Journal of the Chinese Ceramic Society, Volume. 50, Issue 7, 1800(2022)
Graphene-Based Flexible and Wearable Sensors: Fabrication, Application and Perspective
[1] [1] CHOI S, LEE H, GHAFFARI R, et al. Recent advances in flexible and stretchable bio-electronic devices integrated with nanomaterials[J]. Adv Mater, 2016, 28(22): 4203-4218.
[2] [2] TRUNG T Q, LEE N E. Flexible and stretchable physical sensor integrated platforms for wearable human-activity monitoring and personal healthcare[J]. Adv Mater, 2016, 28(22): 4338-4372.
[3] [3] WANG C, XIA K, WANG H, et al. Advanced carbon for flexible and wearable electronics[J]. Adv Mater, 2019, 31(9): 1801072.
[4] [4] WANG J, JIU J, NOGI M, et al. A highly sensitive and flexible pressure sensor with electrodes and elastomeric interlayer containing silver nanowires[J]. Nanoscale, 2015, 7(7): 2926-2932.
[6] [6] LI Q, ULLAH Z, LI W, et al. Wide-range strain sensors based on highly transparent and supremely stretchable graphene/ag-nanowires hybrid structures[J]. Small, 2016, 12(36): 5058-5065.
[7] [7] DONG X, WEI Y, CHEN S, et al. A linear and large-range pressure sensor based on a graphene/silver nanowires nanobiocomposites network and a hierarchical structural sponge[J]. Compos Sci Technol, 2018, 155: 108-116.
[8] [8] GONG S, CHENG W. One-dimensional nanomaterials for soft electronics[J]. Adv Electron Mater, 2017, 3(3): 1600314.
[9] [9] YUAN Y, PENG B, CHI H, et al. Layer-by-layer inkjet printing SPS: PEDOT NP/RGO composite film for flexible humidity sensors[J]. RSC Adv, 2016, 6(114): 113298-113306.
[10] [10] YAO S, SWETHA P, ZHU Y. Nanomaterial-enabled wearable sensors for healthcare[J]. Adv Healthcare Mater, 2018, 7(1): 1700889.
[11] [11] LI C, WU Z-Y, LIANG H-W, et al. Ultralight multifunctional carbon-based aerogels by combining graphene oxide and bacterial cellulose[J]. Small, 2017, 13(25): 1700453.
[12] [12] ZHANG B-X, HOU Z-L, YAN W, et al. Multi-dimensional flexible reduced graphene oxide/polymer sponges for multiple forms of strain sensors[J]. Carbon, 2017, 125: 199-206.
[13] [13] NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696): 666-669.
[14] [14] YANG H, XUE T, LI F, et al. Graphene: Diversified flexible 2D material for wearable vital signs monitoring[J]. Adv Mater Technol, 2019, 4(2): 1800574.
[15] [15] STANKOVICH S, DIKIN D A, DOMMETT G H B, et al. Graphene-based composite materials[J]. Nature, 2006, 442(7100): 282-286.
[16] [16] ZHAO Y, HU C, SONG L, et al. Functional graphene nanomesh foam[J]. Energy Environ Sci, 2014, 7(6): 1913-1918.
[17] [17] LV L, ZHANG P, CHENG H, et al. Solution-processed ultraelastic and strong air-bubbled graphene foams[J]. Small, 2016, 12(24): 3229-3234.
[18] [18] NAG A, MITRA A, MUKHOPADHYAY S C. Graphene and its sensor-based applications: A review[J]. Sens Actuators A, 2018, 270: 177-194.
[19] [19] MA C-B, ZHU Z-T, WANG H-X, et al. A general solid-state synthesis of chemically-doped fluorescent graphene quantum dots for bioimaging and optoelectronic applications[J]. Nanoscale, 2015, 7(22): 10162-10169.
[20] [20] BIANCO A, CHENG H-M, ENOKI T, et al. All in the graphene family—A recommended nomenclature for two-dimensional carbon materials[J]. Carbon, 2013, 65: 1-6.
[21] [21] HUC V, BENDIAB N, ROSMAN N, et al. Large and flat graphene flakes produced by epoxy bonding and reverse exfoliation of highly oriented pyrolytic graphite[J]. Nanotechnology, 2008, 19(45): 455601.
[22] [22] LI X, ZHANG G, BAI, X, et al. Highly conducting graphene sheets and langmuir-blodgett films[J]. Nat Nanotechnol, 2008, 3(9): 538-542.
