Journal of Inorganic Materials, Volume. 35, Issue 5, 511(2020)

Advances in Inorganic All-solid-state Electrochromic Materials and Devices

Hanxiang JIA1...2, Xun CAO1,* and Pingshi JIN1 |Show fewer author(s)
Author Affiliations
  • 1State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22.Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(24)
    Schematic diagram of chromogenic system
    Schematic diagram (a) and photographs (b-e) of flexible electrochromic device of Ag/W18O49 nanowire co-assemble[17]
    Schematic illustrations of functioning mechanisms for the bi-functional device[18]
    Performance index of the functional layers of inorganic all-solid-state electrochromic device
    Schematic diagram of typical electrochromic device structure[10]
    The key performance evaluation index of typical electrochromic device
    Schematic illustration of the preparation for electrochromic electrodes with and without a graphene interface layer[31]
    Pictures of gel films on FTO glass[32]
    Schematic illustration for the formation of Co3O4 macro- bowl array films[33]
    Synthesis of Nb2O5 thin films grown by single source precursor CVD[34]
    Ag/W18O49 nanowire co-assembles prepared by L-B technique[17]
    Schematic diagram of the fabrication process of the hybrid electrochromic electrode based on self-forming crackle pattern technology[35]
    Ag grid/PEDOT hybrid flexible eletrode film[36]
    Scheme of a new ESS window device system (a) and schematic for the device preparation process (b)[16]
    Transmittance and optical modulation changes of the WO3 on the silver grid/PEDOT:PSS hybrid film in the bleached and colored state[36]
    SEM cross-section image of ECD-fresh: Glass/ITO/ WO3/LiTaO3/NiO/ITO[52]
    SEM cross-sectional images (a-b) of ECD-1 and ECD-2 with and without the embedment of Ta2O5 layers[53]
    Electrochromic response of W18O49 nanowires under electrochemical insertion from one of the three different ions: Li+, Na+, and Al3+ in organic polycarbonate (PC) solvent using ClO4- as counter ion under ambient conditions[54]
    Electrochromic performance of WO3 films under various operations[58]
    Electrochromic properties of NiO nanoparticles film with seed layer on ITO glass[61]
    LixNiOy all-solid-state ECDs based on gradient Li+ distribution and its performance
    Schematic representation for the LBL fabrication of the multilayered (LDH/PB)n electrochromic film[63,64]
    All-solid-state electrochromic devices developed by our research group
    • Table 1. Electrochromic materials and their deposition methods

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      Table 1. Electrochromic materials and their deposition methods

      CategoryEC LayerPreparation method
      Cathod colorationWO3Magnetron sputtering[23], vacuum evaporation, Sol-Gel
      MoO3Magnetron sputtering[24], vacuum evaporation[25]
      Nb2O5Anodic oxidation[26]
      TiO2Hydrothermal[27]
      Anode coloringNiOxMagnetron sputtering
      IrO2Anodic oxidation[28]
      CoO2Hydrothermal[29]
      Prussian blueElectrochemical deposition[30]
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    Hanxiang JIA, Xun CAO, Pingshi JIN. Advances in Inorganic All-solid-state Electrochromic Materials and Devices[J]. Journal of Inorganic Materials, 2020, 35(5): 511

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    Paper Information

    Category: REVIEW

    Received: Jun. 24, 2019

    Accepted: --

    Published Online: Mar. 1, 2021

    The Author Email: CAO Xun (cxun@mail.sic.ac.cn)

    DOI:10.15541/jim20190305

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