偏差0.43-0.43
      标称值89.276.034.70
      CPN实测值89.625.824.56
      偏差0.35-0.21-0.14
      标称值39.7256.232.032.02
      LCPN1实测值40.3056.121.901.68
      偏差0.58-0.11-0.13-0.34
      标称值17.3260.175.9816.53
      LCPN2实测值17.1759.386.2417.21
      偏差-0.15-0.790.260.68
      标称值83.3714.290.831.51
      LCPN3实测值83.8314.390.511.27
      偏差0.460.10-0.32-0.24
      标称值29.8351.284.5814.31
      LCPN4实测值29.4151.275.1914.13
      偏差-0.42-0.010.61-0.18
    • Table 2. Tested results of stability

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      Table 2. Tested results of stability

      元素名称La/%Ce/%Pr/%Nd/%
      115.4753.0915.3616.08
      215.8153.2315.1715.79
      315.4453.4115.3815.77
      415.4753.6215.2115.71
      515.4353.3915.0916.08
      615.6153.2915.3715.72
      715.7153.4915.0115.79
      815.6253.4015.0115.95
      915.5953.2915.1915.94
      1015.7553.3915.2315.63
      1115.4853.4015.2915.83
      标称值15.3353.8215.0715.78
      相对标准偏差RSD/%0.860.260.880.95
      极差0.380.530.370.46
      最大偏差0.480.730.310.30
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    Ming-bo LIU, Xue-liang LIAO, Da-wei CHENG, Zi-yue NI, Hai-zhou WANG. An EDXRF Quantitative Algorithm Based on Fundamental Parameters and Spectrum Unfolding[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2807

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    Paper Information

    Category: Research Articles

    Received: Sep. 21, 2020

    Accepted: --

    Published Online: Oct. 29, 2021

    The Author Email: LIU Ming-bo (liumingbo@ncschina.com)

    DOI:10.3964/j.issn.1000-0593(2021)09-2807-05

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