[23] [23] KIM J, ISHIHARA M, KOGA Y, et al. Low-temperature synthesis of large-area graphene-based transparent conductive films using surface wave plasma chemical vapor deposition[J]. Appl Phys Lett, 2011, 98(9): 091502.
[24] [24] CHEN J, YAO B, LI C, et al. An improved hummers method for eco-friendly synthesis of graphene oxide[J]. Carbon, 2013, 64: 225-229.
[25] [25] WU Z-S, REN W, GAO L, et al. Synthesis of high-quality graphene with a pre-determined number of layers[J]. Carbon, 2009, 47(2): 493-499.
[26] [26] ISLAM A, MUKHERJEE B, PANDEY K K, et al. Ultra-fast, chemical-free, mass production of high quality exfoliated graphene[J]. ACS Nano, 2021, 15(1): 1775-1784.
[27] [27] LIU F, WANG C, SUI X, et al. Synthesis of graphene materials by electrochemical exfoliation: Recent progress and future potential[J]. Carbon Energy, 2019, 1(2): 173-199.
[28] [28] LOTYA M, HERNANDEZ Y, KING P J, et al. Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions[J]. J Am Chem Soc, 2009, 131(10): 3611-3620.
[29] [29] LIN L, DENG B, SUN J, et al. Bridging the gap between reality and ideal in chemical vapor deposition growth of graphene[J]. Chem Rev, 2018, 118(18): 9281-9343.
[30] [30] LI X, CAI W, AN J, et al. Large-area synthesis of high-quality and uniform graphene films on copper foils[J]. Science, 2009, 324(5932): 1312-1314.
[31] [31] CAI W, PINER R D, ZHU Y, et al. Synthesis of isotopically-labeled graphite films by cold-wall chemical vapor deposition and electronic properties of graphene obtained from such films[J]. Nano Res, 2009, 2(11): 851.
[32] [32] WANG J, CHEN L, WU N, et al. Uniform graphene on liquid metal by chemical vapour deposition at reduced temperature[J]. Carbon, 2016, 96: 799-804.
[33] [33] CHEN Z, QI Y, CHEN X, et al. Direct CVD growth of graphene on traditional glass: Methods and mechanisms[J]. Adv Mater, 2019, 31(9): 1803639.
[34] [34] CHEN Z, XIE C, WANG W, et al. Direct growth of wafer-scale highly oriented graphene on sapphire[J]. Sci Adv, 2021, 7(47): eabk0115.
[35] [35] HUMMERS W S, OFFEMAN R E. Preparation of graphitic oxide[J]. J Am Chem Soc,1958, 80(6): 1339-1339.
[36] [36] PENG L, XU Z, LIU Z, et al. An iron-based green approach to 1 h production of single-layer graphene oxide[J]. Nat Commun, 2015, 6(1): 5716.
[37] [37] JIAN M, ZHANG Y, LIU Z. Graphene fibers: Preparation, properties, and applications[J]. Acta Phys Chim Sin, 2022, 38(2): 2007093.
[38] [38] XU T, ZHANG Z, QU L. Graphene-based fibers: Recent advances in preparation and application[J]. Adv Mater, 2020, 32(5): 1901979.
[39] [39] XU Z, GAO C. Graphene chiral liquid crystals and macroscopic assembled fibres[J]. Nat Commun, 2011, 2(1): 571.
[40] [40] TIAN Q, XU Z, LIU Y, et al. Dry spinning approach to continuous graphene fibers with high toughness[J]. Nanoscale, 2017, 9(34): 12335-12342.
[41] [41] DONG Z, JIANG C, CHENG H, et al. Facile fabrication of light, flexible and multifunctional graphene fibers[J]. Adv Mater, 2012, 24(14): 1856-1861.
[42] [42] MA T, GAO H-L, CONG H-P, et al. A bioinspired interface design for improving the strength and electrical conductivity of graphene-based fibers[J]. Adv Mater, 2018, 30(15): 1706435.
[43] [43] FANG B, XIAO Y, XU Z, et al. Handedness-controlled and solvent-driven actuators with twisted fibers[J]. Mater Horiz, 2019, 6(6): 1207-1214.
[44] [44] CUI G, CHENG Y, LIU C, et al. Massive growth of graphene quartz fiber as a multifunctional electrode[J]. ACS Nano, 2020, 14(5): 5938-5945.
