Nano-Micro Letters, Volume. 15, Issue 1, 238(2023)

Atomic Cu Sites Engineering Enables Efficient CO2 Electroreduction to Methane with High CH4/C2H4 Ratio

Minhan Li1...2,†, Fangzhou Zhang1,†, Min Kuang1, Yuanyuan Ma1,*, Ting Liao3, Ziqi Sun3, Wei Luo1, Wan Jiang1 and Jianping Yang1,** |Show fewer author(s)
Author Affiliations
  • 1Institute of Functional Materials, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, People’s Republic of China
  • 2College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, People’s Republic of China
  • 3School of Mechanical, Medical and Process Engineering, School of Chemistry and Physics, Queensland University of Technology, 2 George Street, Brisbane, QLD 4001, Australia
  • show less
    References(63)

    [6] [6] Y. Cheng, S. Zhao, B. Johannessen, J.-P. Veder, M. Saunders et al., Atomically dispersed transition metals on carbon nanotubes with ultrahigh loading for selective electrochemical carbon dioxide reduction. Adv. Mater. 30, e1706287 (2018).

    [8] [8] H. Guo, D.-H. Si, H.-J. Zhu, Q.-X. Li, Y.-B. Huang et al., Ni single-atom sites supported on carbon aerogel for highly efficient electroreduction of carbon dioxide with industrial current densities. eScience 2, 295–303 (2022).

    [22] [22] D. Karapinar, N.T. Huan, N. Ranjbar Sahraie, J. Li, D. Wakerley et al., Electroreduction of CO2 on single-site copper-nitrogen-doped carbon material: Selective formation of ethanol and reversible restructuration of the metal sites. Angew. Chem. Int. Ed. 58, 15098–15103 (2019).

    [31] [31] H. Zhang, C. Wang, H. Luo, J. Chen, M. Kuang et al., Iron nanoparticles protected by chainmail-structured graphene for durable electrocatalytic nitrate reduction to nitrogen. Angew. Chem. Int. Ed. 62, e202217071 (2023).

    [50] [50] B. Yue, Q. Li, H. Iwai, T. Kako, J. Ye, Hydrogen production using zinc-doped carbon nitride catalyst irradiated with visible light. Sci. Technol. Adv. Mater. 12, 034401 (2011).

    [53] [53] X. Zhao, Y. Cao, L. Duan, R. Yang, Z. Jiang et al., Unleash electron transfer in C–H functionalization by mesoporous carbon-supported palladium interstitial catalysts. Natl. Sci. Rev. 8, nwaa126 (2020).

    [57] [57] G. Zhu, R. Guo, W. Luo, H.K. Liu, W. Jiang et al., Boron doping-induced interconnected assembly approach for mesoporous silicon oxycarbide architecture. Natl. Sci. Rev. 8, nwaa152 (2020).

    [61] [61] Y. Pan, H. Li, J. Xiong, Y. Yu, H. Du et al., Protecting the state of cu clusters and nanoconfinement engineering over hollow mesoporous carbon spheres for electrocatalytical C-C coupling. Appl. Catal. B: Environ. 306, 121111 (2022).

    Tools

    Get Citation

    Copy Citation Text

    Minhan Li, Fangzhou Zhang, Min Kuang, Yuanyuan Ma, Ting Liao, Ziqi Sun, Wei Luo, Wan Jiang, Jianping Yang. Atomic Cu Sites Engineering Enables Efficient CO2 Electroreduction to Methane with High CH4/C2H4 Ratio[J]. Nano-Micro Letters, 2023, 15(1): 238

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: Research Articles

    Received: May. 12, 2023

    Accepted: Aug. 17, 2023

    Published Online: Dec. 15, 2023

    The Author Email: Ma Yuanyuan (yyma@dhu.edu.cn), Yang Jianping (jianpingyang@dhu.edu.cn)

    DOI:10.1007/s40820-023-01188-1

    Topics