[45] [45] FANG B, CHANG D, XU Z, et al. A review on graphene fibers: Expectations, advances, and prospects[J]. Adv Mater, 2020, 32(5): 1902664.
[46] [46] LAN X, TIAN Z Q, SHEN P K. Hollow graphene fibers with archimedean-type spirals for flexible and wearable electronics[J]. ACS Appl Nano Mater, 2021, 4(7): 6985-6994.
[47] [47] LI X, ZHAO T, WANG K, et al. Directly drawing self-assembled, porous, and monolithic graphene fiber from chemical vapor deposition grown graphene film and its electrochemical properties[J]. Langmuir, 2011, 27(19): 12164-12171.
[48] [48] CRUZ-SILVA R, MORELOS-GOMEZ A, KIM H-I, et al. Super-stretchable graphene oxide macroscopic fibers with outstanding knotability fabricated by dry film scrolling[J]. ACS Nano, 2014, 8(6): 5959-5967.
[49] [49] WANG H, WANG C, JIAN M, et al. Superelastic wire-shaped supercapacitor sustaining 850% tensile strain based on carbon nanotube@graphene fiber[J]. Nano Res, 2018, 11(5): 2347-2356.
[50] [50] ZUO Y, YU W, LIU C, et al. Optical fibres with embedded two-dimensional materials for ultrahigh nonlinearity[J]. Nat Nanotechnol, 2020, 15(12): 987-991.
[51] [51] SUN Z, FANG S, HU Y H. 3D graphene materials: From understanding to design and synthesis control[J]. Chem Rev, 2020, 120(18): 10336-10453.
[52] [52] XU Z, ZHANG Y, LI P, et al. Strong, conductive, lightweight, neat graphene aerogel fibers with aligned pores[J]. ACS Nano, 2012, 6(8): 7103-7113.
[53] [53] MOORTHY B, PONRAJ R, YUN J H, et al. Ice-templated free-standing reduced graphene oxide for dendrite-free lithium metal batteries[J]. ACS Appl Energy Mater, 2020, 3(11): 11053-11060.
[54] [54] CHABOTV, HIGGINS D, YU A, et al. A review of graphene and graphene oxide sponge: Material synthesis and applications to energy and the environment[J]. Energy Environ Sci, 2014, 7(5): 1564-1596.
[55] [55] HU G, XU C, SUN Z, et al. 3D graphene-foam-reduced-graphene-oxide hybrid nested hierarchical networks for high-performance Li-S batteries[J]. Adv Mater, 2016, 28(8): 1603-1609.
[56] [56] CHEN W, GUI X, LIANG B, et al. Structural engineering for high sensitivity, ultrathin pressure sensors based on wrinkled graphene and anodic aluminum oxide membrane[J]. ACS Appl Mater Interfaces, 2017, 9(28): 24111-24117.
[57] [57] ZHANG M, CHEN K, WANG C, et al. Mineral-templated 3D graphene architectures for energy-efficient electrodes[J]. Small, 2018, 14(22): 1801009.
[58] [58] QIAO Y, LI X, HIRTZ T, et al. Graphene-based wearable sensors[J]. Nanoscale, 2019, 11(41): 18923-18945.
[59] [59] YANG T, WANG W, ZHANG H, et al. Tactile sensing system based on arrays of graphene woven microfabrics: Electromechanical behavior and electronic skin application[J]. ACS Nano, 2015, 9(11): 10867-10875.
[60] [60] LIU Q, CHEN J, LI Y, et al. High-performance strain sensors with fish-scale-like graphene-sensing layers for full-range detection of human motions[J]. ACS Nano, 2016, 10(8): 7901-7906.
[61] [61] ZANG J, RYU S, PUGNO N, et al. Multifunctionality and control of the crumpling and unfolding of large-area graphene[J]. Nat Mater, 2013, 12(4): 321-325.
[62] [62] FU X-W, LIAO Z-M, ZHOU J-X, et al. Strain dependent resistance in chemical vapor deposition grown graphene[J]. Appl Phys Lett, 2011, 99(21): 213107.
[63] [63] CHENG Y, WANG R, SUN J, et al. A stretchable and highly sensitive graphene-based fiber for sensing tensile strain, bending, and torsion[J]. Adv Mater, 2015, 27(45): 7365-7371.
[64] [64] LIAO X, LIAO Q, YAN X, et al. Flexible and highly sensitive strain sensors fabricated by pencil drawn for wearable monitor[J]. Adv Funct Mater, 2015, 25(16): 2395-2401.
[65] [65] LIAO X, ZHANG Z, LIAO Q, et al. Flexible and printable paper-based strain sensors for wearable and large-area green electronics[J]. Nanoscale, 2016, 8(26): 13025-13032.
[66] [66] MIAO P, WANG J, ZHANG C, et al. Graphene nanostructure-based tactile sensors for electronic skin applications[J]. Nano-Micro Lett, 2019, 11(1): 71.
[67] [67] XU Y, ZHAO G, ZHU L, et al. Pencil-paper on-skin electronics[J]. Proc Natl Acad Sci, 2020, 117(31): 18292-18301.
[68] [68] MANNSFELD S C B, TEE B C K, STOLTENBERG R M, et al. Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers[J]. Nat Mater, 2010, 9(10): 859-864.
[69] [69] RIM Y S, BAE S-H, CHEN H, et al. Recent progress in materials and devices toward printable and flexible sensors[J]. Adv Mater, 2016, 28(22): 4415-4440.
[70] [70] BAE G Y, PAK S W, KIM D, et al. Linearly and highly pressure-sensitive electronic skin based on a bioinspired hierarchical structural array[J]. Adv Mater, 2016, 28(26): 5300-5306.
[71] [71] XIA K, WANG C, JIAN M, et al. CVD growth of fingerprint-like patterned 3D graphene film for an ultrasensitive pressure sensor[J]. Nano Res, 2018, 11(2): 1124-1134.
[72] [72] CAO M, SU J. FAN S, et al. Wearable piezoresistive pressure sensors based on 3D graphene[J]. Chem Eng J, 2021, 406: 126777.
[73] [73] MIN P, LI X, LIUP, et al. Rational design of soft yet elastic lamellar graphene aerogels via bidirectional freezing for ultrasensitive pressure and bending sensors[J]. Adv Funct Mater, 2021, 31(34): 2103703.
[74] [74] YAO H-B, GE J, WANG C-F, et al. A flexible and highly pressure-sensitive graphene-polyurethane sponge based on fractured microstructure design[J]. Adv Mater, 2013, 25(46): 6692-6698.
[75] [75] TRUNG T Q, RAMASUNDARAM S, HONG S W, et al. Flexible and transparent nanocomposite of reduced graphene oxide and p(vdf-trfe) copolymer for high thermal responsivity in a field-effect transistor[J]. Adv Funct Mater, 2014, 24(22): 3438-3445.
[76] [76] HOU C, WANG H, ZHANG Q, et al. Highly conductive, flexible, and compressible all-graphene passive electronic skin for sensing human touch[J]. Adv Mater, 2014, 26(29): 5018-5024.
[77] [77] TRUNG T Q, RAMASUNDARAM S, HWANG B-U, et al. An all-elastomeric transparent and stretchable temperature sensor for body-attachable wearable electronics[J]. Adv Mater, 2016, 28(3): 502-509.
[78] [78] JEON J, LEE H-B-R, BAO Z. Flexible wireless temperature sensors based on ni microparticle-filled binary polymer composites[J]. Adv Mater, 2013, 25(6): 850-855.
[79] [79] HOD H, SUN Q, KIM S Y, et al. Stretchable and multimodal all graphene electronic skin[J]. Adv Mater, 2016, 28(13): 2601.
[80] [80] DAVAJI B, CHO H D, MALAKOUTIAN M, et al. A patterned single layer graphene resistance temperature sensor[J]. Sci Rep, 2017, 7(1): 8811.
[81] [81] KONG D, LE L T, LI Y, et al. Temperature-dependent electrical properties of graphene inkjet-printed on flexible materials[J]. Langmuir, 2012, 28(37): 13467-13472.
[82] [82] PARK J, KIM M, LEE Y, et al. Fingertip skin-inspired microstructured ferroelectric skins discriminate static/dynamic pressure and temperature stimuli[J]. Sci Adv, 2015, 1(9): e1500661.
[83] [83] FARAHANI H, WAGIRAN R, HAMIDON M N. Humidity sensors principle, mechanism, and fabrication technologies: A comprehensive review[J]. Sensors, 2014, 14(5): 7881-7939.
[84] [84] CAO Y, LI T, GU Y, et al. Fingerprint-inspired flexible tactile sensor for accurately discerning surface texture[J]. Small, 2018, 14(16): 1703902.
[85] [85] CHEN C, WANG X, LI M, et al. Humidity sensor based on reduced graphene oxide/lignosulfonate composite thin-film[J]. Sens Actuators B, 2018, 255: 1569-1576.
[86] [86] ZHANG D, CHANG H, LI P, et al. Fabrication and characterization of an ultrasensitive humidity sensor based on metal oxide/graphene hybrid nanocomposite[J]. Sens Actuators B, 2016, 225: 233-240.
[87] [87] TU N D K, CHOI J, PARK C R, et al. Remarkable conversion between n- and p-type reduced graphene oxide on varying the thermal annealing temperature[J]. Chem Mater, 2015, 27(21): 7362-7369.
[88] [88] AGMON N. The grotthuss mechanism[J]. Chem Phys Lett, 1995, 244(5): 456-462.
[89] [89] ZHANG D, WANG D, LI P, et al. Facile fabrication of high-performance QCM humidity sensor based on layer-by-layer self-assembled polyaniline/graphene oxide nanocomposite film[J]. Sens Actuators B, 2018, 255: 1869-1877.
[90] [90] ZHANG D, TONG J, XIA B. Humidity-sensing properties of chemically reduced graphene oxide/polymer nanocomposite film sensor based on layer-by-layer nano self-assembly[J]. Sens Actuators B, 2014, 197: 66-72.
[91] [91] TRUNG T Q, RAMASUNDARAM S, HWANG B-U, et al. An all-elastomeric transparent and stretchable temperature sensor for body-attachable wearable electronics[J]. Adv Mater, 2016, 28(3): 502.
[92] [92] SINGH E, MEYYAPPAN M, NALWA H S. Flexible graphene-based wearable gas and chemical sensors[J]. ACS Appl Mater Interfaces, 2017, 9(40): 34544-34586.
[93] [93] LEE H, CHOI T K, LEE Y B, et al. A graphene-based electrochemical device with thermoresponsive microneedles for diabetes monitoring and therapy[J]. Nat Nanotechnol, 2016, 11(6): 566-572.
[94] [94] LIPANI L, DUPONT B G R, DOUNGMENE F, et al. Non-invasive, transdermal, path-selective and specific glucose monitoring via a graphene-based platform[J]. Nat Nanotechnol, 2018, 13(6): 504-511.
[95] [95] YANG G, KIM H-Y, JANG S, et al. Transfer-free growth of multilayer graphene using self-assembled monolayers[J]. ACS Appl Mater Interfaces, 2016, 8(40): 27115-27121.
[96] [96] STRONG V, DUBIN S, EL-KADY M F, et al. Patterning and electronic tuning of laser scribed graphene for flexible all-carbon devices[J]. ACS Nano, 2012, 6(2): 1395-1403.
[97] [97] ZHAO X, LONG Y, YANG T, et al. Simultaneous high sensitivity sensing of temperature and humidity with graphene woven fabrics[J]. ACS Appl Mater Interfaces, 2017, 9(35): 30171-30176.
[98] [98] XU H, XIANG J X, LU Y F, et al. Multifunctional wearable sensing devices based on functionalized graphene films for simultaneous monitoring of physiological signals and volatile organic compound biomarkers[J]. ACS Appl Mater Interfaces, 2018, 10(14): 11785-11793.
[99] [99] HUANG L, SU J, SONG Y, et al. Laser-induced graphene: En route to smart sensing[J]. Nano-Micro Lett, 2020, 12(1): 157.
[100] [100] WANG H, WANG H, WANG Y, et al. Laser writing of janus graphene/kevlar textile for intelligent protective clothing[J]. ACS Nano, 2020, 14(3): 3219-3226.
[101] [101] WEI Y, LI X, WANG Y, et al. Graphene-based multifunctional textile for sensing and actuating[J]. ACS Nano, 2021, 15(11): 17738-17747.
Get Citation
Copy Citation Text
ZHANG Qing, LI Shuo, LIU Guimin, ZHANG Yong, ZHANG Yingying. Graphene-Based Flexible and Wearable Sensors: Fabrication, Application and Perspective[J]. Journal of the Chinese Ceramic Society, 2022, 50(7): 1800
Special Issue:
Received: Dec. 23, 2021
Accepted: --
Published Online: Dec. 6, 2022
The Author Email:
CSTR:32186.14.